• Title/Summary/Keyword: Volume Porosity

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Fabrication of Continuously Porous Alumina Bodies by Multi-Extrusion Process and their In-vitro and In-vivo Study for Biocompatibility (다중압출공정을 이용한 알루미나 연속다공질체 제조 및 그의 생체친화성 평가를 위한 In-vitro, In-vivo 실험)

  • 강인철;조순희;송호연;이병택
    • Journal of the Korean Ceramic Society
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    • v.41 no.7
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    • pp.560-566
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    • 2004
  • To fabricate the continuously porous alumina bodies by multi-extrusion process, carbon powder and ethylene vinyl acetate were used as a pore forming agent and a binder, respectively. As the change of extrusion pass number, reduction ratio as well as the volume fraction of core and tube, the porous alumina bodies having various kind of pore size and porosity could be obtained. The porous bodies showed continuous pore shape, high specific surface as well as high bending strength, which were compared with those of commercial alumina bodies. In-vitro study was carried out using MG-63 osteoblast cells to investigate of their biocompatibility. As a result, the cells grew well on top and bottom as well as inside surface of pore. From the result of in-vivo study of 3-dimensional porous alumina bodies using rats, it was confirmed that any inflammatory response was not found in the subcutaneous tissue around porous body. Also the porous bodies removed from the rats were fully covered with well-developed fibrous tissues and showed the formation of new capillary blood vessels.

Free vibration of sandwich micro-beam with porous foam core, GPL layers and piezo-magneto-electric facesheets via NSGT

  • Mohammadimehr, Mehdi;Firouzeh, Saeed;Pahlavanzadeh, Mahsa;Heidari, Yaser;Irani-Rahaghi, Mohsen
    • Computers and Concrete
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    • v.26 no.1
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    • pp.75-94
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    • 2020
  • The aim of this research is to investigate free vibration of a novel five layer Timoshenko microbeam which consists of a transversely flexible porous core made of Al-foam, two graphen platelets (GPL) nanocomposite reinforced layers to enhance the mechanical behavior of the structure as well as two piezo-magneto-electric face sheets layers. This microbeam is subjected to a thermal load and resting on Pasternak's foundation. To accomplish the analysis, constitutive equations of each layer are derived by means of nonlocal strain gradient theory (NSGT) to capture size dependent effects. Then, the Hamilton's principle is employed to obtain the equations of motion for five layer Timoshenko microbeam. They are subsequently solved analytically by applying Navier's method so that discretized governing equations are determined in form of dynamic matrix giving the possibility to gain the natural frequencies of the Timoshenko microbeam. Eventually, after a validation study, the numerical results are presented to study and discuss the influences of various parameters such as nonlocal parameter, strain gradient parameter, aspect ratio, porosity, various volume fraction and distributions of graphene platelets, temperature change and elastic foundation coefficients on natural frequencies of the sandwich microbeam.

Separation of Hydrogen-Nitrogen Gases by PTMSP-Borosilicate Composite Membranes (PTMSP-Borosilicate 복합막에 의한 수소-질소 기체 분리에 관한 연구)

  • Lee, Suk Ho;Kang, Tae Beom
    • Membrane Journal
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    • v.24 no.6
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    • pp.438-447
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    • 2014
  • The amorphous and porous borosilicate without any cracks was obtained under the following condition : 0.01~ 0.10 mole ratio of trimethylborate (TMB)/ tetraethylorthosilicate (TEOS) and the temperature of $700{\sim}800^{\circ}C$. According to the BET and SEM measurements, borosilicate heat-treated in between 700 and $800^{\circ}C$ showed the surface area of $251.12{\sim}355.62m^2/g$, the pore diameter of 3.5~4.9 nm, and the particle size of 30~60 nm. According to the TGA measurements, the thermal stability of poly[1-(trimethylsilyl)propyne](PTMSP) membrane was enhanced by inserting borosilicate. SEM observation showed that the size of dispersed borosilicate in the composite membrane was $1{\mu}m$. The results showed that the permeability of $H_2$ and $N_2$ increased and the selectivity of $H_2/N_2$ decreased upon the addition of borosilicate into PTMSP membranes. Addition of borosilicate may possibly increase the free volume, cavity and porosity of membranes indicating that permeation occurred by molecular sieving, surface and Knudsen diffusion rather than solution diffusion of gases.

Characteristics of Denitrification from Municipal Wastewater Treatment using a Combined Fixed Film Reactor (CFFR) Process (복합생물막 반응기를 이용한 하수처리시 탈질화 특성)

  • 이종현;남해욱;김영규;박태주
    • Journal of Environmental Science International
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    • v.8 no.1
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    • pp.107-113
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    • 1999
  • A new biological nutrient removal system combining $A^2/O$ process with fixed film was developed in this work and the characteristics of denitrification were especially investigated in the combined fixed film reactor(CFFR). Media was added in the anaerobic, anoxic and aerobic reactors, respectively. Tests were made to establish the effluent level of $NO_x-N$, COD, DO and nitrite effects on $NO_x-N$ removal in the CFFR by decreasing hydraulic retention time (HRT) from 10.0 to 3.5 hours and by increasing internal recycle ratio form 0% to 200%. The influent was synthesized to levels similar to the average influent of municipal wastewater treatment plants in Korea. SARAN media with a porosity of 96.3% was packed 40% / 130% / 25% based on its reactor volume, respectively. It was found that COD rarely limited dentrification in the anoxic reactor because of high $C/NO_x/-N$ ratio in the anoxic reactor, while DO concentration in the anoxic reactor and $NO_2-N/NO_x/-N$ from the aerobic effluent inhibited denitrification in the anoxic reactor. It was proved that the critical points of DO concentration in the anoxic reactor and $NO_2-N/NO_x/-N$ from the aerobic effluent were 0.15mg/L and 10%, respectively. As the internal recycle ratio increased, DO concentration in the anoxic reactor and $NO_2-N/NO_x/-N$ from the aerobic effluent increased. Especially, at the condition of internal recycle ratio, 200%, DO concentration in the anoxic reactor and $NO_2-N/NO_x/-N$ from the aerobic effluent exceeded the critical points of 0.15mg/L and 10%, respectively. Then, denitrification efficiency considerably decreased. Consequently, it was represented that the control of DO concentration in the anoxic reactor and $NO_2-N/NO_x/-N$ from the aerobic effluent can assure effective denitrification.

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Anode Properties of Sn-Ni Nanoparticle Composites for Rechargeable Lithium Batteries (주석-니켈 나노입자 복합체의 리튬 이차전지 음전극 특성)

  • Kim, Kwang-Man;Kang, Kun-Young;Choi, Min-Gyu;Lee, Young-Gi
    • Korean Chemical Engineering Research
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    • v.49 no.6
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    • pp.846-850
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    • 2011
  • Nanocomposite anodes for rechargeable lithium battery are prepared by mixing tin and nickel nanoparticles via wet method and their electrochemical properties are examined. The Sn-Ni nanocomposite anode shows a maximum discharge capacity of 700 mAh $g^{-1}$ at the first cycle but very poor cycle performance. This means that the electrode porosity and the Ni component formed by the simple mixing of nanoparticles no longer play the role of buffering the volume expansion/contraction of Sn component during charge-discharge. To solve the cycle performance problem, a novel nanostructured Sn-Ni anode should be designed and tested.

Fracture behavior and pore structure of concrete with metakaolin

  • Akcay, Burcu;Sengul, Cengiz;Tasdemir, Mehmet ali
    • Advances in concrete construction
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    • v.4 no.2
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    • pp.71-88
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    • 2016
  • Metakaolin, a dehydroxylated product of the mineral kaolinite, is one of the most valuable admixtures for high-performance concrete applications, including constructing reinforced concrete bridges and impact- and fire-resistant structures. Concretes produced using metakaolin become more homogeneous and denser compared to normal-strength concrete. Yet, these changes cause a change of volume throughout hardening, and increase the brittleness of hardened concrete significantly. In order to examine how the use of metakaolin affects the fracture and mechanical behavior of high-performance concrete we produced concretes using a range of water to binder ratio (0.42, 0.35 and 0.28) at three different weight fractions of metakaolin replacement (8%, 16% and 24%). The results showed that the rigidity of concretes increased with using 8% and 16% metakaolin, while it decreased in all series with 24% of metakaolin replacement. Similar effect has also been observed for other mechanical properties. While the peak loads in load-displacement curves of concretes decreased significantly with increasing water to binder ratio, this effect have been found to be diminished by using metakaolin. Pore structure analysis through mercury intrusion porosimetry test showed that the addition of metakaolin decreased the critical pore size of paste phases of concrete, and increasing the amount of metakaolin reduced the total porosity for the specimens with low water to binder ratios in particular. To determine the optimal values of water to binder ratio and metakaolin content in producing high-strength and high-performance concrete we applied a multi-objective optimization, where several responses were simultaneously assessed to find the best solution for each parameter.

Modeling of Mesh Screen for Use in Surface Tension Tank Using Flow-3d Software (Flow-3d를 이용한 표면장력 탱크용 메시 스크린 모델링)

  • Kim, Hyuntak;Lim, Sang Hyuk;Yoon, Hosung;Park, Jeong-Bae;Kwon, Sejin
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2017.05a
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    • pp.984-990
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    • 2017
  • Mesh screen modeling and liquid propellant discharge simulation of surface tension tank were performed using commercial CFD software Flow-3d. $350{\times}2600$, $400{\times}3000$ and $510{\times}3600$ DTW mesh screen were modeled using macroscopic porous media model. Porosity, capillary pressure, and drag coefficient were assigned for each mesh screen model, and bubble point simulations were performed. The mesh screen model was validated with the experimental data. Based on the screen modeling, liquid propellant discharge simulation from PMD tank was performed. NTO was assigned as the liquid propellant, and void was set to flow into the tank inlet to achieve an initial volume flow rate of liquid propellant in $3{\times}10^{-3}g$ acceleration condition. The intial flow pressure drop through the mesh screen was approximately 270 Pa, and the pressure drop increased with time. Liquid propellant discharge was sustained until the flow pressure drop reached approximately 630 Pa, which was near the estimated bubble point value of the screen model.

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STIFFNESS AND POROSITY EVALUATION USING FIELD VELOCITY RESISTIVITY PROBE

  • Lee, Jong-Sub;Yoon, Hyung-Koo;Choi, Yong-Kyu
    • Proceedings of the Korean Geotechical Society Conference
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    • 2010.09c
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    • pp.24-30
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    • 2010
  • The void ratio and elastic moduli are design parameters used in geotechnical engineering to understand soil behavior. Elastic and electromagnetic waves have been used to evaluate the various soil characteristics due to high resolution. The objective of this study is to evaluate the void ratio and elastic moduli based on elastic wave velocities and electrical resistivity. The Field Velocity Resistivity Probe (FVRP) is developed to obtain the elastic and electromagnetic wave profiles of soil during penetration. The Piezoelectric Disk Elements (PDE) and Bender Elements (BE) are used as transducers for measuring the elastic wave velocities such as compressional and shear wave velocities. The Electrical Resistivity Probe (ERP) is also installed for capturing the electrical resistivity profile. The application test is carried out on the southern coast of the Korean peninsula. The field tests are performed at a depth of 6~20 m, at 10 cm intervals for measuring elastic wave velocities and at 0.5cm intervals for measuring electrical resistivity. The elastic moduli such as constraint and shear moduli are calculated by using measured elastic wave velocities. The void ratios are also evaluated based on the elastic wave velocities and the electrical resistivity. Furthermore, the converted void ratios by using FVRP are compared with the volumetric void ratio obtained by a standard consolidation test. The comparison shows that the void ratios based on the FVPR match the volume based void ratio well. This study suggests that the FVRP may be a useful device to effectively determine the elastic moduli and void ratio in the field.

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Image Calibration Techniques for Removing Cupping and Ring Artifacts in X-ray Micro-CT Images (X-ray micro-CT 이미지 내 패임 및 동심원상 화상결함 제거를 위한 이미지 보정 기법)

  • Jung, Yeon-Jong;Yun, Tae-Sup;Kim, Kwang-Yeom;Choo, Jin-Hyun
    • Journal of the Korean Geotechnical Society
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    • v.27 no.11
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    • pp.93-101
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    • 2011
  • High quality X-ray computed microtomography (micro-CT) imaging of internal microstructures and pore space in geomaterials is often hampered by some inherent noises embedded in the images. In this paper, we introduce image calibration techniques for removing the most common noises in X-ray micro-CT, cupping (brightness difference between the periphery and central regions) and ring artifacts (consecutive concentric circles emanating from the origin). The artifacts removal sequentially applies coordinate transformation, normalization, and low-pass filtering in 2D Fourier spectrum to raw CT-images. The applicability and performance of the techniques are showcased by describing extraction of 3D pore structures from micro-CT images of porous basalt using artifacts reductions, binarization, and volume stacking. Comparisions between calibrated and raw images indicate that the artifacts removal allows us to avoid the overestimation of porosity of imaged materials, and proper calibration of the artifacts plays a crucial role in using X-ray CT for geomaterials.

Study on Performance Comparison in Carbon Nanotube Embedded Electrospun Membranes for Particulate Matter Removal (탄소나노튜브가 첨가된 전기방사 멤브레인의 미세입자 제거 성능 비교에 관한 연구)

  • Gu, Minkyung;kim, Dongwan;Han, Sangil
    • Korean Chemical Engineering Research
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    • v.56 no.1
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    • pp.56-60
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    • 2018
  • There have been a lot of study to improve the performance of membrane filters as the removal of particulate matter has been of great interest due to the negative effects. Among the membrane fabrication techniques, the electrospinning technique is the most promising because it can produce uniform fibers ranging from nano to micrometer size. The electrospun membranes will greatly improve the filtration performance due to the high ratio of surface area to volume and the high porosity. In the present study, polystyrene (PS) and cellulose acetate (CA) polymers were used to produce the membranes with carbon nanotube (CNT), showing the filtration performances were improved with the optimal amounts of CNT.