• 한국진공학회지
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• 제9권3호
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• pp.279-284
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• 2000

본 연구는 옥외용 epoxy/glass fiber의 열화과정을 분석하기 위하여 FRP 적층판을 고온과 수에 노출시켰다. 열화과정은 접촉각, 표면전위감쇠, 표면저항률의 비교에 의해 평가하였다. 젖음성의 변화는 열처리 시료에서 $200^{\circ}C$까지 접촉각이 증가하였지만 수분처리 시료는 감소하였다. 표면전위감쇠 특성은 수분처리 시료에서는 감소하지만, 열처리 시료는 미 처리와 비교해서 증가하였다. 또한, 표면저항률은 접촉각의 변화와 같은 경향을 보이고 있다.

• 대한화학회지
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• 제57권6호
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• pp.691-696
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• 2013

Black carbon contributes to global warming and melting of polar ice as well as causing respiratory diseases. However, it is also an inexpensive, easily available carbon nano material for elementary chemistry experiments. In this study, black carbon samples collected from candle light and automobile exhaust pipes have been investigated to examine their compositions and surface characteristics. The observed broad G and D bands and amorphous $sp^3$ band in their Raman spectra as well as the high intensity of the D (defect) band reveal that black carbon is principally made of amorphous graphite. The black carbon deposits in automobile exhaust pipes are apparently more amorphous, probably due to the shorter time allowed for formation of the carbonaceous matter. An exceptionally large water contact angle ($159.7^{\circ}$) is observed on black carbon, confirming its superhydrophobicity. The surface roughness evidently plays an important role for the contact angle much larger than that of crystalline graphite ($98.3^{\circ}$). According to the Sassie-Baxter equation, less than 1% the area actually in contact with the water drop.

• 한국지반신소재학회논문집
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• 제21권4호
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• pp.93-100
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• 2022

본 연구에서는 다양한 소수성 조건으로 코팅된 흙 입자 표면이 함수비 조건에 따라 분광정보에 미치는 영향을 평가하였다. 이를 위해 소수성으로 코팅된 표준사의 습윤성 실험 및 분광정보 평가 실험을 수행하였다. 습윤성 평가 결과, 1%, 3% 및 5%로 소수성 코팅된 표준사의 건조시간에 따른 표준사-물 경계면의 접촉각은 각각 약 130°~143°, 약 129°~144°와 약 131°~144°의 범위를 보였다. 이는 동일한 건조시간에서 소수성 코팅 정도가 증가할수록 접촉각은 증가하였지만, 접촉각의 범위는 동일한 범주의 습윤성을 갖는 것을 의미한다. 분광정보 평가 결과, 소수성 상태를 갖는 건조된 표준사는 친수성 상태의 표준사에 비하여 소수성 수준의 증가에 따라 최대분광반사율이 감소한 반면에, 동일한 함수비 조건에서는 소수성 정도가 증가할수록 최대분광반사율이 증가하는 것으로 평가되었다.

• 접착 및 계면
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• 제4권4호
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• pp.1-6
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• 2003

대기압 플라즈마를 이용하여 폴리프로필렌 필름의 표면을 처리한 후 각각 극성 용매(water)와 비극성 용매(diiodomethane)를 사용한 접촉각 측정기로 필름 표면의 접촉각을 측정하였다. 측정된 접촉각을 이용해 표면 자유에너지 변화를 계산한 후 대기압 플라즈마 처리 전후의 폴리프로필렌 필름의 접촉각과 표면 자유에너지 상태를 비교, 분석하였다. 또한 대기압 플라즈마의 처리 조건을 바꿔가며 폴리프로필렌 필름 표면을 처리함으로써 접촉각과 표면 자유에너지가 각각의 처리 조건에 따라 어떠한 영향을 받는지 연구하였다. 대기압 플라즈마 처리 조건에 따라 접촉각 및 표면 자유에너지는 최적값을 보여주거나 일정한 값에 도달하는 경향을 보여 주었다.

• 설비공학논문집
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• 제30권1호
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• pp.33-43
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• 2018

This study numerically investigated statistic and dynamic behaviors of the water droplet on plate with or without various structured-pillars at nano-scale by molecular dynamics simulation. This study considered smooth plate, plate with the rectangular-structured pillar, and the plate with dual-structured pillar under various characteristic energy conditions. The static behavior of water droplet depending on the plate shape, plate surface energy, and the pillar characteristics were examined. After the water droplet reaches its steady state, this study investigated the dynamic behavior of the water droplet by applying a constant force. Finally, this study investigated the static and dynamic behaviors of the water droplet by measuring its contact angle and contact angle hysteresis. As a result, we found that the structure was more hydrophobic.

• 한국건축시공학회지
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• 제21권6호
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• pp.529-538
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• 2021

본 논문은 발수제 첨가 모르타르의 강도 및 발수성에 미치는 다양한 요인 중에서 발수제 종류 및 잔골재 입도에 대한 영향을 검토하고자 하였다. 그 결과 발수제 첨가 시멘트 모르타르의 압축강도는 무첨가 시멘트 모르타르와 비교하여 감소하였고, 올리고머계 발수제 첨가 모르타르의 압축강도는 모노머계 발수제와 비교하여 높게 나타났다. 또한 잔골재 입도에 따른 시멘트 모르타르 압축강도 영향은 크게 나타나지 않았다. 발수제 첨가 모르타르의 접촉각은 무첨가 모르타르와 비교하여 증가하였고, 올리고머계 발수제보다는 모노머계 발수제가 상대적으로 증가하였다. 또한 연마 전후 접촉각은 잔골재 입도에 따라서 상이한 경향을 보이고 있다.

• 대한기계학회논문집A
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• 제31권6호
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• pp.679-685
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• 2007

Superhydrophobic surface, with a water contact angle greater than $150^{\circ}$, has a self-cleaning effect termed 'Lotus effect'. This surface is created by the combination of rough surface and the low surface energy. We proposed square pillar and square shapes to control surface roughness. Microstructure arrays are fabricated by DRIE(Deep Reactive Ion Etching) process and followed by PPFC(Plasma Polymerized Fluorocarbon) deposition. On the experimental result, contact angle at square pillar arrays is well matched with Cassie's model and largest contact angle is $173.37^{\circ}$. But contact angle of square pore shape arrays is lower than Cassie's theoretical contact angle about $5{\sim}10%$. Nevertheless, square pore arrays have more rigidity than square pillar arrays.

• Tribology and Lubricants
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• 제35권5호
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• pp.294-299
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• 2019

Most previous studies on water repellent surfaces using lasers rely on the use of pico- or femtosecond lasers. However, in industrial application, these methods have the disadvantages of high cost and low efficiency. In this study, we implement a hydrophobic surface using a high-power general-purpose diode laser. We have fabricated the microsurface using laser groove processing technology, and we present the correlation of wettability characteristics with space and width. The metal material is stainless steel (SUS 304), and the groove height during laser processing is set to $30{\mu}m$ to evaluate the wettability based on the gap and width of various grooves. Results show that the contact angle of the groove-shaped surface is increased by $40^{\circ}$ or more as compared with the surface without patterning, and the contact angle in the parallel direction is greater than that in the perpendicular direction. Results from contact angle hysteresis measurement experiments show that the groove width has a greater influence on the contact angle history than does the gap between grooves. In addition, the coating reveals that the contact angle can be increased using a chemical method and that the laser grooving process can further improve the wetting properties of the surface.

• 설비공학논문집
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• 제12권1호
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• pp.95-101
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• 2000

The effect of surface contact angle on the behavior of frost formation in a fin-tube heat exchanger is investigated experimentally. It is shown that both heat exchangers with hydrophilic and hydrophobic surfaces appear to have a better thermal performance than bare aluminium heat exchanger, but the improvements are very small. There is a little increase in the amount of the frost deposited onto the heat exchanger with both hydrophilic and hydrophobic surface. However, the effect of contact angle on the frost density is observed ; the frost with high density forms on the heat exchanger with hydrophilic surface ; and the frost with low density is deposited onto the heat exchanger with hydrophobic surface when compared with the frost deposited onto the heat exchanger with bare aluminium surface. This may be attributed to the fact that the shape of water droplets which condense on the surface of heat exchanger at the early stage of frosting varies with contact angle, and thus makes a difference on the structure of frost formation. From the experiments with different relative humidity of inlet air, it is shown that the variations of operating parameter make no influence on the effect of surface contact angle on the frosting behavior in the heat exchanger.

• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제49권10호
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• pp.553-558
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• 2000

This paper deals with change of contact angle, surface potential decay, surface resistivity and XPS of water-treated epoxy insulator. From the experimental results on the contact angle was reduced from $74^{\circ}$to $24^{\circ}$ due to the formation of polar hydroxyl groups on surface which was associated with intermolecular reaction between epoxy chains of three-dimensional network structure and water molecules. From the experimental results in the surface potential decay of water treated-samples, it was found that the accumulation of charge is decreased and the surface potential decay time is shortened by the interaction of polar hydroxyl groups induced on the treated surface as the increment of treatment time. The positive charging on the treated surface compared with negative charging is relatively lowered by the induction of polar hydroxyl groups. The surface resistivity was changed from $10^{15}[{\Omega}/cm^2$] to $10^{12}[{\Omega}/cm^2$] caused by water treatment. From XPS, it was found that the changes affected by the surface degradation of epoxy were caused by the generation of carboxyl groups through the chain decomposition and recombination with oxygen molecules in the air.