• 제목/요약/키워드: W Substituted

검색결과 151건 처리시간 0.023초

텅스텐이 첨가된 슈퍼 2상 스테인리스강의 내부식성에 관한 연구 (Study of Corrosion Resistance in Super-Duplex, Tungsten-Containing Stainless Steel)

  • 최한글;박형균;정병호;한현성;배동수;강창룡
    • 한국해양공학회지
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    • 제24권5호
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    • pp.55-59
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    • 2010
  • The effect of aging on the precipitation of the $\sigma$ phase and corrosion resistance in W-substituted, super-duplex stainless steel was investigated. The volume fraction of the $\sigma$ phase and the current density increased as the aging temperature increased up to $750^{\circ}C$, and, then, they decreased. As aging time increased, the volume fraction of the $\sigma$ phase and the current density also increased. The $\sigma$ phase considerably influenced to corrosion resistance. When Mo was substituted for W in super-duplex stainless steel, the volume fraction of the $\sigma$ phase and the current density both decreased markedly.

UTILIZATION OF NON-CONVENTIONAL FEED RESOURCES IN POULTRY PRODUCTION: RESULTS OF ON-FARM TRIALS

  • Ravindran, V.;Cyril, H.W.
    • Asian-Australasian Journal of Animal Sciences
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    • 제8권4호
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    • pp.387-392
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    • 1995
  • Though a variety of non-conventional feedstuffs have been successfully evaluated in research stations in Asian countries, there had been little adoption of these technologies at the small farm level. The methodology and results of three separate on-farm trials evaluation the possible use of some non-conventional feedstuffs in broiler diets under small farm conditions in Sri Lanka are reported in this paper. In all trials, the commercial mash, that in normally used in the farms, served as the control. In trials 1 and 2, 5 and 10% cassava leaf meal, respectively, was substituted (w/w) for the commercial mash and fed to broilers for six weeks. In trial 3, several non-conventional feedstuffs (cassava leaf meal, rubber seed meal, ipil ipil leaf meal and died poultry manure) were substituted (w/w) for the commercial mash at levels of 15-20%. The results demonstrated that these non-conventional feed resources can be used in broiler diets under small farm conditions, with no adverse effects on performance. The salient features of on-farm animal research are highlighted.

포졸란계 미분말과 ∥ 형 무수석고 치환 시멘트 페이스트 유동성과 시멘트 모르타르의 유동성 및 압축강도 (Fluidity of Cement Paste and Fluidity and Compressive Strength of Cement Mortar Substituted by Pozzolanic fine Powders and II-Anhydrite)

  • 노재성;이범재;김도수;이병기
    • 콘크리트학회지
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    • 제9권3호
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    • pp.149-156
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    • 1997
  • 시멘트 모르타르의 압축강도 향상을 휘하여 분말혼화제를 제조하였으며,분말혼화재 사용에 따르는 유동성 감소를 억제하고자 고유동화제를 사용하였다. 분말혼화재(FAS)는 불산부생 II형 무수석고와 플라이애쉬 및 실리카흄을 혼합제조하여 시멘트 대신 각각10,20 wt% 씩 치환하였다. 물/고형분비(W/S)=0.40에서 FAS 로 치환된 시멘트 페이스트의 유동성은 저하되었고, 유동성 저하의 억제를 위한 고유동화제는 NSF와 NT-2가 효과적이었다. 시멘트 모르타르의 유동성은 II형 무수석고의 분말도가 미세할수록 증가하였고, 유동성저하는 FAS를 10 wt% 치환하였을 때 작게 나타났다. 압축강도는 10 wt%치환한 공시체가 20 wt%치환한 것보다 높게 나타났고 특히 $\gamma$ 를 10 wt%치환한 공시체( CI )에서 가장 높은 압축강도값을 나타내었다.

A Facile One-Pot Synthesis of 1-Substituted Tetrazole-5-thiones and 1-Substituted 5-Alkyl(aryl)sulfanyltetrazoles from Organic Isothiocyanates

  • Han, Sam-Yong;Lee, Je-Woo;Kim, Hee-Jung;Kim, Yong-Joo;Lee, Soon-W.;Gyoung, Young-Soo
    • Bulletin of the Korean Chemical Society
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    • 제33권1호
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    • pp.55-59
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    • 2012
  • Treatments of organic isothiocyanates (R-NCS) with $NaN_3$ in the presence of pyridine in water at room temperature gave corresponding various organic tetrazole-thiones, [$S=CN_4(R)$] (R = alkyl or aryl). Isolated products are obtained as white or yellow solids in good yields (76-97%). The molecular structure by X-ray diffraction study for one of products shows the proposed formation. In addition, one-pot synthesis of 1-substituted 5-alkyl(or aryl)sulfanyltetrazoles has been demonstrated. Addition of alkyl or aryl halides into the mixture of organic isothiocyanates, $NaN_3$, and pyridine in water at room temperature exclusively formed 1-substituted 5-alkyl(or aryl)sulfanyltetrazoles (S-derivatives) in high yields.

Reactioin Characteristics of the Sm2Fe17-xGax(x0, 2) Alloy with Hydrogen and Methane Gas

  • Shon, S.W;Kwon, H.W
    • Journal of Magnetics
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    • 제4권4호
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    • pp.123-127
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    • 1999
  • The Ga-stabilised $Sm_2Fe_{17-}$type alloy can hardly be disproportionated under ordinary HDDR condition. The HDDR characteristics of Ga-substituted $Sm_2Fe_{17-}$type alloy were examined, and, in particular, the effect of particle size on the disproportionation of the Ga-substituted alloy was investigated in detail. The reaction characteristics of the $Sm_2Fe_{17-}$type alloys with or without Ga-substitution with methane (CH4) gas are also examined. The Ga-stabilised $Sm_2Fe_{17-}$type alloy was able to be disproportionated significantly on heating up to 80$0^{\circ}C$ under hydrogen with normal pressure. The particle size influenced significantly on the disproportion-ation of the Ga-substitute alloy, and the materials with finer particle size (<40 ${\mu}{\textrm}{m}$) was fully disproportionated on heating up to around 80$0^{\circ}C$ under hydrogen gas with normal pressure. The Ga-substituted alloy has a very sluggish recombination kinetics with respect to the alloy without Ga-substitution. The $Sm_2Fe_{17}C_{x-}$type carbide was stabilised significantly by the Ga-substitution for Fe in the parent alloy. While the $Sm_2Fe_{17}C_x$ was disproportionated below 80$0^{\circ}C$ the Ga-stabilised $Sm_2Fe_{14}Ga_2C_x$ carbide remained intact even on heating up to 80$0^{\circ}C$.

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Ferroelectric Properties of Substituted Aurivillius Phases SrBi2Nb2-xMxO9 (M=Cr, Mo)

  • Moon, S.-Y.;Choi, K. S.;Jung, K. W.;Lee, H.;Jung, D.
    • Bulletin of the Korean Chemical Society
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    • 제23권10호
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    • pp.1463-1482
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    • 2002
  • Partially doped Aurivillius phases SrBi2N$b_{2-x}M_xO_9$ (M=Cr and Mo) were successfully synthesized and characterized. The extent of the substitution was limited at ~20 mole % because of the size differences between $Nb^{5+}$ and $Cr^{6+}$, and between $Nb^{5+}$ and $Mo^{6+}$. When the amount of substitution exceeded ~20 mole%, the phases began to collapse and the second phases were made. The dielectric constants of substituted compounds were enlarged nevertheless Cr or Mo is substituted. The increment is bigger in the Mo substituted compound than in the Cr doped one although the Nb(Cr)$O_6$ octahedra could be more strongly distorted than the Nb(Mo)$O_6$ octahedra since the ionic size difference between $Nb^{5+}$ and of $Cr^{6+}$ is much bigger than that between $Nb^{5+}$ and $Mo^{6+}$. Consequently, the dielectric constant of the substituted Aurivillius phase $Bi_2$A_{n-1}B_{n-x}M_xO_{3n+1}$$ depends on the extent of distortion of the B$O_6$ octahedra and more strongly on the polarizability of the metal.

육계병아리 사육에 있어서 느타리버섯 재배 폐볏짚의 사료가치에 관한 연구 (Studies on Feed Value of Waste Rice Straws for Broiler Chicken)

  • 오세정;김법회;이택원;조성구
    • 한국가금학회지
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    • 제11권2호
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    • pp.115-125
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    • 1984
  • Broiler 사료에 있어서 밀기울 대신 느타리버섯재배 폐볏집을 대치하는 실험을 1,2차에 걸쳐 시험한 결과를 요약하면 다음과 같다. 1. 공시재료인 느타리버섯재배 폐볏짚의 조성분을 분석한 바 원료볏짚과 비교하면 조단백질은 1.5% 증가되었고, 조지방에는 큰 변화가 없었으나 가용 무질소물과 조섬유는 약 10%이상 감소를 보이고 있었다. 2. 증체량은 느타리버섯재배 폐볏짚으로 대치한 구가 대조구에 비해 더욱 빨리 증체하는 경향을 보였으며, 특히 4% 대치구와 유의성을 나타내고 있었다 (P<0.05). 3. 사료섭취량은 폐볏짚으로 대치한 구가 많이 섭취하였으나 처리구간에 유의성을 나타내지 않았다. 4. 사료효율에 있어서도 처리구간에 유의성은 없었다. 5. Amino 산의 조성에 있어서는 밀기울과 느타리버섯재배 폐볏짚과 비교한 바 methionine만이 0.01% 다량 함유되어 있었고 여타 amino산은 모두 소량 함유되어 있었다. 6. 폐볏짚의 사용량 증가를 위하여 6% 폐볏짚을 밀기울과 대치하고 메치오닌 혼합제를 첨가한 결과 증체량, 사료섭취량 및 사료효율에 있어서 유의성은 없으나 시험구가 대조구에 비하여 사료는 많이 섭취하고 사료효율은 낮아지는 경향을 보이고 있었다. 7. 경제성을 분석한 바 메치오닌 첨가구가 대조구에 비하여 kg당 생산원가 높아져 (P<0.01) 6%까지 대치함은 경제성이 없음을 인지하게 되었다. 따라서 1, 2차시험 결과로 볼 때 폐볏짚에 의한 밀기울 대치는 4%가 한계라고 사료된다.

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Fully Substituted Ethylene as a New Class of Highly Efficient Blue Emitting Materials for OLEDs

  • Park, Jong-Wook;Kim, Soo-Kang;Park, Young-Il;Kim, Kyoung-Soo;Choi, Cheol-Kyu;Lee, Sang-Do;Kim, Sang-Wook
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2006년도 6th International Meeting on Information Display
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    • pp.363-367
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    • 2006
  • We synthesized new blue and bluish green emitting materials by using fully substituted ethylene moieties. Multi-layered EL devices were fabricated with synthesized materials and evaluated in terms of emission color and luminescence efficiency. BPBAPE[EML 4] having high $T_g$ of $155^{\circ}C$ showed luminance and power efficiency of 10.33cd/A and 4.0 lm/W without any doping agent. BTBPPA[EML 5] exhibited 5cd/A and 1.67lm/W efficiency with blue CIE value of (0.165, 0.195).

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PZT 특성에 미치는 부조물의 영향(II) (Effects of Impurity on Properties of PZT(II))

  • 임응극;정수진;유강수
    • 한국세라믹학회지
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    • 제20권3호
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    • pp.227-235
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    • 1983
  • The dielectric and piezoelectic properties in which $(Zr_{0.52} Ti_{0.48})^{+4}$ ions of $Pb(Zr_{0.52} Ti_{0.48})O_3$ are partially substituted for $W^{+6}$ ions were studied. $ZrTiO_4$ was made by coprecipitation. The specimens of disc shape were sintered respectively at 1180$^{\circ}$to 130$0^{\circ}C$ at an intervals of 2$0^{\circ}C$ for 1 hour. The optimum sintering temperature were found to be between 126$0^{\circ}C$ and 128$0^{\circ}C$. PZT solid solutions sintered had the tetragonal structure with c/a=1.025$\pm$0.005 and theoretical densities incre-ased from 8.02 to 8.17g/cm3 with increasing the amount of the partial substitution of $(Zr_{0.52} Ti_{0.48})^{+4}$ ion for $W^{+6}$ ion The grain size and curie temperature decreased with increasing the amount of $WO_3$ while the dielectric constant increased. When $(Zr_{0.52} Ti_{0.48})^{+4}$ ion was substituted for 1 mole% of $W{+6 ]$ion the planar coupling coefficient$(K_P)$ was as high as 0.58 But as the amount of $WO_3$ increased the mechanical quality factor(Qm) decreased considerably.

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