• Title/Summary/Keyword: Volatile contamination

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Numerical Simulation and Experimental Study on an Ejector System for VOC Recovery (VOC 회수를 위한 이젝터 시스템에 관한 수치모사 및 실험적 연구)

  • Kim, Hyun-Dong;Lee, Dong-Yeop;Kim, Yoon-Kee;Jeong, Won-Taek;Ahn, Joo-Ha;Kim, Kyung-Chun
    • Journal of the Korean Society of Visualization
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    • v.9 no.2
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    • pp.54-60
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    • 2011
  • This paper is a basic study on volatile organic compounds(VOC) recovery system in a crude oil carrier. VOC is easily evaporated in cargo tankers during loading and transportation of crude oil, causes serious environmental contamination and a huge economic loss. An ejector system is designed to mix VOC gas into crude oil flow to reduce VOC concentration. Detail two-phase flow inside the ejector is simulated using a commercial CFD code. To verify the numerical prediction, a scale-down experiment is conducted. Instead of crude oil and VOC, water and air are used as the working fluids. Flow characteristics and main parameters are obtained by two-phase flow visualization and PIV measurements. Air volume flow rate induced by the ejector is compared with respect to the volume flow rate of water using experimental and numerical results. Overall performance of the two-phase ejector predicted by the CFD simulation agrees well with that of the experiment.

Comparison between Head Space Gas Sampling and Purge & Trap Sampling in Water Analysis

  • Nagayanagi, Yutaka;Nakagawa, Katsuhiro;Saito, Yoshihiro;Kim, Poongzag
    • Analytical Science and Technology
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    • v.8 no.4
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    • pp.739-744
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    • 1995
  • The two main methods to prepare water samples for analyzing volatile organic compounds(VOC's) were investigated. One is the purge and trap(PT) method and another is the head space(HS) sampling method. Both methods were effective to transfer the low boiling point components from the water sample onto the capillary column. The cryo-focusing at the top of the main capillary column was an effective way to obtain the sharpness of the chromatographic peaks but could be avoided when a semi-wide bore column was used. The recovery from the same amount of the sample was better in PT than in HS but a larger sample volume in HS method could compensate the lower efficiency. Therefore PT is suitable to the analysis of drinking water where the very low concentration must be determined. HS is suitable to waste water analysis because of the easiness of the operation. The repeatability was good and similar in both methods. For the contamination of the former sample, both methods were tough and could be used without any problems. The matrix effect which could change the equilibrium parameters in HS method was find negligible in many components. The actual samples such as tap water and river water were analyzed with both methods concerning 16 components regulated in Korea.

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A Study on the Concentration Variations of VOCs and Formaldehyde on the Type of Interior Materials of New Vehicles by Simulation Program (시뮬레이션 프로그램을 이용한 신규 차량의 인테리어 물질에 따른 VOC와 폼알데히드의 농도 변화에 관한 연구)

  • Yi, Young-Seop;Kim, In-Bum;Ko, Won-Kyoung
    • Journal of the Korean Society of Safety
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    • v.27 no.3
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    • pp.89-95
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    • 2012
  • The concentrations of Volatile Organic Compounds(VOCs) and Formaldehyde(HCHO) for interior materials of new vehicles are estimated and recognized by using the simulation program known as IAQx. The concentrations of contaminants are estimated and evaluated by the ventilation rates of new domestic vehicles and the required ventilation rates for new vehicles are estimated through the given contaminant data. This study is conducted to compare the ventilation rates for the contaminants between the discontinuously ventilated new vehicles and the continuously ventilated new vehicles using the simulation program. The equation of ventilation rate of new vehicles is acquired to be able to lower initial concentrations below the standard level under different conditions for both business and personal commuting.

A Study on the Optimal Flash-Point of WDF Production (유화유 생산의 적정 인화점에 관한 연구)

  • Lee, Jin;Kim, Hwaseong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.33 no.4
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    • pp.310-314
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    • 2020
  • Although waste oil derived fuel (WDF) production technology was developed under a government initiative ~10 years ago, it became stagnant owing to the small size of participating companies, residents' rejection of foul odor, and the nature of the technology for recycling waste that was avoided. However, this subject is under the spotlight again because of recent developments, such as garbage crisis. In particular, plastic is the most difficult waste to dispose of, with more than 4 million tons of plastic waste produced every year according to statistics from the Ministry of Environment. The most effective method for treating plastic waste is to produce WDF through low temperature thermal decomposition. The WDF includes several volatile ingredients that mostly limit the use of fuel for boilers, owing to safety concerns. In particular, flash point is legally stipulated because of secondary contamination in the distribution process and the risk of fire and explosion. It is required that external shipments (distribution) should be maintained in the range of at least 30~60℃ (excluding explosion prevention facilities) for diesel power generation. Therefore, this study seeks to find the flash point that is best suited to WDFs produced from plastic waste.

Effect of the Atmospheric Exposome on the Skin (대기 중 엑스포좀이 피부에 미치는 영향)

  • Song, Mee;Baek, Ji Hwoon
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.47 no.3
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    • pp.185-191
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    • 2021
  • Environmental pollution is defined as contamination of the earth's environment with materials which interfere with human health, quality of life, or the natural functioning of the ecosystem. Whenever a prolonged and repetitive exposure to environmental stressors exceeds the skin's normal defensive potential, there is a disturbance in the skin barrier function leading to the development of various skin diseases. Major air pollutants which affect the skin are polycyclic aromatic hydrocarbons, volatile organic compounds, nitrogen oxides, particulate matter, cigarette smoke, heavy metals and arsenic. Dermal uptake depends on the deposition of air pollutants on the skin surface, the composition of epidermal lipids, and the diffusion through the epidermis to the blood vessels.

Characteristics of Domestic and Imported Red Wines (국산 및 수입 적포도주의 품질특성)

  • Chang, Eun-Ha;Jeong, Seok-Tae;Park, Kyo-Sun;Yun, Hae-Keun;Roh, Jeong-Ho;Jang, Han-Ik;Choi, Jong-Uck
    • Food Science and Preservation
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    • v.15 no.2
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    • pp.203-208
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    • 2008
  • This study was conducted to evaluate quality of domestic wines, with a long-tenn goal of improving their quality. We compared the characteristics of 19 domestic and imported red wines. The titratable acidity of imported wines ranged from 0.5-0.6% and that of domestic wines ranged from 0.4-0.8%. The sugar content of domestic wines ranged from 4-10% whereas all imported wines had a sugar content below 1.0%. Red color value and tannin contents were generally high in imported wines and some domestic wines had similar tannin levels. For ratio of total sulfite contents below 10 mg/L, domestic wines were higher with 36.8% than imported wines with 5%. Volatile acid contents were higher in domestic wines than in imported wines, which may be due to contamination of domestic wines by acetic acid bacteria.

Adsorption Characteristics of Heavy Metal and VOCs of Pyrolysis Char from Organic Waste Sludge (유기성 폐슬러지의 열분해 차르에 대한 중금속 및 VOCs 흡착특성)

  • Park, Sang-Sook;Kang, Hwa-Young
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.2
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    • pp.130-137
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    • 2005
  • This research programme include investigation of the adsorption behavior of heavy metals and VOCs by Pyrolysis char for using landfill cover material. The volatile potions in the sludge gasified during the pyrolysis period and gave birth to porosity throughout the matrix. The result of the ad/desorption experiment of nitrogen to find out the formation of some pore by the gasification of the volatile matter, we can certify that the pyrolysis char($14.56\;m^2/g$) has increased twice more than the organic wasted sludge($6.68\;m^2/g$) in specific surface area. The pyrolysis char has the adsorption characteristic of medium type of Type II and V in BDDT classification, and showed a little micro pore. In the adsorption experiment of ethylbenzene and toluene, as a result of applying the Freundlich adsorption isotherms, the pyrolysis char was higher in the adsorptivity of ethylbenzene and toluene than the granite and the organic wasted sludge. The results of the heavy metal adsorption test for the char indicated that it had some ability of adsorption. It is suggest that pyrolysis char has some advantages for utilizing as landfill covers because the pyrolysis char can adsorb/absorb hazardous substances from the landfill sites and inhibit the ground water and soil contamination.

Tendency of the indoor pollutants along with increased dwelling period at new apartments (거주기간 증가에 따른 신축 공동주택의 실내오염도 변화추이)

  • Jang, Seong Ki;Ryu, Jung Min;Seo, Soo Yun;Lim, Jung Yeon;Lee, Woo Seok
    • Analytical Science and Technology
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    • v.20 no.6
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    • pp.453-459
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    • 2007
  • This study is for investigation of indoor conditions with air contamination after occupation 120 households in brand-new apartments by measuring the concentration of VOCs and carbonyl compounds. It has been found that TVOC (total volatile organic compounds; TVOCs) were $688.61{\mu}g/m^3$ after moving in. And formaldehyde, toluene, m, p-xylene, acetone and ethylbenzene were $158.56{\mu}g/m^3$, $146.58{\mu}g/m^3$, $69.28{\mu}g/m^3$, $63.80{\mu}g/m^3$ and $29.65{\mu}g/m^3$, respectively. The mean concentrations of indoor air pollutants tend to decrease along an increase dwelling period. But, the mean concentration of d-limonene increased from 2 months to 10 months. Also, toluene, ethylbenzene, m, p, o-xylene amounted to 38.8 % among VOCs studied, this ratio tend to decrease along with and increased dwelling period.

Concentrations of VOCs in Groundwater Associated with Land Uses in Ulsan Area (토지이용에 따른 울산지역 지하수의 VOCs 함량 특성)

  • Yun Uk;Cho Byong-Wook
    • Economic and Environmental Geology
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    • v.37 no.6 s.169
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    • pp.613-629
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    • 2004
  • Contamination of groundwater by volatile organic compounds (VOCs) was investigated for 168 groundwater wells in Ulsan area to study the natural attenuation of organic compounds in the aquifers. As groundwater contamination by VOCs is closely related to land use, 168 groundwater samples were classified into 4 different groups; agricultural, forestry, industrial, and residential & business. From analysis 65 out of 168 groundwater samples contained more than one VOC. Analysis of samples were performed fir 36 halogenated aliphatic hydrocarbons and 25 petroleum hydrocarbons set up by NAWQA of US geological survey. Twelve petroleum hydrocarbons were detected in 26 groundwater wells, but their concentrations were less than 1.5 g/L except for MTBE. Twenty three chlorinated aliphatic hydrocarbons, composed of 11 methanes, 6 ethanes and 6 ethenes, were detected in 63 groundwater samples. The range of methanes concentration was $ND\~330\;/gL,\;ethanes\;ND\~84\;gL$, and PCE and their derivatives $ND\~62\;g/L$. As the study area was comprised of the aerobic/denitrification zones and $Fe^{+3}$ redox condition, most of petroleum hydrocarbons were degraded well, while halogenated hydrocarbons were slowly biodegradation.

Influence of various concentrations of aflatoxin B1 on in vitro rumen fermentation of a buffalo diet

  • Singh, Ram;Park, Sungkwon;Koo, Jin Su;Balasubramanian, Balamuralikrishnan
    • Korean Journal of Agricultural Science
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    • v.47 no.1
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    • pp.131-138
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    • 2020
  • The aim of this study was to evaluate the effect of aflatoxin B1 (AFB1) on in vitro rumen fermentation at various dose levels of 0 (T1), 100 (T2), 200 (T3), and 300 (T4) ppb in a wheat straw-based buffalo diet. The results show that the truly degradable dry matter, truly degradable organic matter, gas production, microbial biomass production and partitioning factor values in the control group (T1) were higher (p < 0.05) than those of the T2, T3, and T4 groups. The total volatile fatty acids, acetate, propionate, and butyrate values in the control group (T1) were higher (p < 0.05) than those of the T2, T3, and T4 groups. The partitioning factor value in the control group (T1) was higher (p < 0.05) than those of the T2, T3, and T4 groups. The partitioning factor values of the T2 and T3 groups were higher (p < 0.05) than that of the T4 group. There was no significant variation in the partitioning factor value between the T2 and T3 group. The acetate : propionate (A : P) ratio in the control group (T1) was lower (p < 0.05) than those of the T2, T3, and T4 groups. The A : P ratio in the T2 group was lower (p < 0.05) than those of the T3 and T4 groups. It was concluded that different levels of AFB1 contamination in feed significantly affect the in vitro rumen fermentation characteristics. Thus, these findings could help to determine the influences of AFB1 in a wheat straw-based buffalo diet. Additionally, it is necessary to manage AFB1 contamination in ruminants.