• Title/Summary/Keyword: Volume Porosity

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The Critical Pigment Volume Concentration Concept for Paper Coatings: II. Later-Bound Clay; Ground Calcium Carbonate, and Clay- carbonate Pigment Coatings

  • Lee, Do-Ik
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.34 no.5
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    • pp.18-38
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    • 2002
  • A previous study on the model coatings based on latex-bound plastic pigment coatings (1) has been extended to latex-bound No. 1 clay, ultra-fine ground calcium carbonate (UFGCC), and clay-carbonate pigment mixture coatings, which are being widely used in the paper industry. The latex binder used was a good film-forming, monodisperse S/B latex or 0.15$\mu\textrm{m}$. No. 1 clay was representative of plate-like pigment particles, whereas UFGCC was of somewhat rounded rhombohedral pigment particlel. Both of them had negatively skewed triangular particle size distributions having the mean particle suet of 0.7${\mu}{\textrm}{m}$ and 0.6$\mu\textrm{m}$, respectively. Their packing volumes were found to be 62.5% and 657%, respectively. while their critical pigment volume concentrations (CPVC's) were determined to be 52.7% and 50.5% ( average of 45% caused by the incompatibility and 55.9% extrapolated) by coating porosity, respectively. Each pigment/latex coating system has shown its unique relationship between coating properties and pigment concentrations, especially above its CPVC. Notably, the clay/latex coating system hat shown higher coating porosity than the UFGCC/latex system at high pigment concentrations above their respective CPVC's. It was also found that their coating porosity and gloss were inter-related to each other above the CPVC's, as predicted by the theory. More interestingly, the blends of these two pigments have shown unique rheological and coating properties which may explain why such pigment blends are widely used in the industry. These findings have suggested that the unique structure of clay coatings and the unique high-shear rheology of ground calcium carbonate coatings can be judiciously combined to achieve superior coatings. Importantly, the low-shear viscosity of the blends was indicative of their unique packing and coating structure, whereas their high-shear rheology was represented by a common mixing rule, i.e., a viscosity-averaging. Transmission and scanning electron and atomic force microscopes were used to probe the state of pigment / latex dispersions, coating surfaces, freeze fractured coating cross-sections, and coating surface topography. These microscopic studies complemented the above observations. In addition, the ratio, R, of CPVC/(Pigment Packing Volume) has been proposed as a measure of the binder efficiency for a given pigment or pigment mixtures or as a measure of binder-pigment interactions. Also, a mathematical model has been proposed to estimate the packing volumes of clay and ground calcium carbonate pigments with their respective particle size distributions. As well known in the particle packing, the narrower the particle size distributions, the lower the packing volumes and the greater the coating porosity, regardless of particle shapes.

Effects of Rice Straw as Bulking Materials on Aerobic Composting of Food Wastes (팽화재로서의 볏짚이 음식물쓰레기의 호기성 퇴비화에 미치는 영향)

  • 박석환
    • Journal of Environmental Health Sciences
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    • v.28 no.2
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    • pp.141-148
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    • 2002
  • This study was performed to examine the effects of rice straw as bulking materials on temperature, pH, weight and volume reduction, porosity, C/N ratio, salinity, and conductivity in aerobic composting of food wastes. Volume ratios of food wastes to rice straw in reactor control, RS-1, RS-2, RS-2 and RS-4 were 4:0, 4:1. 4:2. 4:3 and 4:4, respectively. Reactors were operated for 24days with 1 hour stirring by lrpm and 2hours aeration per day. The values of pH of food wastes and rice straw were 4.39 and 7.4, respectively. The lowering of the volume ratio of food wastes to rice straw resulted in the high reaction temperature and the fast weight and volume reduction rates. C/N ratio in control was larger than that in rice straw containing reactors. Salinity and conductivity in reactors were condensed and increased by reaction days.

Preparation and Characterization of KOH-Activated Carbons Developed from Petroleum Coke

  • Sayed Ahmed, S.A.;Abo El-Enin, Reham M.M.;El-Nabarawy, Th.
    • Carbon letters
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    • v.10 no.4
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    • pp.293-299
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    • 2009
  • Potassium hydroxide activated carbons were prepared from Egyptian petroleum cokes with different KOH/coke ratios and at different activation temperatures and times. The textural properties were determined by adsorption of nitrogen at $-196^{\circ}C$. The adsorption of iodine and methylene blue was also investigated at $30^{\circ}C$. The surface area and the non-micropore volume increased whereas the micropore volume decreased with the increase of the ratio KOH/coke. Also the surface area and porosity increased with the rise of activation temperature from 500 to $800^{\circ}C$. Textural parameter considerably increased with the increase of activation time from 1 to 3 h. Further increasing of activation time from 3 to 4 h was associated with a less pronounced increase in textural parameters. The adsorption of iodine shows the same trend of surface area and porosity change exhibited by nitrogen adsorption, with KOH/coke ratio and temperature of activation. Adsorption of methylene blue follows pseudo-first-order kinetics and its equilibrium adsorption follows Langmuir and D-R models.

Prediction of Permeability for Braided Preform (브레이드 프리폼의 투과율 계수 예측)

  • Youngseok Song;Youn, Jae-Roun
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2003.04a
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    • pp.184-187
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    • 2003
  • Complete prediction of second order permeability tensor for three dimensional circular braided preform is critical to understand the resin transfer molding process of composites. The permeability can be predicted by considering resin flow through the multi-axial fiber structure. In this study, permeability tensor for a 3-D circular braided preform is calculated by solving a boundary problem of a periodic unit cell. Flow field through the unit cell is obtained by using a 3-D finite volume method (FVM) and Darcy's law is utilized to obtain permeability tensor. Flow analysis for two cases that a fiber tow is regarded as impermeable solid and permeable porous medium is carried out respectively. It is found that the flow within the intra-tow region of the braided preform is negligible if inter-tow porosity is relatively high but the flow through the tow must be considered when the porosity is low. To avoid checkerboard pressure field and improve the efficiency of numerical computation, a new interpolation function for velocity variation is proposed on the basis of analytic solutions. Permeability of the braided preform is measured through a radial flow experiment and compared with the permeability predicted numerically.

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Nonlinear bending of functionally graded porous nanobeam subjected to multiple physical load based on nonlocal strain gradient theory

  • Gao, Yang;Xiao, Wan-shen;Zhu, Haiping
    • Steel and Composite Structures
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    • v.31 no.5
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    • pp.469-488
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    • 2019
  • We in this paper study nonlinear bending of a functionally graded porous nanobeam subjected to multiple physical load based on the nonlocal strain gradient theory. For more reasonable analysis of nanobeams made of porous functionally graded magneto-thermo-electro-elastic materials (PFGMTEEMs), both constituent materials and the porosity appear gradient distribution in the present expression of effective material properties, which is much more suitable to the actual compared with the conventional expression of effective material properties. Besides the displacement function regarding physical neutral surface is introduced to analyze mechanical behaviors of beams made of FGMs. Then we derive nonlinear governing equations of PFGMTEEMs beams using the principle of Hamilton. To obtain analytical solutions, a two-step perturbation method is developed in nonuniform electric field and magnetic field, and then we use it to solve nonlinear equations. Finally, the analytical solutions are utilized to perform a parametric analysis, where the effect of various physical parameters on static bending deformation of nanobeams are studied in detail, such as the nonlocal parameter, strain gradient parameter, the ratio of nonlocal parameter to strain gradient parameter, porosity volume fraction, material volume fraction index, temperature, initial magnetic potentials and external electric potentials.

Investigation on the Physical Properties of the Lightweight Mortar Made with Hydrogen Peroxide (과산화수소를 혼입한 경량기포 모르타르의 물리적 특성에 관한 연구)

  • Lee, Soo-Yong;Kim, Ji-Hyun;Lee, Jae-Yong;Chung, Chul-Woo
    • Journal of the Korea Institute of Building Construction
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    • v.18 no.2
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    • pp.117-123
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    • 2018
  • The increase in energy efficiency has became a significantly important issue for building construction and maintenance. The energy efficiency is known to be achieved by using a material with lower thermal conductivity, and the best method is to increase the internal porosity of the material. Typical ways to increase internal porosity within cementitious composite are to use foaming agents or to use reactive powder such as aluminum. However, in this work, hydrogen peroxide was chosen as an alternative material to make lightweight cement mortar. The volume expansion of fresh cement mortar and unit weight, compressive strength and thermal conductivity of 28 day old cement mortar were measured. According to the experimental results, the incorporation of hydrogen peroxide increased internal porosity, and thereby reducing the compressive strength and thermal conductivities of cement mortar. It was found that hydrogen peroxide can be successfully used to produce lightweight mortar for thermal insulation purposes of buildings.

Substrate removal characteristics in anaerobic filter using volcanic stones (화산석(火山石)을 이용(利用)한 혐기성고정상(嫌氣性固定床)에 있어서 기질(基質)의 제거특성(除去特性))

  • Eom, Tae-Kyu;Kim, Young-Chur;Kim, Kyung-Ho
    • Journal of Korean Society of Water and Wastewater
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    • v.7 no.1
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    • pp.46-53
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    • 1993
  • This study was carried out to examine substrate removal characteristics with the variation of the hydraulic retention time in an anaerobic filter. The feed concentration of synthetic wastewater used in the experiment was $10,000mg/l$ glucose. As media, the porosity of volcanic stones in Jeju island were 76%. The conditions of the experiment were as follows; HRT ranging from 1 day to 3 day, loading rates ranging from 3.33kg $COD_{er}/void\;m^3.day$ to 10kg $COD_{er}/void\;m^3.day$ and a temperature $35^{\circ}C$. Based on the results of the experiments, the COD removal efficiency was 98~99% in $COD_{er}$ method with loading rates ranging from 3.33kgCOD/void $m^3.day$ to 10kg COD/void $m^3.day$ and HRT ranging from 1day to 3 day. The produced quantity of gas equivalant to a porosity volume was $1.332~3.756Nm^3/void\;m^3.day$. The relationship between $COD_{er}$ loading rates and gas produced quantity equivalant to a porosity volume was well fitted with the equation of $Nm^3/void\;m^3.day{\cdot}=0.359L_0+0.179$($L_0=COD$ loading rate). Judging from the removal efficiency in this experiment, We concluded that anaerobic filter using Volcanic stones is one of improved and effective. As media, practical value of volcanic stones is sufficient.

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An efficient shear deformation theory for wave propagation in functionally graded material beams with porosities

  • Benadouda, Mourad;Atmane, Hassen Ait;Tounsi, Abdelouahed;Bernard, Fabrice;Mahmoud, S.R.
    • Earthquakes and Structures
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    • v.13 no.3
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    • pp.255-265
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    • 2017
  • In this paper, an efficient shear deformation theory is developed for wave propagation analysis in a functionally graded beam. More particularly, porosities that may occur in Functionally Graded Materials (FGMs) during their manufacture are considered. The proposed shear deformation theory is efficient method because it permits us to show the effect of both bending and shear components and this is carried out by dividing the transverse displacement into the bending and shear parts. Material properties are assumed graded in the thickness direction according to a simple power law distribution in terms of the volume fractions of the constituents; but the rule of mixture is modified to describe and approximate material properties of the functionally graded beams with porosity phases. The governing equations of the wave propagation in the functionally graded beam are derived by employing the Hamilton's principle. The analytical dispersion relation of the functionally graded beam is obtained by solving an eigenvalue problem. The effects of the volume fraction distributions, the depth of beam, the number of wave and the porosity on wave propagation in functionally graded beam are discussed in details. It can be concluded that the present theory is not only accurate but also simple in predicting the wave propagation characteristics in the functionally graded beam.

Soil Physicochemical Properties by applied with Mixed Ratio Soldier Fly (Hermetia illucens) Casts (동애등애 분변토의 혼합비율에 따른 토양이화학적 특성)

  • Kim, Young-Sun;Lee, Sang-Beom;Ham, Suon-Kyu;Lim, Hye-Jung;Cboe, Young-Cheol
    • Asian Journal of Turfgrass Science
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    • v.25 no.1
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    • pp.106-111
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    • 2011
  • This study was conducted to investigate the effect of the mixture ratio of a soldier fly casts (SFC), compost and cocopeat on the soil physicochemical properties. The mixture ratios of soil amendment were 0%, 3%, 5%, 7% and 10% (V/V) incorporated with sand which met to the USGA particle standard. To analyze the effects of amendments on soil chemical properties, pH and EC were measured. The porosity, capillary porosity, air-filled porosity, bulk density and hydraulic conductivity also measured to analyze the physical properties. Chemical properties were significantly different by mixture ratios of a SFC, compost and cocopeat. Capillary porosity was a factor involved in soil physical properties by blending with a SFC and compost. It was affected on the volume of porosity or hydraulic conductivity. To analyze the correlation of mixture ratio versus to physical characters, the ratios of SFC were significantly different in capillary porosity, air-filled porosity, and hydraulic conductivity. These results indicated that mixing ratios of SFC were affected on soil physicochemical properties such as porosity and hydraulic conductivity of the root zone on the USGA sand green.

Variation of Porosity and Gas Permeability of Gas Diffusion Layers Under Compression (가스확산층의 압축에 따른 공극률 및 기체투과율의 변화)

  • Lee, Yongtaek
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.37 no.8
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    • pp.767-773
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    • 2013
  • This study suggested the variations of porosity and gas permeability of gas diffusion layers (GDLs), which are easily deformed among the components of a highly compressed PEMFC stack. The volume change owing to compression was measured experimentally, and the variations in the porosity and gas permeability were estimated using correlations published in previous literature. The effect of polytetrafluoroethylene (PTFE) which is added to the GDLs to enhance water discharge was investigated on the variations of porosity and gas permeability. The gas permeability which strongly affects the mass transport through GDL, decreases sharply with increasing compression when the GDL has high PTFE loading. As a result, the mass transport through the pore network of GDL can be changed considerably according to the PTFE loading even with the same clamping force. The accuracy of modeling of transport phenomena through GDL can be improved due to the enhanced correlations developed based on the results of this study.