• 제목/요약/키워드: Voltage utilization rate

검색결과 27건 처리시간 0.019초

Analysis of Flow Rate Inducing Voltage Loss in a 100 cm2 Class Molten Carbonate Fuel Cell

  • Lee, Choong-Gon
    • Journal of Electrochemical Science and Technology
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    • 제2권1호
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    • pp.20-25
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    • 2011
  • This work focuses on the behavior of the overpotential increase due to a utilization rise in a molten carbonate fuel cell. The behavior is generally explained by Nernst loss, which is a kind of voltage loss due to the thermodynamic potential gradients in a polarization state due to the concentration distribution of reactant species through the gas flow direction. The evaluation of Nernst loss is carried out with a traditional experimental method of constant gas utilization (CU). On the other hand, overpotential due to the gas-phase mass-transport resistance at the anode and cathode shows dependence on the utilization, which can be measured using the inert gas step addition (ISA) method. Since the Nernst loss is assumed to be due to the thermodynamic reasons, the voltage loss can be calculated by the Nernst equation, referred to as a simple calculation (SC) in this work. The three values of voltage loss due to CU, ISA, and SC are compared, showing that these values rise with increases in the utilization within acceptable deviations. When we consider that the anode and cathode reactions are significantly affected by the gas-phase mass transfer, the behavior strongly implies that the voltage loss is attributable not to thermodynamic reasons, namely Nernst loss, but to the kinetic reason of mass-transfer resistance in the gas phase.

Distributed Secondary Voltage Control of Islanded Microgrids with Event-Triggered Scheme

  • Guo, Qian;Cai, Hui;Wang, Ying;Chen, Weimin
    • Journal of Power Electronics
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    • 제17권6호
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    • pp.1650-1657
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    • 2017
  • In this study, the distributed secondary voltage control of islanded microgrids with multi-agent consensus algorithm is investigated. As an alternative to a time-triggered approach, an event-triggered scheme is proposed to reduce the communication load among inverter-based distributed generators (DGs). The proposed aperiodic control scheme reduced unnecessary utilization of limited network bandwidth without degrading control performance. By properly establishing a distributed triggering condition in DG local controller, each inverter is only required to send voltage information when its own event occurs. The compensation of voltage amplitude deviation can be realized, and redundant data exchange related to fixed high sampling rate can be avoided. Therefore, an efficient use of communication infrastructure can be realized, particularly when the system is operating in steady state. The effectiveness of the proposed scheme is verified by simulations on a microgrid test system.

반응성 마그네트론 스퍼터링법에 의한 Nickel Oxide 박막 제작 특성에 관한 연구 (Characteristics of Nickel Oxide Thin Film Manufactured by Reactive Magnetron Sputtering Method)

  • 김기범;황윤식;김영식;박장식
    • 반도체디스플레이기술학회지
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    • 제7권1호
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    • pp.29-34
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    • 2008
  • In this paper, the DE(double erosion) cathode for the reactive magnetron sputtering system is developed for high deposition rate and high target utilization efficiency. The utilization efficiency of the developed DE cathode is 22% higher than that of normal SE(single erosion) cathode. Sputtering process for the nickel oxide thin films with the DE cathode is performed under the following conditions; power with $1kW{\sim}3kW$, pressure with 4mtorr and 8mtorr, oxygen flow ratio with $0%{\sim}80%$. As a result, the hysteresis phenomenon of discharge voltage in 4mtorr is lower than that in 8mtorr and the hysteresis phenomenon of discharge voltage is getting lower as the applied power is getting higher. The structure of cross section and surface roughness of the thin films are observed by FE-SEM and AFM. The structure of cross section of the thin films is columnar and the average surface roughness under oxygen flow ratio of 0%, 52.5% and 65.0% are $2.08{\AA}$, $2.20{\AA}$ and $0.854{\AA}$, respectively.

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STUDIES ON PRODUCTION AND EFFICIENT UTILIZATION OF LIVESTOCK EMBRYOS BY IN VITRO FERTILIZATION AND MICROMANIPULATION IV. NUCLEAR TRANSPLANTATION AND ELECTROFUSION FOR CLONING IN BOVINE FOLLICULAR OOCYTES

  • Chung, Y.C.;Kim, C.K.;Song, X.X.;Yoon, J.T.;Choi, S.H.;Chung, Y.H.
    • Asian-Australasian Journal of Animal Sciences
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    • 제8권6호
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    • pp.641-645
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    • 1995
  • This study was conducted to develop a method for production of nuclear transplant bovine embryos using in vitro-matured (IVM) oocytes and to examine the effect of different conditions of electrofusion on fusion rate and developmental capacity of donor nucleus transplanted to enucleated oocytes. Eight- to sixteen-cell embryos derived from oocytes matured and fertilized in vitro used as donor blastomeres and IVM oocytes were used as recipient oocytes. Oocytes were enucleated immediately after 23-24 h IVM and then reconstituted with a donor blastomere in two different micromanipulation media. Fusion rate and subsequent development of the reconstituted oocytes was compared under the different electric stimuli and recipient oocyte ages. Success rate of enucleation was significantly higher in TCM-199 medium containing FCS than in DPBS. The high fusion rate(75-94%) and development (6.4-14.8%) to morulae and blastocyst (M + B) were obtained from 0.6-0.75 kV/cm DC voltage, although total cleavage was not different among the electric pulses. Most optimal condition of electric stimulation for fusion and development was 1 DC voltage of 0.75 kV/cm, in which 80.5% of oocytes were fused, 80.0% and 31.7% of which was cleaved and developed to M + B, respectively. No M + B was obtained from 1.2 kV/cm DC voltage regardless of pulse frequency. Recipint oocyte age at electrofusion greatly affected the cleavage and subsequent development to M + B, showing high rate at 40-41 h oocyte maturation. These results suggest that a suitable condition of electrofusion for donor nuclei derived from IVF may be 1-2 DC pulses of 0.7 kV/cm for $70{\mu}sec$ and that processing of a transplanted nucleus in IVM oocytes may be affected by maturation age of recipient oocytes.

병렬 3레벨 AC/DC 전력변환 시스템의 영상분 순환전류 억제 (Suppression of Circulating Current in Parallel Operation of Three-Level AC/DC Converters)

  • 손영광;지승준;이영기;설승기
    • 전력전자학회논문지
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    • 제21권4호
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    • pp.312-319
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    • 2016
  • Zero-sequence Circulating Current (ZSCC) flows inevitably in parallel converters that share common DC and AC sources. The ZSCC commonly flowing in all converters increases loss and decreases the overall capacity of parallel converters. This paper proposes a simple and effective ZSCC suppression method based on the Space Vector PWM (SVPWM) with the ZSCC controller. The zero-sequence voltage for the proposed SVPWM is calculated on the basis of the grid voltage and not on the phase voltage references. The limit of the linear modulation region of the converters with the proposed method is analyzed and compared with other methods, thereby proving that the limit of the region can be extended with the proposed method. The effectiveness of the proposed method has been verified through the experimental setup comprising four parallel three-level converters. The ZSCC is confirmed to be well suppressed, and the linear modulation region is extended simultaneously with the proposed method. Moreover, the proposed control method does not require any communication between the converters to suppress the ZSCC unlike other conventional methods.

전압 불평형시 콘덴서 전압, 전류, 용량 특성 해석 (Characteristics Analysis for Voltage, Current & Capacity of Condenser at Voltage Unbalance)

  • 김종겸;박영진
    • 조명전기설비학회논문지
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    • 제24권5호
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    • pp.145-151
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    • 2010
  • 전압 불평형은 수용가 설비에서 상당히 중요한 전기 품질의 하나로 간주되고 있다. 전압은 송전선로 계통에서는 평형에 가깝지만, 수용가에서의 전압 레벨은 시스템 임피던스의 불평형과 단상 부하의 고르지 못한 배분 등으로 인해 불평형이 될 수 있다. 콘덴서는 역률 보상으로도 사용되며, 비선형 부하에서 발생하는 고조파를 저감하기 위해 리액터와 함께 사용되고 있다. 전압 불평형이 존재할 경우 전류 불평형으로 콘덴서에서는 용량변화가 일어난다. 콘덴서와 리액터를 함께 사용하는 경우 사고 발생이 높은 편이다. 그래서 콘덴서 설비에 전압 불평형이 존재할 경우 전압, 전류 그리고 용량의 변화가 어떻게 진행되는지 확인하는 것이 매우 중요하다. 본 연구에서는 전압 불평형률이 존재할 경우 콘덴서 단독운전과 리액터의 부착시 전압, 전류 및 용량의 크기가 규정에서 제시한 범위 이내인지를 계산하였다.

교차류형 100W급 용융탄산염 연료전지 스택 장기운전평가 (Evaluation of Long Term Operation of Cross-flow Molten Carbonate Fuel Cell Stack)

  • 임희천;설진호;류철성;이창우;홍성안
    • 한국수소및신에너지학회논문집
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    • 제6권2호
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    • pp.53-63
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    • 1995
  • 차세대의 새로운 발전방식인 용융탄산염형 연료전지 시스템개발 사업중 실용 스택개발을 위하여 전극유효연적이 $100cm^2$ 인 단위전지를 10단 적층한 Cross Flow형 MCFC스택을 제작하고 2성능측정설비를 구성하여 장기운전시험을 실시하였다 연료로는 $H_2/CO_2/H_2O$의 비율을 72%/18%/10% 로 조성한 가스를 이용하고 산화제가스로는 $O_2/CO_2$$Air/CO_2$ 비율이 33%/67%, 70%/30%가 되는 가스를 이용하여 운전할때의 초기성능 및 15A($150mA/cm^2$) 정부하 상태에서의 장기운전시험시의 전압 강하율을 조사하였다. 운전시간 310시간이 경과된 후의 스택전압은 8.39V이었고 이때의 출력은 125.8W를 보여주었다. 한편 1845시간이 경과한후 공기를 산화제로 이용하는 경우 전압은 6.95V로서 출력 104W를 나타내고 있다. 초기성능치에 의한 에너지 변환효율은 이용율이 40%인 경우 29.65%이었고 80%로 증가하는 경우 약 51.5%가 된다. 1840시간의 경과한때 까지의 전압 강하율은 약 52.4mV/1000hr로서 이전의 스택보다는 전압강하율이 감소되고 있으며 스택의 성능 저하의 주요한 요인은 개회로 전압의 저하로 내부단락동에서 기인하는 것으로 여겨진다. 또한 장기운전사 스택내부에서의 단위전지 전압분포가 균일하지 않음을 알 수 있어 이에 대한 개선을 필요로 한다.

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Dead ended 모드에서 수소 재순환이 고분자전해질연료전지의 성능에 미치는 영향 (Effect of Hydrogen Recirculation on the Performance of Polymer Electrolyte Membrane Fuel Cell with Dead Ended Mode)

  • 김준섭;김준범
    • Korean Chemical Engineering Research
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    • 제57권4호
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    • pp.531-538
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    • 2019
  • 고분자전해질 연료전지(PEMFC)의 성능이 개선됨에 따라 생성물인 물과 열의 발생이 증가하고 이를 처리하기 위한 관리기법이 중요해지고 있다. 본 연구에서는 물 관리 기법으로 수소 재순환을 적용하였고, 수소 재순환 유량(flow rate)과 퍼지 간격(purge interval) 및 지속 시간(duration)이 연료전지의 성능에 미치는 영향에 대한 실험을 수행하였다. Purge 조건의 영향을 해석하기 위하여 수소극의 압력, 연료의 습도, 운전 간의 연료 이용 효율과 물 배출 양을 측정하였다. 수소 재순환 유량이 증가할수록 수소극 출구의 압력 저하로 인하여 스택 성능이 낮아졌다. Purge 조건에 따라서 물을 효과적으로 배출하지 못해 순간적인 전압 강하가 발생하거나 혹은 잦은 purge로 인해 수소극의 습도를 유지하지 못하여 성능이 점차적으로 감소하는 것을 확인하였다. Purge 조건 실험을 통하여 수소극의 습도를 유지하고 응축된 물을 충분히 배출할 수 있는 purge interval과 duration을 선정하였고, 이를 통하여 스택의 성능과 연료 이용 효율을 향상시킬 수 있었다.

100W 급 용융탄산염 연료전지 스택운전특성 (Operation Characteristics of 100W Class Molten Carbonate Fuel Cell Stack)

  • 임희천;이창우
    • 대한전기학회:학술대회논문집
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    • 대한전기학회 1994년도 하계학술대회 논문집 A
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    • pp.94-96
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    • 1994
  • To develop the 2kw class MCFC stack, preliminarly 3 cell and 10 cell stack having a $100cm^2$ effective electrode area were fabricated and tested. These stacks showed 30 W and 100 W of output respectively and average cell voltage of 0.734V at $150mA/cm^2$. The stack performance decreased with the increase of fuel utilization rate. In durability test of 10 cell stack, the performance was sharply decreased at the rate of 180mV/1000Hr during 720hours operation time.

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네트워크 배전계통용 통신기반 보호협조에 관한 연구 (A study of communication-based protection coordination for networked distribution system)

  • 김우현;채우규;황성욱;이학주
    • KEPCO Journal on Electric Power and Energy
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    • 제8권1호
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    • pp.43-48
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    • 2022
  • Although the distribution system has been structured as complicated as a mesh in the past, the connection points for each line are always kept open, so that it is operated as a radial distribution system (RDS). For RDS, the line utilization rate is determined according to the maximum load on the line, and the utilization rate is usually kept low. In addition, when a fault occurs in the RDS, a power outage of about 3 to 5 minutes occurs until the fault section is separated, and the healthy section is transferred to another line. To improve the disadvantages of the RDS, research on the construction of a networked distribution system (NDS) that linking multiple lines is in progress. Compared to the RDS, the NDS has advantages such as increased facility utilization, load leveling, self-healing, increased capacity connected to distributed generator, and resolution of terminal voltage drop. However, when a fault occurs in the network distribution system, fault current can flow in from all connected lines, and the direction of fault current varies depending on the fault point, so a high-precision fault current direction determination method and high-speed communication are required. Therefore, in this paper, we propose an accurate fault current direction determination method by comparing the peak value polarity of the fault current in the event of a fault, and a communication-based protection coordination method using this method.