• 제목/요약/키워드: W 치환

검색결과 258건 처리시간 0.022초

나노다공성 실리카 에어로겔 과립의 간단 제조 (Facile Preparation of Nanoporous Silica Aerogel Granules)

  • 김남현;황하수;박인
    • 공업화학
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    • 제22권2호
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    • pp.209-213
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    • 2011
  • 낮은 열전도율, 높은 비표면적과 기공률을 갖는 소수성 실리카 에어로겔 과립을, 저가의 물유리를 실리카 전구체로 사용하고 상압건조하여 제조하였다. 별도의 과립화 첨가제 및 과립화 기구를 사용하지 않고, 산도(~5)를 변화시켜 모노리스 형태의 습윤겔을 먼저 제조하여, 용매치환/소수성화 동시공정과 상압건조공정 과정에서 습윤겔이 깨져 0.5~2 mm 크기의 과립형태 실리카 에어로겔을 제조하였다. 제조된 실리카 에어로겔 과립은 비표면적, 평균기공크기, 기공부피가 각각 $593m^2/g$, 34.9 nm, $4.4cm^3/g$으로 실리카 에어로겔 분말과 거의 유사한 다공도를 가지고 있으며, 열전도율도 $20^{\circ}C$에서 19.8 mW/mK으로 나타나 같은 조건에서 제조된 실리카 에어로겔 분말과 거의 같은 단열성을 나타내었다.

모래다짐말뚝의 원심모델링 (Centrifugal Modeling of Sand Compaction Pile)

  • 유남재;정길수;김상진;채승호
    • 산업기술연구
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    • 제21권B호
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    • pp.187-193
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    • 2001
  • This paper is results of extensive centrifuge model experiments about design factors influencing the bearing capacity and the settlement behaviors of SCP (Sand Compaction Pile). Centrifuge model tests were carried out changing design factors for SCP method such as replacement area ratio (as= 20, 40, 70%), improvement ratio to footing width (W/B = 1, 2, 3), and amount of fines in sand pile (#200 = 5, 10, 15). Therefore, the effects of these design factors on the bearing capacity and the settlement behavior of SCP were investigated and changes of stress concentratio rato due to such an design factors were also investigated. Centrifuge model testing technique for preparing and installing centrifuge model of sand compaction pile, using freezing them, was also developed. As results of centrifuge model tests, more fines in sand compaction pile increases the bearing capacity of SCP. Optimum improvement ratio to footing width was found to be 2. Values of stress concentration ratio was in the ranges of 1.5 - 3.5. The depth of bulging in sand piles was found in the range of 2.0 - 2.5 times of pile diameter.

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모래다짐말뚝으로 개량된 연약지반의 응력분담특성 (Stress Concentration Characteristics of Soft Ground Treated by Sand Compaction Pile)

  • 유남재;박병수;정길수;김상진
    • 산업기술연구
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    • 제22권A호
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    • pp.145-151
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    • 2002
  • This paper is results of extensive centrifuge model experiments about design factors influencing the bearing capacity and the settlement behaviors of SCP (Sand Compaction Pile). Centrifuge model tests were carried out changing design factors for SCP method such as replacement area ratio (as= 20, 40, 70%), Improvement ratio to footing width (W/B = 1, 2, 3), and amount of fines m sand pile (#200 = 5, 10, 15). Therefore, the effects of these design factors on the bearing capacity and the settlement behavior of SCP were investigated and changes of stress concentratio rato due to such an design factors were also investigated. Centrifuge model testing technique for preparing and installing centrifuge model of sand compaction pile, using freezing them, was also developed. As results of centrifuge model tests, more fines in sand compaction pile increases the bearing capacity of SCP. Optimum improvement ratio to footing width was found to be 2. Values of stress concentration ratio was in the ranges of 1.5 - 3.5. The depth of bulging in sand plies was found in the range of 2.0 - 2.5 times of pile diameter.

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Ba 치환에 따른 PMW-PNN-PZT 세라믹스의 압전 및 전계유기왜형 특성 (Piezoelectric and Electric Field Induced Strain Properties of PMW-PNN-PZT Ceramics with the Substitution of Ba)

  • 윤광희;김규수;최병수
    • 한국전기전자재료학회논문지
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    • 제14권1호
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    • pp.20-25
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    • 2001
  • To develop the piezoelectric actuator, the structural, dielectric and piezoelectric properties and electric fieldinduced strain of the ceramics(Pb$\_$1-2/Ba$\_$x/)[Mg$\_$1/2/W$\_$1/2/)$\_$0.03/-Ni$\_$1/3/Nb$\_$2/3/)$\_$0.12/-(Zr$\_$0.5/Ti$\_$0.5/)$\_$0.85/]O$_3$(x=0, 0.01, 0.03, 0.05, 0.07, 0.1) were investigated with the substitution of Ba. The tetragonality of crystal structure and grain size decreased by the substitution of Ba. Curie temperature decreased due to the decrease of the tetragonality, and dielectric constants increased with the substitution of Ba. The coercive field, remnant polarization and electromechanical coupling factor also decreased, whereas the piezoelectric constatns d$\_$33/ and d$\_$31/ were showed the highest value of 430 and 209(x10$\^$-12/C/N), respectively, because of the increase of dielectric constant. The strain induced by 60Hz AC electric field had the maximum value of 204x10$\^$-6/Δℓ/ℓ at the substitution of Ba 3mol%. As the applied electric field approaches to the coercive field, the piezoelectric element is depolarized and the electric field induced strain revealed non-linearity.

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전기로슬래그 잔골재를 사용한 콘크리트의 황산염침식 저항성에 관한 연구 (A Study on the Sulfate Attack Resistance of Concrete Using EAF Slag as Fine Aggregate)

  • 박문석;김영수
    • 한국건축시공학회지
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    • 제9권1호
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    • pp.81-87
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    • 2009
  • The purpose of this study is to investigate the sulfate attack resistance of concrete using the EAF(electric arc furnace) Slag as fine aggregate. In order to figure out the effects of magnesium sulfate solution on the durability of concrete using the EAF Slag as fine aggregate, the experiments for the immerging test in the 10% magnesium sulfate solution was executed by selecting factors such as aging processes, replacement ratio(0, 10, 20, 30, 50%), and duration of immerging. The specimens were made with various EAF slag replacements for fine aggregates and with W/C ratio fixed 0.45. compressive strength and S.D.F(Sulfate Deterioration Factor), weight change, and SEM(Scanning Electron Microscope) were tested. From the test results, EAF slag aggregate treated with accelerated aging is better than treated with air aging. The compressive strength and resistance to the sulfate attack is slightly improved with an increase in the EAF slag aggregate treated with accelerated aging replacement for aggregate.

조기강도 발현형 AE감수제를 사용한 콘크리트의 혼화재 치환방법 변화에 따른 초기 강도발현 특성 (Properties of Early Strength Development according to the Replacing Method of Admixture of Concrete Using AE Water Reducing Agent of Early-Strength Type)

  • 황인성;우종완;김규동;이승훈;한천구
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2003년도 가을 학술발표회 논문집
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    • pp.269-272
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    • 2003
  • This study is intended to investigate the properties of concrete using AE Water Reducing Agent of Early-Strength Type. According to the results, as for the replacing method of mineral admixture, setting time is shortened faster in order of replacement for fine aggregate, combination and replacement for cement, and when AE Water Reducing Agent of Early-Strength Type is used, it is shortened by about 4 hours, compared with normal AE Water Reducing Agent Compressive strength is lower in the case of replacement for fine aggregate, but higher in the other case than that of plain concrete. And When AE Water Reducing Agent of Early-Strength Type is used, early compressive strength is very high in comparison to normal AE Water Reducing Agent. Early strength development is very favorable by the use of AE Water Reducing Agent of Early-Strength Type regardless of the replacing method of mineral admixture at $20^{\circ}C$, but at $l0^{\circ}C$, it is effective for Early strength development that W/B is lowered to below 45%, BS of 20% is replaced for fine aggregate, and AE Water Reducing Agent of Early-Strength Type is used.

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토양(土壤)의 이화학적(理化學的) 특성(特性)과 대나무 생장(生長)과의 관계(關係) (Relationships between Soil-Site Properties and Bamboo (Phyllostachys bambusoides) Growth)

  • 정영관
    • 한국산림과학회지
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    • 제79권1호
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    • pp.16-20
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    • 1990
  • 17개(個)의 토양인자(土壤因子)와 대나무의 직경(直徑), 간고(稈高) 그리고 절간(節間) 생장량(生長量)과의 관계(關係)를 구명(究明)하기 위하여 정준상관분석(正準相關分析)을 실시(實施)하였다. 첫번째 정준상관(正準相關)은 매우 유의적(有意的) 이었고, 변수(變數)의 2조합(組合)에서 분산(分散)은 크고, 그리고 정준변량(正準變量)은 생물학적(生物學的)으로 의의(意義)가 있었다. 따라서 표층토심(表層土深), 전질소(全窒素) 그리고 유기물함량(有機物含量)등은 첫번째 토양성질(土壤性質)의 정준변량(正準變量)과 매우높은 정(正)의 상관(相關)을 나타내었다. 그리고 점토함량(粘土含量)과 치환성용량(置煥性容量)은 부(負)의 상관(相關)으로 나타났다. 17개(個) 변수(變數) 가운데 8개(個) 변수(變數)만이 대나무의 생장(生長)을 예측(豫測)하는데 관계(關係)되는 것으로 사료(思料)된다.

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CeMnO3가 치환된 저온소결 PMW-PNN-PZT 세라믹스의 유전 및 압전 특성 (Dielectric and Piezoelectric Properties of Low Temperature Sintering PMW-PNN-PZT Substituted with CeMnO3)

  • 김용진;류주현
    • 한국전기전자재료학회논문지
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    • 제28권3호
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    • pp.160-164
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    • 2015
  • In this study, $(1-x)Pb(Mg_{1/2}W_{1/2})_{0.03}(Ni_{1/3}Nb_{2/3})_{0.09}(Zr_{0.5}Ti_{0.5})_{0.88}O_3+xCeMnO_3$ (x= 0~0.02) ceramics were prepared by Columbite precursor method. The phase structure, ferroelectric and piezoelectric properties were systematically investigated. It was found that PMW-PNN-PZT possessed superior electrical properties due to its composition close to the MPB (morphotropic phase boundary). Coercive electric field of 10.05 [kV/cm] and density of 7.88 [$g/cm^3$] were obtained when the substitution amount of $CeMnO_3$ is x=0.02. In contrast, specimens with x=0.01 showed the mechanical quality factor($Q_m$) of 1,091 and the electromechanical coupling factor($k_p$) of 0.613.

혼합재 치환율에 따른 경량소재의 물리적 특성 (Physical Properties of Lightweight Materials According to the Replacement Ratios of the Admixture)

  • 정연조;추용식;이종규;송훈
    • 한국세라믹학회지
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    • 제46권6호
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    • pp.633-638
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    • 2009
  • Lightweight materials were fabricated using glass abrasive sludge, bottom ash and slag powder in this study. This study tried to draw the correlation between physical properties and internal pore of lightweight material. The content of bottom ash and slag powder was from 10% to 50% and firing temperature from $760{^{\circ}C}\;to\;800{^{\circ}C}$ in rotary kiln. The lightweight material containing bottom ash or slag powder had a specific gravity of $0.21{\sim}0.70$ at particle size $2{\sim}4$ mm. Replacement ratio of the admixture increasing with specific gravity increased. Fracture strength of panel made with various lightweight materials was $32{\sim}55\;kgf/cm^2$ and flexural strength was $11{\sim}18\;kgf/cm^2$. Fracture strength increased by 72% and flexural strength was 63% compared with reference. Thermal conductivities of panel was $0.07{\sim}0.11W/m{\cdot}k$. The water absorption ratios of panel with lightweight materials containing bottom ash were $1.8{\sim}2.8$% and slag powder were $2.65{\sim}2.8$%. Excellent results on resistant of water absorption.

이규화몰리브덴 고온발열체의 제조에 관한 연구 (Fabrication of $\textrm{MoSi}_2$ Heating Elements)

  • 김원백;심건주;장대규;서창열
    • 한국재료학회지
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    • 제7권9호
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    • pp.763-771
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    • 1997
  • 이규화몰리브덴 고온발열체의 제조공정을 개발하였다. 원료분말은 상용 MoSi$_{2}$분말이었으며 Bentonite, Si$_{3}$N$_{4}$, B, ThO$_{2}$를 각각 가소제와 첨가제로 사용하였다. 이들은 진공압출, 소결, 단자부 기계가공, U자형 성형, 용접 등의 과정을 거쳐 U자형 발열체로 제조되었다. 사용제품의 분석결과 최근 사용온도가 크게 증가된 것으로 알려진 190$0^{\circ}C$용 발열체는 다량(33wt%)의 W이 Mo을 치환하고 있는 것으로 나타났다. 발열체의 전기비저항은 겉보기 밀도가 증가함에 따라 급격하게 감소하는 경향을 보였으며 첨가물들의 영향은 미미하였다. 1400-1$600^{\circ}C$에서 용접한 경우 용접면에서의 전기비저항은 비용접부보다 낮았으며 용접온도가 증사함에 따라 감소하였다. 발열시험결과 제조된 발열체는 표면온도가 1$700^{\circ}C$이하에서는 문제가 없었으며 175$0^{\circ}C$ 이상의 온도에서는 원형의 융기가 표면에 발생하면서 급속하게 파괴되었다. 이 융기는 X-선 회절분석결과 SiO로 밝혀졌으며 따라서 발열체의 파괴는 MoSi$_{2}$/SiO$_{2}$계면에서의 Si(in MoSi$_{2}$) + SiO$_{2}$=2SiO(g)반응에 으해 일어나는 것으로 판단된다.

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