• 한국수자원학회논문집
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• 제33권1호
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• pp.73-85
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• 2000

농촌 소하천의 수리학적 및 수질특성을 반영한 모형을 개발하였다. 모형구조 설계시 제어체적 기법을 활용하여 하천 형상, 수질 및 유량의 변화가 심한 농촌 유역의 소하천에 대한 수질의 모의하였다. 개발한 모형에 난수발생기법을 도입하여 최적 반응계수와 모형구조를 추정하였다. 또한 모형 보정기준의 일반화를 위해 동의지표와 효율계수를 도입하여 매개변수추정의 신뢰성 향상을 도모했다. 모형의 적용성을 검증하기 위해 경남 김해시 한림면 용덕천에서 수질을 채취하여 분석하였다. 관측된 자료와 개발된 모형의 비교연구를 통해 대상유역의 소하천에서 일어나는 수질 반응계수들과 그 변동성을 추정하였다.

• Asian Journal of Atmospheric Environment
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• 제11권1호
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• pp.54-60
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• 2017

Quantifying the trace elements in infinitesimal ambient liquid samples (e.g., single raindrop, cloud/fog water, and the soluble fraction extracted from the particles collected for a short time) is an important task for understanding formation processes, heating/cooling rates, and their health hazards. The purpose of this study is to employ an in-air micro PIXE system for quantitative analysis of the trace elements in a thimbleful of reference liquid sample. The bag type liquid sample holder originally designed with $10{\mu}m$ thick $Mylar^{(R)}$ film retained the original shape without any film perforation and apparent peaks of film blank by the end of the analysis. As one of tasks to be solved, the homogeneity of the elemental distribution in liquid reference species was verified by the X-ray line profiles for several references. It was possible to resolve the significant peaks for whole target elements corresponding to the channel number of micro-PIXE spectrum. The calibration curves for the six target elements (Si, S, Cl, Fe, Ni, and Zn) in standard solutions were successfully plotted by concentration (ppm) and ROI of interest net counts/dose (nC).

• Natural Product Sciences
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• 제20권3호
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• pp.182-190
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• 2014

An ultra-performance liquid chromatography (UPLC) coupled with electrospray ionization (ESI) tandem mass spectrometry (MS) method was established for quantitative analysis of twelve components, allantoin (1), morroniside (2), 5-hydroxymethyl-2-furfural (5-HMF) (3), loganin (4), coumarin (5), cinnamic acid (6), mesaconitine (7), cinnamaldehyde (8), hypaconitine (9), aconitine (10), alisol B (11), and alisol B acetate (12) in a Palmijihwang-hwan decoction. The twelve constituents were separated on a UPLC BEH C18 column ($2.1{\times}100mm$, $1.7{\mu}m$) at a column temperature of $40^{\circ}C$ by gradient elution with 0.1% (v/v) formic acid in water and acetonitrile as the mobile phase. The flow rate was 0.3 mL/min and the injection volume was $2.0{\mu}L$. Calibration curves of all compounds were acquired with values of the correlation coefficient ${\geq}0.99$ within the test ranges. The limits of detection and quantification for all analytes were 0.01 - 4.53 ng/mL and 0.03 - 13.60 ng/mL, respectively. The concentrations of the compounds 1 - 9 and 12 were 72.83, 4389.00, 4859.00, 3155.17, 223.67, 33.50, 1.97, 518.00, 2.25, and $25.00{\mu}g/g$, respectively. However, compounds 10 and 11 were not detected.

• 한국물환경학회지
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• 제23권6호
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• pp.807-813
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• 2007

Settling velocity is one of major parameters determining algal biomass in water quality modeling. In this study, the settling velocity of phytoplankton was measured in reservoir and stream sites of the Nakdong River, Korea. Settling velocities of various phytoplankton species were determined by measuring algal cell biomass settled in a sedimentation cylinder. Mean settling velocities were $0.22m\;day^{-1}$ in reservoir sites and $0.33m\;day^{-1}$ in stream sites, which were relatively higher compared with other default values suggested by water quality models (e.g. $0.1m\;day^{-1}$ in CE-QUAL-W2). The lower settling velocity in reservoirs than in stream implies the adaptation of phytoplakton to low turbulence in lentic environments. Cyanobacteria showed lower settling velocity ($0.2m\;day^{-1}$) than diatoms ($0.3m\;day^{-1}$), and this phenomenon may have resulted from buoyancy mechanisms of cyanobacteria. Cell volume did not show a significant correlation with settling velocity in this study, implying that conformation factors of colonies or other factors had large effects on settling velocity of algal cells as well as cell size. The result of this study may suggest proper coefficients of settling velocity of phytoplankton in the calibration of water quality model.

• 한국연초학회지
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• 제22권1호
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• pp.91-98
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• 2000

This study was carried out to evaluate the uncertainty in the analysis of menthol content from the mentholated cigarette. Menthol in the sample cigarette was extracted with methanol containing an anethole as an internal standard, and then analyzed by gas chromatography. As the sources of uncertainty associated with the analysis of menthol, were the following points tested, such as the weighing of sample, the preparation of extracting solution, the pipetting of extracting solution into the sample, the preparation of standard solution, the precision of GC injections for standard & sample solution, the GC response factor of standard solution, the reproducibility of menthol analysis, and the determination of water content in tobacco, etc. For calculating the uncertainties, type A of uncertainty was evaluated by the statistical analysis of a series of observation, and type B by the information based on supplier's catalogue and/or certificated of calibration. Sources of uncertainty were subsequently included and mathematically combined with the uncertainty arising from the assessment of accuracy to provide the overall uncertainty. It was shown that the main source of uncertainty came from the errors in the reproducibility of menthol and water determination, the purity of menthol reference material in the preparation of standard solution, and the precision of GC injections for sample solution. The errors in sample weighing and volume measurement contributed relatively little to the overall uncertainty. The expanded uncertainty in the mentholated cigarettes, Korean and American brand, at 0.95 level of statistical confidence was $\pm$0.06 and $\pm$0.07 mg/g for a menthol content of 1.89 and 2.32 mg/g, respectively.

• 한국수자원학회논문집
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• 제34권3호
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• pp.209-216
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• 2001

개발등 인위적 건설활동에 의하여 발생되는 토사유출량을 산정하기 위하여 국내에서는 주로 범용토양손실공식(USLE)을 주로 사용하여 왔으나 이 기법은 연평균 토사생산량을 산정하기위한 기법으로 개발되었다. 따라서 l본 연구에서는 단일호우에 대한 토사유출향 산정을 목적으로 개발된 수정범용토양손실공식(MUSLE)을 강우자료와 토사유출 실측값이 있는 국내 개발현장에 적용하여 실측치와 계산치를 비교함으로써 그 적용가능성을 확인하였으며 MUSLE 적용시 필요한 첨두유출량과 총유출량 산정기법 중 국내여건에 적합한 산정기법도 제시하였다. 또한 MUSLE 적용결과와 개정범용토양손실공식(RUSLE)을 이용한 토사유출량 산정 결과와도 비교하였다.

• 분석과학
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• 제8권3호
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• pp.313-319
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• 1995

표면강화 라만분광학을 이용하여 단일전자 산화반응으로 형성된 발암성 벤조피렌 유도체가 nucleobase와 반응하여 생성된 첨가 생성물을 분석하였다. 표면강화 라만분광학을 이용하여 아데닌 또는 구아닌과 같이 각기 다른 종류의 nucleobase와 결합하여 형성된 첨가생성물을 구분하여 분석할 수 있었고 또한 nucleobase 분자의 다른 부분에 결합하여 형성된 이성길체를 라만분광스펙트럼을 통하여 구분하여 분석이 가능하였다. N7Ade-BP에 대한 검정곡선의 선형도 범위는 20 picogram/${\mu}l$에서 800 nanogram/${\mu}l$였고, 본 실험 조건하에서의 검출한계는 $20{\mu}l$의 샘플을 이용하고 20 picogram/${\mu}l$였다.

• 한국압력기기공학회 논문집
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• 제7권3호
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• pp.40-47
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• 2011

KSNPs(Korea Standard Nuclear Power Plant) have been applied the break exclusion criteria to the high energy lines passing through containment penetration area to ensure that piping failures would not cause the loss of containment isolation function, and to reduce the resulting dynamic effects. Systems with the criteria are the Main Steam system, Feed Water system, Steam Generator Blowdown system, and Chemical & Volume Control system. In accordance with FSAR(Final Safety Analysis Report), a 100% volumetric examination by augmented in-service inspection of all pipe welds appled the break exclusion criteria is required for the break exclusion application piping. However, it is difficult to fully satisfy the requirements of inspection because 12", 8" and 6" weldolet weldments of Main Steam pipe line have complex structural shapes. To resolve the difficulty on the application of conventional UT(Ultrasonic Testing) technique, realistic mock-ups and UT calibration blocks were made. Simulations of conventional UT were performed utilizing CIVA, a commercial NDE(Nondestructive Examination) simulation software. Phased array UT experiments were performed through mock-up including artificial notch type flaws. A phased array UT technique is finally developed to improve the reliability of ultrasonic test at main steam line pipe to 12", 8" and 6" branch connection weld.

• 한국동물위생학회지
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• 제34권3호
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• pp.285-289
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• 2011

This study was conducted to determine the content of non-steroidal anti-inflammatory drugs (NSAIDs) in meats available on the Korean markets. The analysis was carried out using following conditions; C18 column ($100{\times}2.1$ mm, 1.7 ${\mu}m$), mobile phase composed of DW (containing 0.1% formic acid): acetonitrile (containing 0.1% formic acid), binary pump at a flow rate of 0.3 ml/min and 5 ${\mu}l$ of injection volume, MS/MS detector with ESI positive mode. The calibration range of five NSAIDs showed linearity ($r^2{\geq}0.99$) at concentration range of 3.125~200 ${\mu}g$/kg. The recoveries in fortified muscle more than 78.7~100.3%. The detection limits for meloxicam, ketoprofen, flunixin, carprofen and tolfenamic acid were 3.5, 1.6, 1.7, 9.8 and 4.8 ${\mu}g$/kg, respectively. We also monitored NSAIDs residue in cattle muscle 51 samples. The test results, NSAIDs were all not founded.

• Journal of Radiation Protection and Research
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• 제37권3호
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• pp.146-148
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• 2012

The use of GEANT4 simulation toolkit has increased in the radiation medical field for the design of treatment system and the calibration or validation of treatment plans. Moreover, it is used especially on calculating dose simulation using medical data for radiation therapy. However, using internal visualization tool of GEANT4 detector constructions on expressing dose result has deficiencies because it cannot display isodose line. No one has attempted to use this code to a real patient's data. Therefore, to complement this problem, using the result of gMocren that is a three-dimensional volume-visualizing tool, we tried to display a simulated dose distribution and isodose line on medical image. In addition, we have compared cross-validation on the result of gMocren and GEANT4 simulation with commercial radiation treatment planning system. We have extracted the analyzed data of dose distribution, using real patient's medical image data with a program based on Monte Carlo simulation and visualization tool for radiation isodose mapping.