• Title/Summary/Keyword: W-Ni

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Substitution of Co on Magnetic Properties of Ni-Zn Ferrites (Co 치환에 따른 Ni-Zn Ferrites의 자기적 특성)

  • Park, H.Y.;Ahn, M.S.;Ahn, Y.W.;Lee, S.K.;Oh, Y.W.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.07a
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    • pp.539-542
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    • 2004
  • 전자기기의 발달과 더불어 정보통신분야의 발달로 고주파 대역에서 우수하고 안정적인 Ni-Zn 페라이트를 제조하기 위해, Ni(니켈)의 일부를 코발트(Co)로 치환하여 결정자기이방성 상수 값을 증가시켜, 공명 주파수를 고주파 대역으로 높이고자 하였다. Co 함량이 증가함에 따라 투자율은 감소하는데, 이는 결정자기 이방성 상수를 크게 하여 공명 주파수를 높이는 결과를 보였으며, x=0.05에서 투자율 75, 공명 주파수 20MHz의 특성을 나타내었다.

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A Study on the Burning Characteristics of N-5 Propellant Embedded with Metal Wires (금속선을 삽입한 N-5복기 추진제의 연소 특성)

  • 유지창;박영규;김인철
    • Journal of the Korean Society of Propulsion Engineers
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    • v.3 no.1
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    • pp.78-85
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    • 1999
  • Burning characteristics of solid propellants embedded with four kinds of metal wires(Ag, Cu, Al, Ni-Cr wire) were studied with varying wire diameters(O.10.8 mm) lot N-5 propellant. It was found that the order of the burning rate increment ratio($r_w$/$r_sb$) was Ag wire > Cu wire > Al wire> Ni-Cr wire which was the same as the order of the magnitude of thermal diffusivity. The burning rate increment ratio($r_w$/$r_sb$) of N-5 propellant was less than that of composite Propellant because of the difference of adiabatic flame temperature and flame structure. When Ag, Cu and Al wire having high thermal diffusivity were embedded in N-5 propellant, the plateau and mesa characteristics of the double base propellant were disappeared, but not disappeared in the case of propellant embedded with Ni-Cr wire due to its poor thermal conductivity.

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Effect of Alloying on the Microstructure and Fatigue Behavior of Fe-Ni-Cu-Mo P/M Steels

  • Bohn, Dmitri A.;Lawley, Alan
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 1997.04a
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    • pp.34-34
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    • 1997
  • The effect of alloying mode and porosity on the axial tension-tension fatigue behavior of a P/M steel of nominal composition Fe-4w/o Ni-1.5w/o Cu-O.5w/o Mo-O.5w/o C has been evaluated. Alloying modes utilized were elemental powder mixing, partial alloying(distaloy) and prealloying by water atomization; in each case the carbon was introduced as graphite prior to sintering. Powder compacts were sintered($1120{\circ}C$/30 min.) in 7Sv/o $H_2$/25v/o $N_2$ to densities in the range 6.77-7.2 g/$cm^3$. The dependence of fatigue limit response on alloying mode and porosity was interpreted in terms of the constituent phases and the pore and fracture morphologies associated with the three alloying modes. For the same nominal composition, the three alloying modes resulted in different sintered microstructures. In the elemental mix alloy and the distaloy, the major constituent was coarse and fine pearlite, with regions of Ni-rich ferrite, Ni-rich martensite and Ni-rich areas. In contrast, the prealloy consisted primarily of martensite by with some Ni-rich areas. From an examination of the fracture surfaces following fatigue testing it was concluded that essentially all of the fracture surfaces exhibited dimpled rupture, characteristic of tensile overload. Thus, the extent of growth of any fatigue cracks prior to overload was small. The stress amplitude for the three alloying modes at 2x$l0^6$ was used for the comparison of fatigue strengths. For load cycles <3x$l0^5$, the prealloy exhibited optimum fatigue response followed by the distaloy and elemental mix alloy, respectively. At load cycles >2x$l0^6$, similar fatigue limits were exhibited by the three alloys. It was concluded that fatigue cracks propagate primarily through pores, rather than through the constituent phases of the microstructure. A decrease in pore SIze improved the S-N behavior of the sintered steel.

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Segregation Phenomenon of As-Cast and Heat Treatment Microstructures in Investment Casting of IN738LC Superalloy (IN738LC 초내열합금 정밀 주조의 주조 및 열처리 미세조직에 구성되는 성분 편석 현상)

  • Choe, Byung Hak;Han, Sung Hee;Kim, Dae Hyun;Ahn, Jong Kee;Lee, Jae Hyun
    • Korean Journal of Materials Research
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    • v.31 no.7
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    • pp.409-419
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    • 2021
  • The effect of solidification rate on micro-segregation in investment casting of IN738LC superalloy was studied. In Ni-based superalloys, the micro-segregation of solute atoms is formed due to limited diffusion during cast and solidification. The microstructure of cast Ni-based superalloys is largely divided into dendrite core of initial solidification and interdendrite of final solidification. In particular, mosaic shaped eutectic γ/γ' and carbides are formed in the interdendrite of the final solidification region in some cases. The micro-segregation phenomena formed in regions of dendrite core and interdendrite including eutectic γ/γ' and carbides were analyzed using OM, SEM/EDS and micro Vickers hardness. As a result of analysis, the lack of (Cr, W) and the accumulation of Ti were measured in the eutectic γ/γ', and the accumulation of (Cr, Mo) and the lack of Ti were measured in the interdendrite between dendrite and eutectic. Carbides formed in interdendritic region were composed of (Ti, W, Mo, C). The segregation applied to each microstructure is mainly due to the formation of γ' with Ni3(Al,Ti) composition. The Ni accumulation accompanied by Cr depletion, and the Ti accumulated in the eutectic region as a γ' forming elements. The Mo tends to diffuse out from the dendrite core to the interdendrite, and the W diffuse out from the interdendrite to the dendrite core. Therefore, the accumulation of Mo in the interdendrite and the deficiency of W occur in the eutectic region located in the interdendrite. Heat treatment makes the degree of the micro-segregation decrease due to the diffusion during solid solution. This study could be applied to the heat treatment technology for the micro-segregation control in cast Ni-based superalloys.

Study on characteristics of p-GaN ohmic contacts by rapid thermal annealing (열처리에 따른 p-GaN의 오믹접촉 특성에 관한 연구)

  • Kim, D.S.;Lee, S.J.;Seong, K.S.;Kang, Y.M.;Cha, J.H.;Kim, N.H.;Jung, W.;Cho, H.Y.;Kang, T.W.;Kim, D.Y.;Lee, Y.H.
    • Proceedings of the IEEK Conference
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    • 2000.06b
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    • pp.310-313
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    • 2000
  • In this study, the Au/Ni and Au/Ni/Si/Ni layers prepared by electron beam evaporation were used to form ohmic contacts on p-type GaN. Before rapid thermal annealing, the current-voltage(I-V) characteristic of Au/Ni and Au/Ni/Si/Ni contact on p-type GaN film shows non-ohmic behavior. A Specific contact resistance as 3.4$\times$10$^{-4}$ Ω-$\textrm{cm}^2$ was obtained after 45$0^{\circ}C$-RTA. The Schottky barrier height reduction may be attributed to the presence of Ga-Ni and Ga-Au compounds, such as Ga$_4$Ni$_3$, Ga$_4$Ni$_3$, and GaAu$_2$ at the metal - semiconductor interface. The mixing behaviors of both Ni and Au have been studied by using X-ray photoelectron spectroscopy. In addition, X-ray diffraction measurements indicate that the Ni$_3$N, NiGa$_4$, Ni$_2$Si, and Ni$_3$Si$_2$ Compounds were formed at the metal-semiconductor interface.

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A study on $CeO_2$ buffer layer on biaxially textured Ni-3%W substrate deposited by electron beam evaporation with high deposition rate (전자빔 증착법으로 이축배향된 Ni-3%W 기판 위에 높은 증착률로 제조된 $CeO_2$ 완충층에 대한 연구)

  • Kim, H.J.;Lee, J.B.;Kim, B.J.;Hong, S.K.;Lee, H.J.;Kwon, B.G.;Lee, H.G.;Hong, G.W.
    • Progress in Superconductivity and Cryogenics
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    • v.13 no.1
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    • pp.1-5
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    • 2011
  • [ $CeO_2$ ]has been widely used for single buffer layer of coated conductor because of superior chemical and structural compatibility with $ReBa_2Cu_3O_{7-{\delta}}$(Re=Y, Nd, Sm, Gd, Dy, Ho, etc.). But, the surface of $CeO_2$ layer showed cracks because of the large difference in thermal expansion coefficient between metal substrate and deposited $CeO_2$ layer, when thickness of $CeO_2$ layer exceeds 100 nm on the biaxially textured Ni-3%W substrate. The deposition rate has been limited to be less than 6 $\AA$/sec in order to get a good epitaxy. In this research, we deposited $CeO_2$ single buffer layers on biaxially textured Ni-3%W substrate with 2-step process such as thin nucleation layer(>10 nm) with low deposition rate(3 $\AA$/sec) and thick homo epitaxial layer(>240 nm) with high deposition rate(30 $\AA$/sec). Effect of deposition temperature on degree of texture development was tested. Thick homo epitaxial $CeO_2$ layer with good texture without crack was obtained at $600^{\circ}C$, which has ${\Delta}{\phi}$ value of $6.2^{\circ}$, ${\Delta}{\omega}$ value of $4.3^{\circ}$ and average surface roughness(Ra) of 7.2 nm within $10{\mu}m{\times}10{\mu}m$ area. This result shows the possibility of preparing advanced Ni substrate with simplified architecture of single $CeO_2$ layer for low cost coated conductor.

Effect of Sulfur on the High-temperature Oxidation of Fe-34.4Cr-14.5Ni-2.5Mo-0.4W-0.4Mn-0.5Si Alloys (Fe-34.4Cr-14.5Ni-2.5Mo-0.4W-0.4Mn-0.5Si 합금의 고온 산화에 미치는 S의 영향)

  • Lee, Dong Bok;Lee, Kyong-Hwan;Bae, Geun Soo;Cho, Gyu Chul;Jung, Jae Ok;Kim, Min Jung
    • Journal of the Korean institute of surface engineering
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    • v.50 no.5
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    • pp.386-391
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    • 2017
  • Two kinds of steels whose compositions were Fe-34.4Cr-14.5Ni-2.5Mo-0.4W-0.4Mn-0.5Si-(0.009 or 0.35)S (wt.%) were centrifugally cast, and oxidized at $900^{\circ}C$ for 50-350 h in order to find the effect of sulfur on the high-temperature oxidation of Fe-34.4Cr-14.5Ni-2.5Mo-0.4W-0.4Mn-0.5Si-(0.009 or 0.35)S (wt.%) alloys. These alloys formed oxide scales that consisted primarily of $Cr_2O_3$ as the major oxide and $Cr_2MnO_4$ as the minor one through preferential oxidation of Cr and Mn. They additionally formed $SiO_2$ particles around the scale/alloy interface as well as inside the matrices. The high affinity of Mn with S led to the formation of scattered MnS inclusions particularly in the 0.35S-containing cast alloy. Sulfur was harmful to the oxidation resistance, because it deteriorated the scale/alloy adherence so as to accerelate the adherence and compactness of the formed scales.