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Synthesis of cobalt powder with polyol process (폴리올법을 이용한 미립 코발트 분말 합성)

  • Kim, Dong-Jin;Chung, Hun-Saeng;Woo, Sang-Duck;Lee, Jae-Jang
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.11 no.6
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    • pp.290-296
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    • 2001
  • Fin metal particles of uniform shape, narrow size distribution and high purity are increasingly needed for specific uses in high tech industrial applications. Polyol process for the preparation of monodispersed cobalt powders in micron size is described. In this process in inorganic precursor is reduced in liquid polyol under controlled conditions. The reducing agent is the polyol itself and reaction parameters such as the traction temperature, reaction time, addition of protective agent and concentration of the precursor are varied for controling particles size, shape and agglomeration of the metal particles. An optimum synthesis condition was achieved at E.G/DiE/G volume ratio 1:4,Co$(OH)_{2}$polyol molar ratio 0.08~0.32 reaction temperature $210^{\circ}C$, PVP/Co$(OH)_{2}$ molar ratio 0.4.

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Application of Geophysical Prospecting to Site Assessment of Waste Landfill (매립지 오염평가를 위한 물리탐사의 적용사례)

  • Lee, Cheol-Hyo;Park, Sam-Gyu
    • 한국지구물리탐사학회:학술대회논문집
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    • 2001.09a
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    • pp.104-121
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    • 2001
  • Recently, the pollution of soil and groundwater becomes a serious social problem, and geophysical exploration methods have been introduced as a remedial investigation method of subsurface. Digital technologies such as personal computer have revolutionized our ability to acquire large volume of data in a short term, and to produce more reliable results for subsurface image. Also, color graphics easily visualizes the survey results in a more understandable manner, and it is widely used for not only characterizing the contaminated subsurface but also monitoring contaminant and remedial process. In this paper, electrical resistivity and electromagnetic (EM) surveys were carried out in order to understand characteristics of waste landfills, and the applicability of geophysical prospecting to site assessment of waste landfill was also tested. According to the result, electrical resistivity and electromagnetic (EM) surveys were effective in estimating distribution of the leachate plume.

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Fabrication of 13Cr-1.5Nb-Fe Alloy Powder and AC Magnetic Properties of the Sintered Magnetic Core (소결 13Cr-1.5Nb-Fe 합금의 교류 자기 특성)

  • 오환수;김택기;조용수
    • Journal of the Korean Magnetics Society
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    • v.10 no.1
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    • pp.11-15
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    • 2000
  • 13Cr-1.5Nb-Fe alloy powder prepared by water atomizing method is reduced with flowing hydrogen gas. The characteristics of a reduced alloy powder is investigated and magnetic cores formed by using the reduction power sintered in the vacuum of ∼10$\^$-5/ Torr. In order to study on the magnetic cores permeability and power loss in alternating magnetic field are also measured. The result of particle size distribution shows the paticle size is 70 ㎛ at volume fraction of 50 %. The saturation magnetization of the reduced alloy powder is 160 emu/g. The relative peak permeability (H$\_$a/=5Oe) of a magnetic core is 400 and the power loss (B$\_$m/=80G) 0.12 mW/cc at sintering temperature of 1,200 $\^{C}$, 10 ton/㎠ forming pressure, and 1 kHz.

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Separation of Radionuclide from Dismantled Concrete Waste (해체 콘크리트 폐기물로부터 방사성핵종 분리)

  • Min, Byung-Youn;Park, Jung-Woo;Choi, Wang-Kyu;Lee, Kune-Woo
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.7 no.2
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    • pp.79-86
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    • 2009
  • Concrete materials in nuclear facilities may become contaminated or activated by various radionuclides through different mechanism. Decommissioning and dismantling of these facilities produce considerable quantities such as concrete structure, rubble. In this paper, the characteristics distribution of the radionuclide have been investigated for the effects of the heating and grinding test for aggregate size such as gravel, sand and paste from decommissioning of the TRIGA MARK II research reactor and uranium conversion plant. The experimental results showed that most of the radionuclide could be removed from the gravel, sand aggregate and concentrated into a paste. Especially, we found that the heating temperature played an important role in separating the radionuclide from the concrete waste. Contamination of concrete is mainly concentrated in the porous paste and not in the dense aggregate such as the gravel and sand. The volume reduction rate could be achieved about 80% of activated concrete waste and about 75% of dismantled concrete waste generated from UCP.

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Examination on Liquid Pool Fire Extinguishment Performance of Twin-fluid Nozzle (2유체노즐의 액체풀 화재 소화 성능에 대한 검토)

  • Jeong, Chan Seok;Lee, Chi Young
    • Fire Science and Engineering
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    • v.31 no.4
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    • pp.59-64
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    • 2017
  • In the present experimental study, the liquid pool fire extinguishment performance of twin-fluid nozzle was preliminarily examined. For the liquid pool fire, the ethanol of 1200 ml (volume) was prepared, and two kinds of air flow rate conditions (40 l/min and 70 l/min) were tested at the constant water flow rate condition of 632 ml/min. In the present experimental ranges, the fire extinguishment experiments were carried out using the twin-fluid nozzle and its spray characteristics (i.e., SMD (Sauter Mean Diameter) and flow distribution) were investigated. As a result, at the higher air flow rate, the liquid pool fire was extinguished quickly and successfully, which was discussed using the visualization and spray characteristics of twin-fluid nozzle. In addition, through the comparison with some of previous results, it was found that potentially, the twin-fluid nozzle can extinguish the liquid pool fire under the smaller water flow rate condition, as compared with the single-fluid nozzle.

The simulation study on natural circulation operating characteristics of FNPP in inclined condition

  • Li, Ren;Xia, Genglei;Peng, Minjun;Sun, Lin
    • Nuclear Engineering and Technology
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    • v.51 no.7
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    • pp.1738-1748
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    • 2019
  • Previous research has shown that the inclined condition has an impact on the natural circulation (natural circulation) mode operation of Floating Nuclear Power Plant (FNPP) mounted on the movable marine platform. Due to its compact structure, small volume, strong maneuverability, the Integral Pressurized Water Reactor (IPWR) is adopted as marine reactor in general. The OTSGs of IPWR are symmetrically arranged in the annular region between the reactor vessel and core support barrel in this paper. Therefore, many parallel natural circulation loops are built between the core and the OTSGs primary side when the main pump is stopped. and the inclined condition would lead to discrepancies of the natural circulation drive head among the OTSGs in different locations. In addition, the flow rate and temperature nonuniform distribution of the core caused by inclined condition are coupled with the thermal hydraulics parameters maldistribution caused by OTSG group operating mode on low power operation. By means of the RELAP5 codes were modified by adding module calculating the effect of inclined, heaving and rolling condition, the simulation model of IPWR in inclined condition was built. Using the models developed, the influences on natural circulation operation by inclined angle and OTSG position, the transitions between forced circulation (forced circulation) and natural circulation and the effect on natural circulation operation by different OTSG grouping situations in inclined condition were analyzed. It was observed that a larger inclined angle results the temperature of the core outlet is too high and the OTSG superheat steam is insufficient in natural circulation mode operation. In general, the inclined angle is smaller unless the hull is destroyed seriously or the platform overturn in the ocean. In consequence, the results indicated that the IPWR in the movable marine platform in natural circulation mode operation is safety. Selecting an appropriate average temperature setting value or operating the uplifted OTSG group individually is able to reduce the influence on natural circulation flow of IPWR by inclined condition.

On the Derivation of Safety Requirements and Specifications based Integrated System Operation Scenario for the Development of Unmanned Courier Storage Device Platform in Urban Areas

  • Lee, Sang Min;Park, Jae Min;Kim, Joo Uk;Kim, Young Min
    • International Journal of Internet, Broadcasting and Communication
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    • v.13 no.4
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    • pp.103-111
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    • 2021
  • In modern society, digital lifestyles are spreading to minimize contact with people and to receive contactless information. The spread trend has established an unmanned distribution system in which transactions through contactless technologies such as kiosks and chatbots are activated in face-to-face transactions with sellers and consumers. In order to streamline logistics supply worldwide, digital new deal based joint logistics hubs, unmanned courier storage platforms, and fresh logistics based last mile services have been developed into unmanned logistics systems, focusing on the intelligent logistics system automation process. Unmanned courier storage system installed in urban areas and home to daily logistics where volume is concentrated are provided with fresh logistics services through cold chain and receiving freights in contactless environments. Development is also underway to minimize safety accidents caused by courier services, such as managing various information based on the integrated control system. This paper defines the concept of integrated operation for the development of a platform for contactless unmanned courier storage device developed into next-generation logistics system. In addition, we intend to develop systems engineering-based output for deriving safety requirements and specifications by identifying risk sources that may occur in the operational scenario. Therefore, the goal is to establish a foundation for safety and reliability between interfaces of logistics systems to be installed in apartment and subway station environments that want to provide unmanned logistics services to various consumers.

Aerodynamic and Aeroelastic Tool for Wind Turbine Applications

  • Viti, Valerio;Coppotelli, Giuliano;De Pompeis, Federico;Marzocca, Pier
    • International Journal of Aeronautical and Space Sciences
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    • v.14 no.1
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    • pp.30-45
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    • 2013
  • The present work focuses on the unsteady aerodynamics and aeroelastic properties of a small-medium sized wind-turbine blade operating under ideal conditions. A tapered/twisted blade representative of commercial blades used in an experiment setup at the National Renewable Energy Laboratory is considered. The aerodynamic loads are computed using Computational Fluid Dynamics (CFD) techniques. For this purpose, FLUENT$^{(R)}$, a commercial finite-volume code that solves the Navier-Stokes and the Reynolds-Averaged Navier-Stokes (RANS) equations, is used. Turbulence effects in the 2D simulations are modeled using the Wilcox k-w model for validation of the CFD approach. For the 3D aerodynamic simulations, in a first approximation, and considering that the intent is to present a methodology and workflow philosophy more than highly accurate turbulent simulations, the unsteady laminar Navier-Stokes equations were used to determine the unsteady loads acting on the blades. Five different blade pitch angles were considered and their aerodynamic performance compared. The structural dynamics of the flexible wind-turbine blade undergoing significant elastic displacements has been described by a nonlinear flap-lag-torsion slender-beam differential model. The aerodynamic quasi-steady forcing terms needed for the aeroelastic governing equations have been predicted through a strip-theory based on a simple 2D model, and the pertinent aerodynamic coefficients and the distribution over the blade span of the induced velocity derived using CFD. The resulting unsteady hub loads are achieved by a first space integration of the aeroelastic equations by applying the Galerkin's approach and by a time integration using a harmonic balance scheme. Comparison among two- and three- dimensional computations for the unsteady aerodynamic load, the flap, lag and torsional deflections, forces and moments are presented in the paper. Results, discussions and pertinent conclusions are outlined.

Comparative Study on Reliability-Based Topology Optimization (신뢰성 기반 위상최적화에 대한 비교 연구)

  • Cho, Kang-Hee;Hwang, Seung-Min;Park, Jae-Yong;Han, Seog-Young
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.20 no.4
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    • pp.412-418
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    • 2011
  • Reliability-based Topology optimization(RBTO) is to get an optimal design satisfying uncertainties of design variables. Although RBTO based on homogenization and density distribution method has been done, RBTO based on BESO has not been reported yet. This study presents a reliability-based topology optimization(RBTO) using bi-directional evolutionary structural optimization(BESO). Topology optimization is formulated as volume minimization problem with probabilistic displacement constraint. Young's modulus, external load and thickness are considered as uncertain variables. In order to compute reliability index, four methods, i.e., RIA, PMA, SLSV and ADL(adaptive-loop), are used. Reliability-based topology optimization design process is conducted to obtain optimal topology satisfying allowable displacement and target reliability index with the above four methods, and then each result is compared with respect to numerical stability and computing time. The results of this study show that the RBTO based on BESO using the four methods can effectively be applied for topology optimization. And it was confirmed that DLSV and ADL had better numerical efficiency than SLSV. ADL and SLSV had better time cost than DLSV. Consequently, ADL method showed the best time efficiency and good numerical stability.

The Range of Physicochemical Parameters for the Active Ingredients of Fungicides and Insecticides as Crop Protection Agents (작물 보호제로서 살균제와 살충제의 활성 성분에 대한 물리-화학 파라미터의 범위)

  • Song, Sun-Sup;Sung, Nack-Do
    • Applied Biological Chemistry
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    • v.46 no.4
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    • pp.280-284
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    • 2003
  • To develope of diagnosis and estimation system for utility of fungicides and insecticides as crop protection agents, various 10 physicochemical parameters, hydrophobicity (LogP), dipole moment (DM), HOMO energy, LUMO energy, molar refractivity $(MR:\;cm^3/mol)$, polarizability $(Pol:\;A^3)$, van der Waals molecular surface area $(A^2)$, van der Waals molecular volume $(Vol:\;cm^3)$, molecular weight (amu), hydration energy (Kcal/mol) for the active ingredients of 133 fungicides and 152 insecticides were calculated. And then the distribution ranges for each of the physicochemical parameters in fungicides, sterol biosynthesis inhibitors (DMI: demethylation inhibitor), insecticides and acetylcholine esterase inhibitors (AChE) were confirmed. It is suggested that the various compounds based on the range of the physicochemical parametes could be predicted for possibilities as fungicides and insecticides.