• 한국응용과학기술학회지
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• 제27권4호
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• pp.531-538
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• 2010

The electrochemistry characterization of metal is important in many industrial applications. In this study, we investigated the C-V diagrams related to the electrochemistry characterization of nickel. We determined electrochemical measurement by using cyclic voltammetry with a three electrode system. A measuring range was reduced from initial potential to -1350mV, continuously oxidized to 1650mV and measured to the initial point. The scan rate were 100, 150, 200 and 200mV/s. As a result, the C-V characterization of nickel using ethanolamine and ethylethanolamine inhibitor appeared irreversible process caused by the oxidation current from the cyclic voltammogram. After adding ethanolamine compound additive, adsorption film constituted, and the passive phenomena happened. According to the results by cyclic voltammetry method, it was revealed that the effect of the electrochemistry characterization of nickel depends on ethanolamine structure interaction to adsorption complex.

• 대한화학회지
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• 제25권2호
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• pp.103-109
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• 1981

큰 입력지향을 갖는 20개의 sample and hold가 MOSFET으로 switching되는 간편하면서도 비용이 적게드는 analog 기억장치를 제작하였다. 이것은 digital로 3KHz.까지 임의로 조절되는 shift register로 연결되어 있다. 이 장치의 유용성을 보이기 위해 square와 sine파 및 fast-scan voltammetry와 differential pulse polarography의 전류-시간 변화와 같은 전기화학적 실험을 행하였다.

• 한국환경과학회지
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• 제11권2호
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• pp.131-137
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• 2002

The chemical behavior and properties on the redox state of environmental pollutant has been investigated by electrochemical methods. We carried out to measure the variations in the redox reaction of differential pulse polarogram and cyclic voltammogram. The results observed the influences on redox potential and current of various factors with temperature and pH. These were established factors as the effect of the redox reaction. It can be clearly recognized that the electrode reaction are from qusi-reversible to irreversible processes. Also, it was mixing with reaction current controlled. The bits-phenol A in the waste water was made to compound with cobalt ion and it take away from the separation into compound. The $Co(BPA)_2$ compound was not found to be dissociation in waste water. However, this compound is avery unstable(K=1.02) and for a while, it was to be a dissociation. Therefore, we believed that it was likely to a toxic substance.

• 한국세라믹학회지
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• 제44권11호
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• pp.618-621
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• 2007

In this study, flint glass batches with blast furnace slag (BFS) were prepared and the contribution of the BFS to the fining of melts was studied through investigations of the melting and fining characteristics. Additionally, a sulfur redox reaction for BFS-doped melts was examined by square wave voltammetry (SWV). The results of the melting & fining test showed that BFS improved the fining of the melts. In a voltammogram of BFS-doped melts, two reduction peaks were shown at high frequencies while only one peak appeared at low frequencies. The peaks were located at a potential that was similar to those of melts fined by sulfate. From those results it was concluded that sulfide ($S^{2-}$) in BFS has effects in glass melts that are identical to those of sulfate ($SO_4^{2-}$).

• 한국세라믹학회지
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• 제48권3호
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• pp.205-210
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• 2011

The dependence of sulfur redox behavior and its diffusivity on temperature and composition was studied in mixed alkali silicate melts by means of square wave voltammetry (SWV) at different frequencies in a temperature range of $1000^{\circ}C$ to $1400^{\circ}C$. The voltammograms showed two reduction peaks at high frequency but only one peak at low frequency. Irrespective of $K_2O/(Na_2O+K_2O)$, each peak potential due to reduction of $S^{6+}$ to $S^{4+}$ and $S^{4+}$ to $S^0$ moved toward a negative direction with temperature decrease, and the peak current showed a strong dependence on frequency at a constant temperature. However, the compositional dependence of the peak potential showed an inconsistent behavior with an increase of $K_2O$. The mixed alkali effect was not observed in sulfur diffusion. This inconsistency of both peak potential and diffusion for compositional dependence may be derived from the strong volatilization of sulfur in melts.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2000년도 추계학술대회 논문집
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• pp.339-342
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• 2000

Polypyrrole(PPy) nanotubules were formed within template pores by chemical synthesis using $FeCl_3$ as an oxidant. The oxidation peak of PPy nanotubules in the cyclic voltammogram was observed at about 2.8V and 3.3V vs. $Li/Li^+$, while in the case of PPy film, that was observed at about 3.0V. It suggests that the electron hopping on the main chain of PPy nanotubules was improved. When the PPy nanotubules was used to a cathode of lithium secondary battery, we obtained discharge capacity as much as 27 mAh/g, and initial coulomb efficiency by 90%. We expect that the capacity can be improved by further study.

• 한국전기전자재료학회논문지
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• 제17권6호
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• pp.652-660
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• 2004

The cis-hex-3-ene-1,5-diynyl-bridged diiron compound 3, [(η$^{5}$ - $C_{5}$ M $e_{5}$ ) Fe(dppe)］$_2$($\mu$-C≡C-CH=CH-C≡C), have been prepared and characterized by cyclic voltammetry(CV), and electronic spectroscopy (UV-VIS and near-IR, NMR). From the results, compound 3 show two well resolved, single-electron, reversible oxidation waves by CV, and comproportionation constant(Kc) calculated from the CV data for compound 3. The Mixed-valence (MV) radical cation 3$^{+}$ show strong absorptions in the near IR, 1586 nm, and this band is more readily assigned as MV $\pi$-$\pi$ band of delocalized complex (Robin-Day Mixed-valence Class III), and the $H_{ab}$ , effective coupling parameter are most consistent with electronic delocalization.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2002년도 추계학술대회 논문집 전기물성,응용부문
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• pp.51-53
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• 2002

This research aims to develop a multiple channel electrochemical DNA chip using micro-fabrication technology. At first, we fabricated a high integrated type DNA chip array by lithography technology. Several probe DNAs consisting of thiol group at their 5-end were immobilized on the sold electrodes. Then target DNAs were hybridized by an electrical force. Redox peak of cyclic-voltammogram showed a difference between target DNA and mismatched DNA in the anodic peak current. Therefore, it is able to detect a various genes electrochemically after immobilization of a various probe DNA and hybridization of label-free DNA on the electrodes simultaneously. It suggested that this DNA chip could recognize the sequence specific genes.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2004년도 하계학술대회 논문집 Vol.5 No.2
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• pp.920-923
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• 2004

We have investgated on the monolayer LB film of BASH-DMPC mixture on an ITO for the photoisomerization by light irradiation. We measured electrochemical properties by using cyclic voltammetry with a three-electrode system, An Ag/AgCl reference electrode, a platinum wire counter electrode and LB film-coated ITO working electrode in $NaClO_4$ solution at a variable concentration and monolayer LB films. A measuring range was reduced from initial potential to -1350mV, continuously oxidized to 1650 mV and measured to the initial point. The scan rate were 50, 100, 150 and 200 mV/s. As a results, LB films of 8A5H-DMPC appeared reversible process caused by the reduction-oxidation current from the cyclic voltammogram.

• Bulletin of the Korean Chemical Society
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• 제10권5호
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• pp.414-418
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• 1989

The electrochemical behavior of cadmium(Ⅱ) in tartrate solution has been studied over the pH range of 6 to 13.6 in order to explain the phenomena of the changes in limiting current depending on the pH. The polarographic limiting current showed a constant value up to pH of 7.8, after which it decreased sharply to show a minimum at pH between 11 and 12. The limiting current, then, increased again with increasing pH. The number of peaks in cyclic voltammogram was 1 to 3 depending on the pH of the solution. Two other voltammetric peaks could be observed when the main reduction peak diminished. The decrease of limiting current at 7.5$Cd(C_4H_3O_6)^-$. The increase of limiting current at strong alkaline solution, however, was due to the complex $Cd(Tart)_2(OH)_2^{4-}$.