• Title/Summary/Keyword: Volatile matters

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Selection of Particulate Matter Observation Measurement Sites in Urban Forest Using Wind Analysis (바람장 분석을 통한 도시숲 미세먼지 관측 장비 설치 지점 선정)

  • Lee, Ahreum;Jeong, Su-Jong;Park, Chan-Ryul;Park, Hoonyoung;Yoon, Jongmin;Son, Junghoon;Bae, Yeon
    • Atmosphere
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    • v.29 no.5
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    • pp.689-698
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    • 2019
  • Air pollution in urban areas has become a serious problem in the recent years. Especially, high concentrations of particulate matter (PM) cause negative effects on human health. Several studies suggest urban forest as a tool for improving air quality because of the capability of forests in reducing PM concentrations through deposition and adsorption using leaf area. For this reason, the National Institute of Forest Science plans to install in-situ observation stations for PM and biogenic volatile organic compounds (BVOCs) on a national scale to verify the net effect of forests on urban air pollution. To measure the quantitative change of PM concentrations due to the urban forest, stations should be located within and outside the forest area with respect to atmospheric circulation. In this study, we analyze the wind direction at the potential measurement sites to assess suitable locations for detecting the effect of urban forests on air quality in five cities (i.e. Gwangju, Daegu, Busan, Incheon, and Ilsan). This technical note suggests effective locations of in-situ measurements by considering main wind direction in the five cities of this study. A measurement station network created in the future based on the selected locations will allow quantitative measurements of PM concentration and BVOCs emitted from the urban forest and help provide a comprehensive understanding of the forest capabilities of reducing air pollution.

The Characteristics of Groundwaters in Taegu City (대구시 지하수의 수질특성)

  • Park Byung-Yoon;Cheon Kyung-Ah;Lee Dong-Hoon;Choi Choong-Ryeol;Choi Jyung;Kim Jin-Ho
    • Journal of Environmental Science International
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    • v.8 no.6
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    • pp.685-690
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    • 1999
  • The pollution characteristics of groundwaters in Taegu City and correlation coefficients(r) between water pollution indicators were investigated for two years from January 1996 to December 1997. Volatile organic compounds such as TCE(tri-chloroethylene), PCE(tetrachloroethylene), l,l,l-trichloroethane, THM(trihalo-methane), dichloromethane, pesticides such as diazinon, parathion, malathion, and toxic inoganic matters such as As, Hg, Se, Pb, Cd, $Cr_6^+,$ CN were not detected in the groundwaters. Mean values of groundwater pollution indicators were below drinking-water standards, but hardness, $KMnO_4-C(potassium$ permanganate consumption), evaporate residues, $SO_4^{-2},\;Fe,\;NO_3^{-}-N,$ color and turbidity exceeded a little in some samples. As groundwater became deeper, hardness and evaporate residues remarkably increased, but $KMnO_4-C,\;NO_3^{-}-N,\;Cl-,$ color, turbity and bacteria decreased. $KMnO_4-C,$ evaporate residues, $Cl^-\;and\;SO_4^{-2}$ were very high at industrial and commercial areas, and $NO_3^--N$ and $NH_4^+-N$ were very high at agricultural and forest areas. It showed high positive significances in the relationships between hardness and each of evaporate residues, $SO_4^{-2}$, Zn and Mn, $KMnO_4-C$ and each of color, turbidity and Zn, color and each of turbidity, Cu, Zn and Mn, turbidity and each of Fe, Cu, Zn and Mn, and evaporate residues and each of $Cl^-,\;SO_4^{-2}$ and Zn.

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Efficient Anaerobic Digestion for Highly Concentrated Particulate Organic Wastewater (고농도 입자성 유기폐수의 고효율 혐기성 소화 공정)

  • Lee, Sungbum;Shin, Kyuchul;Kim, Huijoo;Kim, Hyunju;Choi, Changkyoo;Kim, Moonil
    • Journal of the Korean GEO-environmental Society
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    • v.9 no.2
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    • pp.23-29
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    • 2008
  • It has been mentioned that CSTR (Completely Stirred Tank Reactor) and UASB (Upflow Anaerobic Sludge Blanket) processes, the existing anaerobic processes, have problems in the treatment of highly concentrated particulate organic wastewater (HCPOW). Therefore, this paper discusses the treatment possibility of distillery wastewater which is a typical HCPOW using ADEPT (anaerobic Digestion Elutriated Phased Treatment) process. In the comparison of CSTR and ADEPT, ADEPT produced much higher gas than that of CSTR removing more organic matters and suspended solids in ADEPT process, ADEPT had no effect on the decrease in pH by volatile fatty acids and showed steady pH in spite of relatively short HRT. In the results of removal rate according to recycle ratios between 6Qin and 2Qin in ADEPT, 6Qin showed high removal rate during the operation time. Therefore it appears that ADEPT had an applicability for the treatment of distillery wastewater. ADEPT could be a economical process, due to the short HRT, the energy recovery by the methane production, and the utilization for carbon source of produced organic acid from the ADEPT-acid reactor.

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Recovery of Precious Metals from Spent Catalyst Generated in Domestic Petrochemical Industry (한내 석유화학 폐촉매로부터 귀금속의 회수 연구)

  • 김준수;박형규;이후인;김성돈;김철주
    • Resources Recycling
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    • v.3 no.1
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    • pp.17-24
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    • 1994
  • Recovery of precious metal values from petrochemical spent catalyst is important from the viewpoint of environmental protection and resource recycling. Two types of spent catalysts were used in this study. One used in the manufacture of ethylene contains 0.3% Pd in the alumina substrate. The other used in oil refining contains 0.3% Pt and 0.3% Re. Both spent catalysts are roasted to remove volatile matters as carbon and sulfur. Then, metallic Pd powder from Pd spent catalyst is obtained in the course of grinding, hydrochloric acid or aqua regia leaching and cementation with iron. For the recovery of Pt and Re from Pt-Re spent catalyst, Pt and Re are leached with either HCI or aqua regia, first. Metallic Pt powder is recovered from the leach solution by cementation with Fe powder. Re in sulfide form is precipitated by the addition of sodium sulfide to the solution obtained after Pt recovery. It is found that 6N HCI can be successfully used as leaching agent for both types of spent catalyst. 6N HCI is considered to be better than aqua regia in consideration of reagent and equipment cost.

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Monitoring of the Treatment of Leachate by Two Phase Anaerobic Membrane Process (TPAMP) (이상 혐기성 막공정에 의한 침출수 처리 모니터링)

  • Hwang, Moon H.;Hyun, Seong H.;Jang, Nam J.;Cho, Jea W.;Kim, In S.
    • Journal of Korean Society on Water Environment
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    • v.18 no.2
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    • pp.151-157
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    • 2002
  • Landfill leachate is one of highly contaminated and heterogeneous wastewater. The leachate from initial landfill can be treated by anaerobic process because it contains biodegradable matters, particularly, volatile fatty acids (VFAs). However, the anaerobic treatment of leachate is generally required longer hydraulic retention time (HRT) than aerobic process and another treatment process to satisfy effluent concentration. Therefore the modification of conventional anaerobic treatment is needed. Two phase anaerobic membrane process (TPAMP) is an integrated membrane process to be able to separate anaerobic metabolism into two phase which are acidogenesis and methanogenesis for improvement of anaerobic treatment efficiency. In this study, the efficiency of TPAMP and conventional anaerobic treatment were compared in terms of HRT, effluent SCOD, VFAs Membrane used in TPAMP was the UF of capillary type with the surface area of $0.048m^2$. The average effluent SCOD of conventional anaerobic treatment was 1352 mg/L and the removal was 96 % at HRT 60 days, while in TPAMP, 927 mg/L and 98% at HRT 30 days.

Emission Characteristics of Air Pollutants and Black Carbon from Wood-pellet Stove and Boiler (목재 펠릿 난로와 보일러 사용에 의한 대기오염물질과 블랙카본의 배출 특성)

  • Park, Sung Kyu;Lyu, Kun Jung;Kim, Daekeun;Kim, Dong Young;Jang, Young Kee;Jeon, Eui Chan
    • Journal of Climate Change Research
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    • v.6 no.1
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    • pp.41-47
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    • 2015
  • This study was carried out simulating domestic utilization conditions of a wood pellet stove and a wood pellet boiler in order to determine emission factors (EFs) of macro-pollutants, i.e., carbon monoxide, nitrogen oxides, sulfur oxides, ammonia, particulate matters (total suspended particulate, $PM_{10}$, $PM_{2.5}$, black carbon) and trace pollutants (i.e., ten different volatile organic compounds). The composite pollutants EFs for the pellet stove were: for TSP 4.58 g/kg, for $PM_{10}$ 3.35 g/kg, for $PM_{2.5}$ 2.48 g/kg, CO 119.23 g/kg, NO 14.40 g/kg, $SO_2$ 0.17 g/kg, TVOC 37.73 g/kg, $NH_3$ 0.02 g/kg and emissions were similar to the pellet boiler appliance: for TSP 4.73 g/kg, for $PM_{10}$ 3.41 g/kg, for $PM_{2.5}$ 2.63 g/kg, CO 161.51 g/kg, NO 13.67 g/kg, $SO_2$ 0.19 g/kg, TVOC 45.22 g/kg, $NH_3$ 0.02 g/kg.

Emission Characteristics of Air Pollutants and Black Carbon from Wood Stove and Boiler (화목 난로와 보일러 사용에 의한 대기오염물질과 블랙카본의 배출 특성)

  • Park, Sung Kyu;Choi, Sang Jin;Kim, Dae keun;Kim, Dong Young;Jang, Young Kee;Jeon, Eui Chan
    • Journal of Climate Change Research
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    • v.6 no.1
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    • pp.49-54
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    • 2015
  • Manually fed firewood burning appliances, i.e., stove and boiler, were tested in order to determine emission factors (EFs) of macro-pollutants, i.e., carbon monoxide, nitrogen oxides, sulfur oxides, ammonia, particulate matters (total suspended particulate, $PM_{10}$, $PM_{2.5}$, black carbon) and trace pollutants (i.e., ten different volatile organic compounds). The composite pollutants EFs for the wood stove were: for TSP 15.45 g/kg, for $PM_{10}$ 6.53 g/kg, $PM_{2.5}$ 4.16 g/kg, CO 175.49 g/kg, NO 1.58 g/kg, $SO_2$ 0.15 g/kg, TVOC 48.02 g/kg, $NH_3$ 0.02 g/kg and emissions were similar to the wood boiler appliance: for TSP 12.23 g/kg, for $PM_{10}$ 5.84 g/kg, $PM_{2.5}$ 3.66 g/kg, CO 146.74 g/kg, NO 1.42 g/kg, $SO_2$ 0.15 g/kg, TVOC 47.78 g/kg, $NH_3$ 0.01 g/kg.

The Spatio-temporal Distribution of Organic Matter on the Surface Sediment and Its Origin in Gamak Bay, Korea (가막만 표층퇴적물중 유기물량의 시.공간적 분포 특성)

  • Noh Il-Hyeon;Yoon Yang-Ho;Kim Dae-Il;Park Jong-Sick
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.9 no.1
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    • pp.1-13
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    • 2006
  • A field survey on the spatio-temporal distribution characteristics and origins of organic matter in surface sediments was carried out monthly at six stations in Gamak Bay, South Korea from April 2000 to March 2002. The range of ignition loss(IL) was $4.6{\sim}11.6%(7.1{\pm}1.6%)$, while chemical oxygen demand(CODs) ranged from $12.25{\sim}99.26mgO_2/g-dry(30.98{\pm}19.09mgO_2/g-dry)$, acid volatile sulfide(AVS) went from no detection(ND)${\sim}10.29mgS/g-dry(1.02{\pm}0.58mgS/g-dry)$, and phaeopigment was $6.84{\sim}116.18{\mu}g/g-dry(23.72{\pm}21.16{\mu}g/g-dry)$. The ranges of particulate organic carbon(POC) and particulate organic nitrogen(PON) were $5.45{\sim}23.24 mgC/g-dty(10.34{\pm}4.40C\;mgC/g-dry)$ and $0.71{\sim}2.99mgN/g-dry(1.37{\pm}0.58mgN/g-dry)$, respectively. Water content was in the range of $43.1{\sim}77.6%(55.8{\pm}5.6%)$, and mud content(silt+clay) was higher than 95% at all stations. The spatial distribution of organic matter in surface sediments was greatly divided between the northwestern, central and eastern areas, southern entrance area from the distribution characteristic of their organic matters. The concentrations of almost all items were greater at the northwestern and southern entrance area than at the other areas in Gamak Bay. In particular, sedimentary pollution was very serious at the northwestern area, because the area had an excessive supply of organic matter due to aquaculture activity and the inflow of sewage from the land. These materials stayed longer because of the topographical characteristics of such as basin and the anoxic conditions in the bottom seawater environment caused by thermocline in the summer. The tendency of temporal change was most prominently in the period of high-water temperatures than low-water ones at the northwestern and southern entrance areas. On the other hand, the central and eastern areas did not show a regular trend for changing the concentrations of each item but mainly showed a higher tendency during the low-water temperatures. This was observed for all but AVS concentrations which were higher during the period of high-water temperature at all stations. Especially, the central and eastern areas showed a large temporal increase of AVS concentration during those periods of high-water temperature where the concentration of CODs was in excess of $20mgO_2/g-dry$. The results show that the organic matters in surface sediments in Gamak Bay actually originated from autochthonous organic matters with eight or less in average C/N ratio including the organic matters generated by the use of ocean, rather than terrigenous organic matters. However, the formation of autochthonous organic matter was mainly derived from detritus than living phytoplankton, indicated the results of the POC/phaeopigment ratio. In addition, the CODs/IL ratio results demonstrate that the detritus was the product of artificial activities such as dregs feeding and fecal pellets of farm organisms caused by aquaculture activities rather than the dynamic of natural ocean activities.

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Study of Oil Palm Biomass Resources (Part 3) - Torrefaction of Oil Palm Biomass - (오일팜 바이오매스의 자원화 연구 III - 오일팜 바이오매스의 반탄화 연구 -)

  • Cho, Hu-Seung;Sung, Yong Joo;Kim, Chul-Hwan;Lee, Gyeong-Seon;Yim, Su-Jin;Nam, Hyeo-Gyeong;Lee, Ji-Young;Kim, Se-Bin
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.46 no.1
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    • pp.18-28
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    • 2014
  • Renewable Portfolio Standards(RPS) is a regulation that requires a renewable energy generated from eco-friendly energy sources such as biomass, wind, solar, and geothermal. The RPS mechanism generally is an obligatory policy that places on electricity supply companies to produce a designated fraction of their electricity from renewable energies. The domestic companies to supply electricity largely rely on wood pellets in order to implement the RPS in spite of undesirable situation of lack of wood resources in Korea. This means that the electricity supply companies in Korea must explore new biomass as an alternative to wood. Palm kernel shell (PKS) and empty fruit bunch (EFB) as oil palm wastes can be used as raw materials used for making pellets after their thermochemical treatment like torrefaction. Torrefaction is a pretreatment process which serves to improve the properties including heating value and energy densification of these oil palm wastes through a mild pyrolysis at temperature typically ranging between 200 and $300^{\circ}C$ in the absence of oxygen under atmospheric pressure. Torrefaction of oil palms wastes at above $200^{\circ}C$ contributed to the increase of fixed carbon with the decrease of volatile matters, leading to the improvement of their calorific values over 20.9 MJ/kg (=5,000 kcal/kg) up to 25.1 MJ/kg (=6,000 kcal/kg). In particular, EFB sensitively responded to torrefaction because of its physical properties like fiber bundles, compared to PKS and hardwood chips. In conclusion, torrefaction treatment of PKS and EFB can greatly contribute to the implement of RPS of the electricity supply companies in Korea through the increased co-firing biomass with coal.

Environmental Characteristics and Distributions of Marine Bacteria in the Surface Sediments of Kamak Bay in Winter and Summer (동 . 하계 가막만 표층 퇴적물의 환경특성과 해양미생물의 분포)

  • Lee, Dae-Sung;Kim, Yun-Sook;Jeong, Seong-Yun;Kang, Chang-Keun;Lee, Won-Jae
    • Journal of Environmental Science International
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    • v.17 no.7
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    • pp.755-765
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    • 2008
  • To investigate correlation between the distribution of marine bacteria and environmental characteristics in the surface sediments of Kamak Bay, chemical oxygen demand(COD), acid volatile sulfide(AVS), ignition loss(IL), total organic carbon(TOC), and total organic nitrogen(TON) were measured and analyzed at 7 stations in winter and summer. In winter, COD and AVS ranged from 13.45 mg/g to 30.06 mg/g(average: 23.58 mg/g) and from 0.03 mg/g to 1.04 mg/g(average: 0.63 mg/g), respectively. IL, TOC, and TON ranged from 8.03% to 11.41%(average: 9.41%), from 1.17% to 2.10%(average: 1.62%), and from 0.09% to 0.18%(average 0.15%), respectively. In summer, COD, AVS, IL, TOC, and TON ranged from 14.06 mg/g to 32.19 mg/g(average: 24.71 mg/g), from 0.03 mg/g to 1.11 mg/g(average: 0.66 mg/g), from 9.00% to 12.15%(average: 10.96%), from 1.27% to 2.12%(average 1.77%), and from 0.12% to 0.19%(average: 0.16%), respectively. These values were relatively higher than those in winter. Kamak Bay had high C/N ratio that might be resulted from the input of terrestrial sewage and industrial wastewater. The number of marine viable bacteria was $8.9{\times}10^4\;cfu/g$ in winter and $9.7{\times}10^5\;cfu/g$ in summer. The most abundant species were Pseudomonas spp., Flavobacterium spp., and Vibrio spp, in the surface sediments of Kamak Bay. It was found that the concentration of organic matters and viable bacterial cells in the inner part were relatively higher than those in the outer of Kamak Bay. The distribution of viable bacterial cells was closely influenced by environmental factors.