• Title/Summary/Keyword: Volatile contamination

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Dependence of cation ratio in Oxynitride Glasses on the plasma etching rate

  • Lee, Jung-Ki;Hwang, Seong-Jin;Lee, Sung-Min;Kim, Hyung-Sun
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2009.11a
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    • pp.44.2-44.2
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    • 2009
  • Polycrystalline materials suchas yttria and alumina have been applied as a plasma resisting material for the plasma processing chamber. However, polycrystal line material may easily generate particles and the particles are sources of contamination during the plasma enhanced process. Amorphous material can be suitable to prevent particle generation due to absence of grain-boundaries. We manufactured nitrogen-containing $SiO_2-Al_2O_3-Y_2O_3$ based glasses with various contents of silicon and fixed nitrogen content. The thermal properties, mechanical properties and plasma etching rate were evaluated and compared for the different composition samples. The plasma etching behavior was estimated using XPS with depth profiling. From the result, the plasma etching rate highly depends on the silicon content and it may results from very low volatile temperature of SiF4 generated during plasma etching. The silicon concentration at the plasma etched surface was very low besides the concentration of yttrium and aluminum was relatively high than that of silicon due to high volatile temperature of fluorine compounds which consisted with aluminum and yttrium. Therefore, we conclude that the samples having low silicon content should be considered to obtain low plasma etching rate for the plasma resisting material.

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VOCs Emission Characteristics of Coating Materials for Wood Finishing (목재용 마감도료의 휘발성유기화합물 방출특성)

  • Park, Sang-Bum;Lee, Min;Lee, Sang-Min;Kang, Yeong-Seok
    • Journal of the Korea Furniture Society
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    • v.26 no.1
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    • pp.22-30
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    • 2015
  • In order to prevent decay, distortion, bending, twist on wood products such as wooden furnitures, variety of coating materials were developed and used so far. The coating materials for wood finishing can be synthesized by natural resource or petroleum. However, these coating materials can cause contamination of indoor air quality due to emission of volatile organic compounds (VOCs). In this study, commercialized coating materials for wood finishing such as varnish, coat, and stain were evaluated on emission characteristics of VOCs. Among the varnish, eco-friendly products had about 15~46% lower TVOC emission ($1,042{\mu}g/m^2h{\sim}3,257{\mu}g/m^2h$, respectively, than typical product ($7,100{\mu}g/m^2h$). Natural resource based coating material showed lowest TVOC emission level. However, one of natural resource based waterborne stain showed higher TVOC emission level because waterborne stain already contained higher amount of natural VOC. Oil-based stain might not be suitable for indoor use on interior wall and furniture due to exceed amount of TVOC. Based on results, natural resource based coat or waterborne stain are recommenced to use on wood products.

NUMERICAL STUDY ON PERFORMANCE ASSESSMENT AND INSTALLATION CONDITIONS OF AN AUTOMOTIVE AIR CLEANER (자동차용 공기청정기의 성능 평가 및 설치 조건 도출을 위한 수치해석적 연구)

  • Lee, Y.H.;Seo, J.W.;Park, J.H.;Choi, Y.H.
    • 한국전산유체공학회:학술대회논문집
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    • 2010.05a
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    • pp.263-270
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    • 2010
  • In this study, an air cleaner is considered to improve comfort, safety, and health of automobile passengers. The performance and installation conditions of the air cleaner have been studied to investigate their effects on the air quality in the cabin room using numerical analysis. A five-passenger sedan and a seven-passenger minivan that have comparatively large indoor volume have been considered. The distributions of the local mean age and the volume averaged age of indoor air are calculated according to the variation of the placement and the air flow of the air cleaner. In addition, a decrease of contamination concentration, especially VOCs(volatile organic compounds), by the air cleaner is numerically analyzed with time-accurate unsteady calculation to quantify the effect of the air cleaner on the indoor air quality. As a result, the effective installation and operation conditions of the air cleaner for the automobile cabin room could be suggested.

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The Study of Crude Oil Contaminated Soil Remediation by Indirect Thermal Desorption (간접열탈착방식을 이용한 원유오염토양 정화효율 평가)

  • Lee, In;Kim, Jong-Sung;Jung, Tae-Yang;Oh, Seung-Taek;Kim, Guk-Jin
    • Journal of Soil and Groundwater Environment
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    • v.21 no.3
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    • pp.14-20
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    • 2016
  • Remediation of crude oil contaminated soil is complicate and hard to apply traditional methods because of its persistency, durability, and high viscosity. Therefore, in this study, the efficiency of crude oil contaminated soil remediation was tested by developing a pilot-scale thermal desorption system using the indirect heating method with an exhaust gas treatment. Under optimal condition drawed by temperature and retention time, the remedial efficiency of crude oil contaminated soil and treatability of exhaust gas were analyzed. Total Petroleum Hydrocarbon (TPH) concentration of crude oil contaminated soil was decreased to 69.7 mg/kg on average and the remedial efficiency was measured at 99.60%. Through the exhaust gas, 86.0% of Volatile Organic Compounds (VOC) was degraded and 97.16% of complex malodor was reduced under the suggested optimum operation condition. This study provides important basic data to be useful in scaling up of the indirect thermal desorption system for the remediation of crude oil contaminated soil.

Comparison of preservation in poultry carcasses processed by different chilling systems (도계육 냉각공정 방식에 따른 보존성 비교)

  • Kim, Kyeong-Taek;Kim, Ji-Hyun;Park, Young-Min;Myung, Keun-Sik;Park, Tae-Wook
    • Korean Journal of Veterinary Service
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    • v.40 no.4
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    • pp.245-251
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    • 2017
  • Cold air or ice water are used to chill poultry carcasses after slaughter. In order to compare the microbial reduction effect of two different chilling systems in poultry carcasses, Pre-and post-chilled carcass samples were tested for contamination agents such as aerobic bacteria counts, E. coli counts and Salmonella spp. counts. Water chilling system showed higher reduction ratio of bacteria than air chilling system during the three seasons. Also, aging of slaughter facility was related with bacterial contamination of pre-chilld carcasses. And additional volatile basic nitrogen (VBN) test were conducted in poultry packing meats and it increased steadily during 15 days. VBN at 8~9 days were over 13 mg% with putrid smell. Poultry packing meats by water chilling system were fresher than air chilling system during early storage time. But those decayed faster after 9 days.

Biofilter를 이용한 diesel VOCs의 생물학적 제거

  • 이은영;최우진;최진규;김무훈
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2002.09a
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    • pp.347-350
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    • 2002
  • The petrochemical products can cause soil and groundwater contamination during their transportation and the use of the products, and while being contained in underground storage tanks(USTs) throughout the leakage. To treat the contaminated soil, the bioventing method is suitable for the remediation of semi-volatile compounds, such as diesel and kerosene. Biofiltration is one of possible method to treat the off-gas produced in the process of the bioventing. This study is related to the usage, effectiveness of treatment, and feasibility of two types of biofilter system made of ceramic-compost and polymer respectively to treat diesel VOCs at constant retention time of 20 sec. Compost biofilter showed the average removal efficiency of 73 % when the inlet concentration increased to 20 ppmv. Increased the inlet concentration decreased the microbial activities as well as the removal efficiency. On the contrary, the removal efficiency of the polyurethane biofilter was maintained at 88 % at the inlet concentration of 13 ppmv during ten days and was obtained to 80 % at the inlet concentration of 30 ppmv in spite of the drop of the efficiency in the sudden increase of the inlet concentration. At the beginning of the experiment it showed low removal efficiency at low inlet concentration due to the low microbial activity, however, as experiments proceed the removal efficiency could be obtained more than 80% at high inlet concentration.

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Groundwater Contamination by Cation, Anion and Pesticides (지하수중 음이온, 양이온, 및 금속의 함량)

  • 김형석;정세영;최중명
    • Journal of environmental and Sanitary engineering
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    • v.7 no.2
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    • pp.111-128
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    • 1992
  • According to the increase of population and industrialization, the quality of our drinking water are becoming worse by the contamination of resources, production of THM and other halogenated hydrocarbons during the purifying process, the problem of corroded water supplying pipeline, and the water reservoir tanks, Many people choose groundwater to drink instead of city tap water, but sometimes we get report about groundwater contamination by wastes, swage, septic tank, etc. It is reported that in U. S. over 20% of population are drinking groundwater, but U. S EPA reported the groundwater contamination by pesticides, herbicides, fungicides, fertilizer, and various chemical substances. Craun, et at announced the groundwater contamination by bacteria which are related with poor installation of septic tank. Johnson and Kross mentioned aboutmethemoglobinemia by NO3-N originated from human and animal feces, organic chemicals, and fertilizer, and as the results the infant mortality could be risen. Some scientist also reported the high concentration of metals in groundwaters and some cation and anions, and volatile organic compou nds. Authors investigated 80 groundwaters in urban, agricultural, and industrial area during last 3 month(June - August) to check any drinking water quality parameters are exceeding the standards. The results were as follow. 1, The average value of ammonia nitrate were within the standard, but 11.76% of urban area were exceeded the 10 rpm standard, in agricultural area 42.3175 were exceeded, and in industrial area 20.2% were exceeded the drinking water standard of 10 ppm. the highest concentration was 29.37 ppd in industrial area. 2. The mean value of metals is not exceeded the standard, but there were some groundwater whose Mn value was 0.424 ppm(standard is 0,3 ppm) in urban area, 0.737 rpm in agricultural area, and 5.188 ppm in industrial area. The highest Zn value was 1.221 ppm (standard is 1.0 ppm)was found in industrial area. 3. The percentage of contamination by general bacteria was 8.82% in urban area, 15.38% in agricultural area, and 15.00% in industrial area. Escherichia coil group was also contaminated by 35.29% in urban area, 30.76% in agricultural area, and 30.00% in industrial area. 4, The pH value was within the standard which means there was no influence by acid or alkali chemicals, nor acid rain Through the above results, all the groundwater should be tested to check the safety for drinking water and should make some alternative methods suitable for drink.

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Analysis of Volatile Organic Compounds in Water by Modified Injection Mode for Purge & Trap-GC/MS Method (Purge & Trap-GC/MS 분석법의 주입방식 개선에 의한 물 중의 휘발성 유기물 분석)

  • Jeon, Chi Wan;Lee, Sang Hak;Eum, Chul Hun
    • Journal of the Korean Chemical Society
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    • v.39 no.8
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    • pp.635-642
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    • 1995
  • Improved sample introduction system has been investigated for the determination of volatile organic compounds in water using a purge & trap preconcentration apparatus and a capillary gas chromatography/mass spectrometry. The present limitations associated with the moisture control module and cryorefocusing system suggested by EPA were discussed. To solve the problems such as improper separation of peaks due to the adsorption of water and contamination of purge & trap system, a more efficient connection system between the purge & trap apparatus and the gas chromatograph was introduced and the optimum operational conditions were suggested. A carbopack B/carboxen 1000 and 1001 trap was used for the purge & trap procedure and a custom made crosslinked dimethyldiphenylpolysiloxane capillary column was used for the separation of compounds. Accuracy and precision of the method suggested in this report were examined and the method detection limit of each compound was proposed for the simultaneous determination of 54 volatile organic compounds in water.

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Determination of THM(trihalomethane) in Rain by using Solid Phase Micro-Elctraction(SPME) Fiber Assembly (고상 미량 추출 장치(SPME, solid phase micro-extraction device)를 이용한 물 중의 THM(trihalomethane) 분석)

  • 유광식;박상윤
    • Journal of Environmental Science International
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    • v.6 no.3
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    • pp.277-283
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    • 1997
  • SPME deuce was applied to determine the THM in an aqueous solution. The 6 kinds of THM was quantitatively detenuned by using GC-ECD which has the sample eutracted on the SPME fiber from an aqueous solution for 10 min. The THM components were well separated from $CHCl_3$ to the last $CHBr_3$ UHh 13 mons at the condition. 6 kinds of the volatile halogenated organic compounds: $CHCl_3$, $CHBrCl_2$, $CHBrtCl_2$, $CHCl_3$, $C_2Cl$. and $CHBr_3$, showed well defirled calibration graph with good llnearlty from a few ppb level up to several tens of pub concentration. $CHBr_2Cl$ and $C_2C1_4$ were detected from a few samples among the 10 of river samples. CHCl3, however, was detected In 4 sea water samples with the highest of 10 ppd among the pouuted 6 positions. Trace level of $CHBr_2Cl$ and few pub level of $CHBr_3$ were also detected at the other two sample stations. Most of the 13 rain water samples collected from 6 sampling stations were contained ppd level of $CHCl_3$, and also $CHBr_2Cl$, and C_2Cl_4$ were only detected at trace level at a few rain samples among them. We could recognize the fact that our Ut and water enoronment has already been contaminated by certain volatile halogenated organic compounds through this study.

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Screening of Volatile Organic Compound-Producing Yeasts and Yeast-Like Fungi against Aflatoxigenic Aspergillus flavus

  • Nasanit, Rujikan;Jaibangyang, Sopin;Onwibunsiri, Tikamporn;Khunnamwong, Pannida
    • Microbiology and Biotechnology Letters
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    • v.50 no.2
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    • pp.202-210
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    • 2022
  • Aflatoxin contamination in rice has been documented in a number of studies, and has a high incidence in Asian countries, and as such, there has been a growing interest in alternative biocontrol strategies to address this issue. In this study, 147 strains of yeasts and yeast-like fungi were screened for their potential to produce volatile organic compounds (VOCs) active against Aspergillus flavus strains that produce aflatoxin B1 (AFB1). Five strains within four different genera showed greater than 50% growth inhibition of some strains of A. flavus. These were Anthracocystis sp. DMKU-PAL124, Aureobasidium sp. DMKU-PAL120, Aureobasidium sp. DMKU-PAL144, Rhodotorula sp. DMKU-PAL99, and Solicococcus keelungensis DMKU-PAL84. VOCs produced by these microorganisms ranged from 4 to 14 compounds and included alcohols, alkenes, aromatics, esters and furans. The major VOCs produced by the closely related Aureobasidium strains were found to bedistinct. Moreover, 2-phenylethanol was the most abundant compound generated by Aureobasidium sp. DMKU-PAL120, while methyl benzeneacetate was the major compound emitted from Aureobasidium sp. DMKU-PAL144. On the other hand, 2-methyl-1-butanol and 3-methyl-1-butanol were significant compounds produced by the other three genera. These antagonists apparently inhibited A. flavus sporulation and mycelial development. Additionally, the reduction of the AFB1 in the fungal-contaminated rice grains was observed after co-incubation with these VOC-producing strains and ranged from 37.7 ± 8.3% to 60.3 ± 3.4%. Our findings suggest that these same microorganisms are promising biological control agents for use against aflatoxin-producing fungi in rice and other agricultural products.