• 대한기계학회논문집B
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• 제22권5호
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• pp.685-697
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• 1998

Series of recent k-.epsilon. model modification have been carried out with the aid of DNS data to include the effect of near wall. Though these methods opened new way of turbulence modelings, newly developed turbulence models of its kind had yet shortcomings in prediction for the turbulent flows with various Reynolds numbers and various geometric conditions. As a remedy for these shortcomings, a new k-.epsilon. model proposed here by improving the dissipation rate equation and the damping function for eddy viscosity model. The new dissipation rate equation was modeled based on the energy spectrum and magnitude analysis. The damping function for eddy viscosity was also formulated on the ground of distribution of dissipation rate length scales near a wall and the DNS data. The new k-.epsilon. model was applied to the fully developed turbulent flows in a channel and a pipe with a wide range of Reynolds numbers. Prediction results showed that the present model represents properly the turbulence properties in all turbulent regions over a wide range of Reynolds numbers.

• 한국화재소방학회논문지
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• 제16권3호
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• pp.16-25
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• 2002

소화제인 Freon-23과 몬트리올 의정서에 의해서 규제받는 CFC의 대체 물질인 HFC-227ea의 물성(포화압력, 밀도, 점도, 엔탈피, 표면장력)에 관한 실험식을 구하였다. 문헌에서 얻은 실험값을 이용하여 다항식등의 회귀분석에 의해서 실험식을 얻었다. 포화압력은 온도에 대하여 각각 3차와 2차의 실험식으로 표시하였다. 압축인자와 포화압력을 이용하여 온도에 대한 밀도에 관한 실험식을 제시하였다. 점도는 온도에 대한 지수함수로 표시하였고, 엔탈피는 열용량과 마찬가지로 온도에 대한 2차 함수로 정의하여 나타내었다. 표면장력에 대해서는 간단한 1차 온도에 대한 선형적인 관계가 있었다.

• 폴리머
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• 제26권1호
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• pp.88-97
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• 2002

ortho-cresol novolac형 에폭시/페놀 경화제/triphenylphosphine 수지 시스템의 화학 레올로지 특성에 미치는 아민 실록산 개질제의 영향을 검토하였다. DSC측정으로부터 아민 개질제에 의해 경화 속도와 전환량이 증가하였으며 유리전이온도의 증가도 관찰할 수 있었다. 또한, 저장 탄성률과 손실 탄성률의 교차점으로부터 구한 겔화 시간 및 임계 전환량의 감소를 확인할 수 있었다. 이것으로부터 등온 경화반응이 빠르게 진행됨으로써 점도가 상승하는 것을 알 수 있었다. 전환량의 함수로 얻어진 유리전이온도와 측정된 점도로부터 modified WLF 방정식에서의 $C_1$ 및 $C_2$를 온도 함수로써 나타낼 수 있었으며, 유리전이온도와 $C_1$ 및 $C_2$를 modified WLF 방정식에 적용함으로써 등온 경화반응에 따른 점도변화를 정확히 예측할 수 있었다.

• 대한기계학회논문집A
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• 제29권5호
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• pp.762-769
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• 2005

This paper presents a method to investigate the characteristics of a hydrodynamic bearing of a HDD spindle motor due to elevated temperature considering the variation of the clearance as well as the lubricant viscosity. Iterative finite element analysis of the heat conduction and the thermal deformation is performed to determine the viscosity and clearance of a hydrodynamic bearing due to elevated temperature until the temperature of the bearing area converges. Proposed method is verified by comparing the calculated temperature with the measured one in elevated surrounding temperature as well as in room temperature. This research shows that elevated temperature changes the clearance as well as the lubricant viscosity of the hydrodynamic bearing of a HDD spindle motor. Once the viscosity and the clearance of a hydrodynamic bearing of a HDD spindle motor are determined, finite element analysis of the Reynolds equation is performed to investigate the static and dynamic characteristics of a hydrodynamic bearing of a HDB spindle motor due to elevated temperature. It also shows that the variation of clearance due to elevated temperature is another important design consideration to affect the static and dynamic characteristics of a hydrodynamic bearing of a HDD spindle motor

• 한국수자원학회논문집
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• 제33권1호
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• pp.39-50
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• 2000

일반적으로 동수역학 모형은 마찰인자(조도계수 또는 Chezy계수)와 와점성계수를 필요로 하고 수치계산에서 이들 계수의 갑은 통상 가정 또는 반복계산을 통하여 결정된다. 수치모형에서 와점성계수는 물리적인 확산뿐만 아니라 수치점성의 효과도 가지고 있어서 수치계산의 안정성에 영향을 미치므로 이들 계수의 일관된 결정방법이 필요하다. 수위 및 유량자료, 1차원 모형인 HEC-2와 NETWORK, 2차원 모형인 SMS를 이용하여 한강하류 구간에 대한 조도계수의 산정결과와 와점성 계수의 산정식이 제시되었으며 실측수위와 비교를 통해 검증되었다.

• 한국소음진동공학회:학술대회논문집
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• 한국소음진동공학회 2003년도 추계학술대회논문집
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• pp.556-563
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• 2003

This paper presents a method to investigate the characteristics of a hydrodynamic bearing of a HDD spindle motor due to elevated temperature considering the variation of the clearance as well as the lubricant viscosity. Iterative finite element analysis of the heat conduction and the thermal deformation is performed to determine the viscosity and clearance of a hydrodynamic bearing due to elevated temperature until the temperature of the bearing area converges. Proposed method is verified by comparing the calculated temperature with the measured one in elevated surrounding temperature as well as in room temperature. This research shows that elevated temperature changes the clearance as well as the lubricant viscosity of the hydrodynamic bearing of a HDD spindle motor. Once the viscosity and clearance of a hydrodynamic bearing of a HDD spindle motor are determined, finite element analysis of the Reynolds equation is performed to investigate the static and dynamic characteristics of a hydrodynamic bearing of a HDD spindle motor due to elevated temperature. It also shows that the variation of clearance due to elevated temperature is another important design consideration to affect the static and dynamic characteristics of a hydrodynamic bearing of a HDD spindle motor.

• 약학회지
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• 제32권1호
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• pp.86-94
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• 1988

Some rheological properties of subfractions for dextran in the molecular weights range from $3{\times}10^4$ to $2{\times}10^6$ was investigated at room temperature. The dependence of the viscosity on concentration, shear rate, pH & ionic strength, temperature and solvent effect was observed. From the experimental data the Mark-Houwink viscosity equation in water at $25^{\circ}C$ was determined for samples having the molecular weight ranging from $3{\times}10^4$ to $2{\times}10^6$ as$[{\eta}]=3.1{\times}10^{-3}\;Mw^{0.39}(in\;dl/g)$. The intrinsic stiffness of the dextran backbone was estimated by evaluating the 'characteristic ratio' $C_{\infty}$, which is below the 0.082. In the concentrated region, the viscosity was decreased with increasing shear rate and was exponentially decreased with raising temperature, the viscosity showed the maximum value at neutral condition. From the experimental data, it was concluded that dextran chain, linked by the ${\alpha}-1$, 6-glucosidic linkage, behaves like a flexible random coil chain in aqueous solution, dextran solutions were pseudoplastic power law fluids among the empirical models of non-Newtonian behavior. Urea was an active reagent which increases the viscosity and swells dextran while pyrididine and glycerol were inactive reagents. Also, it could be estimated that the formation of gel structure is promote to the neutral state, the molecular weight larger than $2{\times}10^5$, when electrolytic concentration is IN and Ureas is use to solvent.

• 대한화학회지
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• 제19권1호
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• pp.3-10
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• 1975

여러 組成의 dimethyl sulfoxide(DMSO)-물 混合溶媒中에 tetraethylammonium chloride$((C_2H_5)_4NCl)$의 分몰容積 및 相對粘度를 $30^{\circ}C$에서 測定하였다. 그 結果로 부터 DMSO의 몰分率이 0.2${\sim}$0.3인 組成에서 溶媒構造가 가장 强化된 상태임을 알았으며 이것은 粘度에 關한 Jones-ole式(${\eta}_r=1+AC^{1/2}$+BC)의 A-係數의 最小値 및 B-係數의 最大値의 現象을 나타낸다. 또한 DMSO의 몰分率 이 0.4${\sim}$0.5인 組成에서는 溶媒構造가 가장 파괴된 상태로서 $Cl^-$의 强한 electrostriction 效果로 因한 收縮으로 分몰容積이 最小値이며, 粘度 B-係數가 最小로 나타남을 알았다. 그리고 limiting effective flowing volume $V_e^{\circ}$와 粘度 B-係數와의 사이에 B=2.5$V_e^{\circ}$의 관分率계가 近似的으로 成立함을 確認하였다.

• 한국식품과학회지
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• 제29권6호
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• pp.1089-1093
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• 1997

에리스리톨을 설당 대체 감미료 소채로 사용하기 위한 기초 자료를 얻기 위하여 흡습성, 용해도, 수분활성도, 열안정성, 점성과 같은 물성학적 특성을 설탕, 자일리톨, 소르비톨, 프럭토올리고당과 비교 측정하였다. 모든 감미료 중에서 에리스리톨은 가장 낮은 흡습성과 가장 큰 수분활성 저하능력을 나타내었고 $20^{\circ}C$에서 35.8% 용해되어 다른 감미료보다 용해도가 낮았다. 프럭토올리고당이 빠른 감미료들에 비해 현저히 열안정성이 낮았던 반면 에리스리톨의 열안정성은 오히려 설탕보다 컸다 10%, 30% 에리스리톨 용액의 점성은 동일 농도의 다른 감미료 용액의 점성과 비슷하였으나 고농도 50% 이상의 감미료 용액에서의 점도는 분자량이 증가할수록 점토가 증가하였다. 온도 증가에 따른 감미료들의 점성은 감소되었으며 Arrhenius equation으로 표현될 수 있었다. 30% 에리스리톨 용액과 30% 설탕 용액의 유동활성화에너지는 각각 10.8 kcal/g mol와 11.2 kcal/g mol이었다.

• Korean Chemical Engineering Research
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• 제55권4호
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• pp.520-529
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• 2017

Viscosity data were measured at 298.15 K and 308.15 K for formamide + 1-propanol, 2-propanol, 1-butanol, 2-methyl-1-propanol or 2-methyl-2-propanol mixtures. For an equimolar mixture, deviation in viscosity follows the sequence: 2-methyl-2-propanol >2-methyl-1-propanol>1-butanol>2-propanol>1-propanol. The viscosity data were further analyzed in terms of graph theory. Free energy of activation was also calculated from experimental viscosity data along with previously reported excess volume data. The deviation in viscosity and free energy of activation were fitted to Redlich-Kister polynomial equation. The viscosity data were also correlated by correlations like Grunberg-Nissan, Tamura-Kurata, HindMcLaughlin-Ubbelohde, and Katti-Chaudhari relation. Various adjustable parameters, $G_{12}$, $T_{12}$, $H_{12}$, and $W_{vis}/RT$, of various correlations were used to predict viscosity deviation of binary mixtures. Positive value of $G_{12}$ indicates strong interaction in the studied systems. Grunberg-Nissan relation has lowest deviation among the four correlations for formamide + 1-propanol or 2-propanol mixtures; and for mixtures of formamide with 1-butanol or 2-methyl-1-propanol, TamuraKurata has lowest deviation. Grunberg-Nissan gives lowest deviation for formamide + 2-methyl-2-propanol mixtures.