• Title/Summary/Keyword: Volcanic process

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Mineralogical studies and extraction of some valuable elements from sulfide deposits of Abu Gurdi area, South Eastern Desert, Egypt

  • Ibrahim A. Salem;Gaafar A. El Bahariya;Bothina T. El Dosuky;Eman F. Refaey;Ahmed H. Ibrahim;Amr B. ElDeeb
    • Analytical Science and Technology
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    • v.37 no.1
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    • pp.47-62
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    • 2024
  • Abu Gurdi area is located in the South-eastern Desert of Egypt which considered as volcanic massive sulfide deposits (VMS). The present work aims at investigating the ore mineralogy of Abu Gurdi region in addition to the effectiveness of the hydrometallurgical route for processing these ores using alkaline leaching for the extraction of Zn, Cu, and Pb in the presence of hydrogen peroxide, has been investigated. The factors affecting the efficiency of the alkaline leaching of the used ore including the reagent composition, reagent concentration, leaching temperature, leaching time, and Solid /Liquid ratio, have been investigated. It was noted that the sulfide mineralization consists mainly of chalcopyrite, sphalerite, pyrite, galena and bornite. Gold is detected as rare, disseminated crystals within the gangue minerals. Under supergene conditions, secondary copper minerals (covellite, malachite, chrysocolla and atacamite) were formed. The maximum dissolution efficiencies of Cu, Zn, and Pb at the optimum leaching conditions i.e., 250 g/L NaCO3 - NaHCO3 alkali concentration, for 3 hr., at 250 ℃, and 1/5 Solid/liquid (S/L) ratio, were 99.48 %, 96.70 % and 99.11 %, respectively. An apparent activation energy for Zn, Cu and Pb dissolution were 21.599, 21.779 and 23.761 kJ.mol-1, respectively, which were between those of a typical diffusion-controlled process and a chemical reaction-controlled process. Hence, the diffusion of the solid product layer contributed more than the chemical reaction to control the rate of the leaching process. High pure Cu(OH)2, Pb(OH)2, and ZnCl2 were obtained from the finally obtained leach liquor at the optimum leaching conditions by precipitation at different pH. Finally, highly pure Au metal was separated from the mineralized massive sulfide via using adsorption method.

SPECIAL CONSIDERATION ON THE RADARSAT REPEAT-PASS SAR INTERFEROMETRY

  • Kim, Sang-Wan;Won, Joong-Sun;Moon, Wooil-M.
    • Proceedings of the KSRS Conference
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    • 1999.11a
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    • pp.474-478
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    • 1999
  • SAR interferometry (InSAR) using the space-borne Synthetic Aperture Radar (SAR) have recently become one of the most effective tools monitoring surface changes caused by landslides, earthquakes, subsidences or volcanic eruption. This study focuses on examining the feasibility of InSAR using the RADARSAT data. Although the RABARSAT SAR with its high resolution and variable incidence angle has several advantages for repeat-pass InSAR, it has two key limitations: first, the orbit is not precisely known; and second, RADARSAT's 24-day repeat pass interval is not very favourable for retaining useful coherence. In this study, two pairs of RADARSAT data in the Nahanni area, NWT, Canada have been tested. We will discuss about the special consideration required on the interferometric processing steps specifically for RADARSAT data including image co-registration, spectral filtering in both azimuth and range, estimation of the interferometric baseline, and correction of the interferogram with respect to the "flat earth" phase contribution. Preliminary results can be summarized as: i) the properly designed azimuth filter based upon the antenna characteristic improves coherence considerably if difference in Doppler centroid of the two images is relatively large; ii) the co-registration process combined by fringe spectrum and amplitude cross-correlation techniques results in optimal matching; iii) the baseline is not always possible to be estimated from the definitive orbit information.

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Two-Dimensional Particle Simulation for Behaviors of Floating Body near Quaywall during Tsunami (지진해일 중 해안안벽 주변의 부유체 거동에 관한 2차원 입자법 시뮬레이션)

  • Park, Ji-In;Park, Jong-Chun;Hwang, Sung-Chul;Heo, Jae-Kyung
    • Journal of Ocean Engineering and Technology
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    • v.28 no.1
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    • pp.12-19
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    • 2014
  • Tsunamis are ocean waves generated by movements of the Earth's crust. Several geophysical events can lead to this kind of catastrophe: earthquakes, landslides, volcanic eruptions, and other mechanisms such as underwater explosions. Most of the damage associated with tsunamis are related to their run-up onto the shoreline. Therefore, effectively predicting the run-up process is an important aspect of any seismic sea wave mitigation effort. In this paper, a numerical simulation of the behaviors of a floating body near a quaywall during a tsunami is conducted by using a particle method. First, a solitary wave traveling over shallow water with a slope is numerically simulated, and the results are compared with experiments and other numerical results. Then, the behaviors of floating bodies with different drafts are investigated numerically.

An Aanalysis of the Geotechnical Characteristics of the Uncemented Breccia at Kyeongju District (경주 지역 미고결 각력층의 공학적 특성 분석)

  • Yun Sung-Hak;Lee Kun;Sha Sang-Ho;Park Sei-Joo;Ra Il-woong;Cheon Yoon-chul;Cho Nam Jun
    • Proceedings of the KSR Conference
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    • 2005.05a
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    • pp.667-672
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    • 2005
  • The uncemented breccia consisted of conglomerate and breccia, which are not originated from volcanic clastics, shows wide variation of engineering properties depending on the characteristics of matrix of the uncemented breccia. These uncemented breccia have breccia and matrix irregularly distributed according to their depth and position. Clay minerals are also included in the matrix of these uncemented breccia, so they are expected to show expansive behavior and weakness against weathering process. In this study, the volumetric ratio of breccia on the cores had been calculated using digital image processing technique (performed on recovered core box and their sections). The 3-axial compressional strength test had been done with a shaping of rapid cooling method, and the shear strength (c, ${\phi}$) of uncemented breccia due to the breccia content had been calculated by applying BIMROCK model curve suggested by Goodman. A reliable analysis on the engineering properties of uncemented breccia had been also possible by using borehole density logging and borehole loading test for the accurate determination of the unit weight and the deformation constants deformation modulus.

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Genesis of Kaolin-Pyrophyllite Deposits in the Youngnam Area (영남지역 고령토-납석 광상의 성인 연구)

  • Sang, Ki-Nam
    • Economic and Environmental Geology
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    • v.25 no.2
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    • pp.101-114
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    • 1992
  • Occurrences of many kaolin-pyrophyllite deposits in the Youngnam area is related to the Late Cretaceous volcanic rocks, which are widely distributed through southern part from Tongnae-Yangsan to Miryang-Wolsung. The mode of occurrence and genesis of the kaolin-pyrophyllite deposits related to the volcanism was studied. This area is covered by andesitic rocks, rhyolite and rhyolitic welded tuff in ascending order. Lower most andesitic part is almost fresh. The altered rocks in the rhyolitic welded tuff can be classified into the following zones: silicified, pyrophyllite-kaolin, and argillic zone from the center part of ore deposit. The clay deposits occur as irregular massive, layer and funnel type about 5~20 m in width and is accompanied by thin diaspore bed outside of ore shoot. The clays chiefly consist of kaolinite, sericite, pyrophyllite, a little amount of diaspore, alunite, dumortierite, corundum and pyrite. The process of kaolinization-pyrophyllitization has a close relation to a local acidic hydrothermal solution originated from granitic rocks. Acidic hydothermal alteration occurrs mainly in the rhyolitic welded tuff. Initial solution containing $H_2S$ and others was oxidized near the surface and formed hydrothermal sulfuric acid solution.

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Magnetic Characteristics of TA19-1 and TA19-2 Seamounts in the Lau Basin, the South Western Pacific (남서태평양 라우분지 TA19-1 해산과 TA19-2 해산의 지자기 특성 연구)

  • Kim, Chang Hwan
    • Economic and Environmental Geology
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    • v.47 no.4
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    • pp.395-404
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    • 2014
  • We conducted the geophysical survey of possible hydrothermal vent sites at 2009, in the Lau Basin, the south western Pacific and analyzed the magnetic characteristics of TA19-1 and TA19-2 seamounts. TA19-1 is a cone-shaped seamount with a caldera summit. TA19-2 seamount is bigger and shows more complicated topography than TA19-1 seamount. TA19-2 has a large caldera, a summit in the west side of the caldera and several crests. Simple dipole anomalies with a high over the north and a low over the south occur in TA19-1 seamount. High magnetic anomalies are located in the northern flank and the summit of TA19-2 seamount and low anomalies around the summit and the caldera. The results of bathymetry and magnetic data suggest that TA19-2 seamount might have more complicated magmatic process than TA19-1. Low magnetization zones are located over the summit, the calderas and the caldera rims. The magnetization lows indicate that submarine hydrothermal vents, along faults and fracture zones, could have caused an alteration of magnetic minerals. The magnetization highs over the summit and the calderas might have been related with later magmatisms like volcanic sills, intrusions.

Estimation of Sediment Provenance Using Clay Mineral Composition in the Central Basin of the Ross Sea Continental Margin, Antarctica (남극 로스해 대륙주변부 중앙분지의 점토광물 조성을 통한 기원 추적)

  • Ha, Sangbeom;Khim, Boo-Keun;Colizza, Ester;Giglio, Federico;Koo, Hyojin;Cho, Hyen Goo
    • Ocean and Polar Research
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    • v.41 no.4
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    • pp.265-274
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    • 2019
  • To trace the provenance of fine-grained sediments in response to the growth and retreat of glaciers (i.e., Ross Ice Sheet) that affects the depositional process, various kinds of analyses including magnetic susceptibility, granulometry, and clay mineral composition with AMS 14C age dating were carried out using a gravity core KI-13-GC2 obtained from the Central Basin of the Ross Sea continental margin. The sediments mostly consist of silty mud to sand with ice-rafted debris, the sediment colors alternate repeatedly between light brown and gray, and the sedimentary structures are almost bioturbated with some faint laminations. Among the fine-grained clay mineral compositions, illite is highest (59.1-76.2%), followed by chlorite (12.4-21.4%), kaolinite (4.1-11.6%), and smectite (1.2-22.6%). Illite and chlorite originated from the Transantarctic mountains (metamorphic rocks and granitic rocks) situated to the south of the Ross Sea. Kaolinite might be supplied from the sedimentary rocks of Antarctic continent underneath the ice sheet. The provenance of smectite was considered as McMurdo volcanic group around the Victoria Land in the western part of the Ross Sea. Chlorite content was higher and smectite content was lower during the glacial periods, although illite and kaolinite contents are almost consistent between the glacial and interglacial periods. The glacial increase of chlorite content may be due to more supply of the reworked continental shelf sediments deposited during the interglacial periods to the Central Basin. On the contrary, the glacial decrease of smectite content may be attributed to less transport from the McMurdo volcanic group to the Central Basin due to the advanced ice sheet. Although the source areas of the clay minerals in the Central Basin have not changed significantly between the interglacial and glacial periods, the transport pathways and delivery mechanism of the clay minerals were different between the glacial and interglacial periods in response to the growth and retreat of Ross Ice Sheet in the Ross Sea.

Mineral Composition of the Tamna Formation, Jeju Island (제주도 탐라층의 구성광물)

  • Hyun, Weonhak;Hwang, Jinyeon;Lee, Jinhyun;Son, Byeongseo;Oh, Jiho;Yang, Kyounghee;Kim, Kwanghee
    • The Journal of the Petrological Society of Korea
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    • v.25 no.4
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    • pp.335-348
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    • 2016
  • The fluvial Tamna Formation, consisting of conglomerate, sandstone and mudstone layers, is widely distributed in Jeiu Island. Various sizes of quartz crystals were identified from most of the Tamna Formation, including the mudstone layer. XRD analysis also shows that the mudstone layer is composed of various minerals, quartz, plagioclase, K-feldspar, mica, magnetite, hematite, olivine, amphibole, gibbsite, calcite, analcime and clay minerals such as illite, kaolinite, vermiculite, smectite, chlorite, $10{\AA}$-halloysite. There is a tendency showing that the more amount of kaolinite, vermiculite, and chlorite is present where the more amount of quartz crystals is present. It is likely that the main source materials contributing to the Tamna Formation were from the parental rocks containing abundant quartz grains, suggesting that the Tamna Formation could not be related to Jeju volcanic rocks, but possibly to pre-existing basement rocks. Thus, we propose that the Tamna Formation was formed from the materials derived from both pre-existing basement rocks and Jeju volcanic rocks, which were subsequently affected by diagenesis, hydrothermal alteration and weathering process.

Scenario-based Flood Disaster Simulation of the Rim Collapse of the Cheon-ji Caldera Lake, Mt. Baekdusan (시나리오에 따른 백두산 천지의 외륜산 붕괴에 의한 홍수재해 모의)

  • Lee, Khil-Ha;Kim, Sang-Hyun;Choi, Eun-Kyeong;Kim, Sung-Wook
    • The Journal of Engineering Geology
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    • v.24 no.4
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    • pp.501-510
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    • 2014
  • Volcanic eruptions alone may lead to serious natural disasters, but the associated release of water from a caldera lake may be equally damaging. There is both historical and geological evidence of the past eruptions of Mt. Baekdusan, and the volcano, which has not erupted for over 100 years, has recently shown signs of reawakening. Action is required if we are to limit the social, political, cultural, and economic damage of any future eruption. This study aims to identify the area that would be inundated following a volcanic flood from the Cheon-Ji caldera lake that lies within Mt. Baekdusan. A scenario-based numerical analysis was performed to generate a flood hydrograph, and the parameters required were selected following a consideration of historical records from other volcanoes. The amount of water at the outer rim as a function of time was used as an upper boundary condition for the downstream routing process for a period of 10 days. Data from the USGS were used to generate a DEM with a resolution of 100 m, and remotely sensed satellite data from the moderate-resolution imaging spectroradiometer (MODIS) were used to show land cover and use. The simulation was generated using the software FLO-2D and was superposed on the remotely sensed map. The results show that the inundation area would cover about 80% of the urban area near Erdaobaihezhen assuming a 10 m/hr collapse rate, and 98% of the area would be flooded assuming a 100 m/hr collapse rate.

Volcanological History of the Baengnokdam Summit Crater Area, Mt. Halla in Jeju Island, Korea (제주도 한라산 백록담 일대의 화산활동사)

  • Ahn, Ung San;Hong, Sei Sun
    • The Journal of the Petrological Society of Korea
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    • v.26 no.3
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    • pp.221-234
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    • 2017
  • The Baengnokdam, the summit crater of Mt. Halla, is one of the representative geosites of World Natural Heritage and Global Geopark in Jeju Island. The crater is marked by two distinctive volcanic lithofacies that comprise: 1) a trachytic lava dome to the west of the crater and 2) trachybasaltic lava flow units covering the gentle eastern slope of the mountain. This study focuses on understanding the formative process of this peculiar volcanic lithofacies association at the summit of Mt. Halla through field observation and optically stimulated luminescence (OSL) dating of the sediments underlying the craterforming volcanics. The trachyte dome to the west of the crater is subdivided into 3 facies units that include: 1) the trachyte breccias originating from initial dome collapse, 2) the trachyte lava-flow unit and 3) the domal main body. On the other side, the trachybasalt is subdivided into 2 facies units that include: 1) the spatter and scoria deposit from the early explosive eruption and 2) lava-flow unit from the later effusion eruption. Quartz OSL dating on the sediments underlying the trachyte breccias and the trachybasaltic lava-flow unit reveals ages of ca. 37 ka and ca. 21 ka, respectively. The results point toward that the Baengnokdam summit crater was formed by eruption of trachybasaltic magma at about 19~21 ka after the trachyte dome formed later than 37 ka.