• Title/Summary/Keyword: Viscose

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Effect of Cations on the Sorption and the Tensile Properties of CMC Fibers (CMC섬유내의 양이온이 섬유의 흡습성과 인장 성질에 미치는 영향)

  • 이미식
    • Journal of the Korean Society of Clothing and Textiles
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    • v.18 no.1
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    • pp.113-120
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    • 1994
  • The Purpose of this study was to improve the moisture related properties of viscose rayon fibers. Viscose rayon filament yarns were partially etherified to make CMC fibers. CMC fibers were converted to the sodium, calcium, and ferric salt forms by an ion exchange method. The property changes of ion exchanged CMC fibers were examined. Cation contents of fibers were varied depending on the degree of substitution of CMC fibers. The strength of Na, Ca, Fe-CMC was higher than H-CMC owing to the plasticization by moisture sorption and the crosslinking by cations. The moisture regain was increased by carboxymethylation and that of Fe-CMC showed the highest value. The degree of swelling determined by the water retention value was observed to be Na-CMC > Ca-CMC > H-CMC > Fe-CMC. The solution retention value was decreased in the order . Ca-CMC > Na-CMC > H-CMC > Fe-CMC.

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Shrinkproof Finish of Viscose Rayon Fabric (비스코스 레이온 직물의 방축가공)

  • 김성동;이인열;이종렬;김민정
    • Textile Coloration and Finishing
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    • v.10 no.6
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    • pp.20-26
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    • 1998
  • 100% viscose rayon fabric was treated with 1,2,3,4-butanetetracarboxylic acid (BTCA) by pad-dry-cure process in the presence of various catalysts. The dimensional stability, mechanical properties and hand values of fabric treated with BTCA were investigated. The ester-crosslinking reaction was influenced by the concentration of BTCA and type of catalyst. The fabric treated with BTCA was comparable or superior to that treated with conventional crosslinking agents such as dimethyloldihydroxyethyleneurea and 4,5-dihydroxy-1,3-dimethyl-2-imidazolidinone in respect of wrinkle recovery, shrinkproof property, retention of strength, and hand values. But in yellowing of fabric, the fabric treated with BTCA was inferior to that treated with conventional crosslinking agents. The fabric treated with BTCA/sodium formate was inferior to that treated with BTCA/sodium hypophosphite in respect of WRA, but had better strength retention and whiteness.

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Syntheses of Rayon-like Polyester (Rayon-like 폴리에스터의 합성(合成))

  • Ahn, Young-Moo;Park, Young-Gi
    • Journal of Fashion Business
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    • v.11 no.5
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    • pp.155-164
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    • 2007
  • Viscose rayon has advantages such as vivid luster, good dyeability, low static electricity, good absorbance and good spinnability but also has flaws such as easy crease and decrease of physical properties when it gets wetting, and it requires dry cleaning. Therefore in order to synthesize the polymer to solve the problems of rayon while keeping the advantages of it, this study made the high specific gravity polyester for ultra drape property and high contraction polyester for rayon-like fiber having volume, soft and warm sense. The polyester with high specific gravity, 1.47 was made by adding 7 wt% of $BaSO_4$ as additive. High contraction polyester was made by copolymerization by using IPA 5 mole% to increase the amorphous region as comonomer and also using Newpol BPE-20(NPE) 1.5 wt% not to decrease the properties.

Development of Viscose Rayon Process (I. Dissolution of Cellulose in $CO_2$/NaOH System)

  • 오상연;박근후;류동일;최창남;양갑승;박원호;오영세
    • Proceedings of the Korean Fiber Society Conference
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    • 1998.04a
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    • pp.315-319
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    • 1998
  • 셀룰로오스 용매계는 크게 직접용매계와 간접용매계로 나뉠 수 있으며, 잘 알려진 "비스코스 레이온(viscose rayon)"공정은 공정 중간단계에 이황화탄소(CS$_2$)를 사용하여 셀룰로오스 크산테이트 유도체를 만들고 이를 다시 수산화나트륨에 용해시키는 간접용매계에 속한다. 수산화나트륨 수용액에 용해된 비스코스 용액은 응고 욕내에서 황산과 반응하여 셀룰로오스로 재생이 되는데 비스코스 용액의 재생과정에서 발생하는 이황화탄소는 그 자체가 독성이 심한 가연성 액체일 뿐만 아니라 부반응을 통하여 삼황화소다(sodium trithiocarbonate) 및 황화수소(H$_2$S)를 발생한다.(중략)

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Dyeing Properties of Bi-functional Reactive Dyes on a Novel Regenerated Cellulosic Fiber

  • Koh, Joonseok;Kim, Ik Soo;Kim, Sung Soo;Shim, Woo Sub;Kim, Jae Pil
    • Fibers and Polymers
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    • v.5 no.1
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    • pp.44-51
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    • 2004
  • Three bi-functional reactive dyes such as Bis(vinylsulphone) type, Bis(monochlorotriazine) type and Bis(mononicotinotriazine) type were applied to regular viscose rayon and new regenerated cellulosic fiber ($enVix^ⓡ$) which was prepared from cellulose acetate fiber by the hydrolysis of acetyl groups, and their dyeing properties and fastness properties were compared. enVix exhibited better dyeability and fastness than regular viscose rayon and these results were also explained by the differences in the supramolecular structure of these two fibers.

Conversion of Woody Biomass for Utilization(II) - Preparation of Dissolving Pulp by Solvolysis from Woody Biomass - (목질계 Biomass의 변환 이용(II) - 목질계 바이오매스로부터 solvolysis법에 의한 용해용 펄프의 제조 -)

  • Yang, Jae-Kyung;Lim, Bu-Kug;Chang, Jun-Pok;Lee, Jong-Yoon
    • Journal of the Korean Wood Science and Technology
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    • v.25 no.4
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    • pp.45-50
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    • 1997
  • This research was studied for dissolving pulp preparation as the raw material of viscose rayon from woody biomass by solvolysis pretreatment. In the change of pulp characteristic after solvolysis pretreatment, the following results were obtained. In the case of solvolysis pretreatment, we have obtained pulp that high purity cellulose, and degree of polymerization was inclined to decrease less than 440 on the phosphoric acid as catalyst. Comparing phosphoric acid and formic acid as catalyst in the solvolysis pretreatment, using on formic acid catalyst is superior to phosphoric acid catalyst for making dissolving pulp.

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A Study on the Smoke Hazard Increase of Flame-retardant-treated Interior Decorative Textile -Focused on Viscose Rayon Textile Wallcovering- (난연 처리된 실내장식섬유의 연기 위해성 증가에 관한 연구 -비스코스 레이온 섬유 벽지를 중심으로-)

  • Lee, Joonhan;Kim, Sun Mee
    • Journal of Fashion Business
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    • v.24 no.3
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    • pp.30-39
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    • 2020
  • This study was conducted to identify problems in domestic flame-retardant performance specifications. Currently, the domestic wallcovering anti-inflammatory regulations are not prepared for damage caused by smoke, with the carbonized area as the main function. In particular, given that smoke is the main cause of human casualties and injuries in a fire, it is reasonable that the flame density and toxicity of the wallcovering should also be the main performance indicators. The scope and method of research in this study were as follows. First, a prior study related to fire on various wallcoverings was considered. Second, it raised questions about the effects of smoke in the event of a fire and domestic anti-inflammatory performance tests. Third, textile wallcovering samples were manufactured with viscose rayon for experimental verification of the problems and tested by Korean and EU standards without flame retardant processing to analyze the differences between each regulation. Fourth, the performance of flame retardant wallcovering according to Korean standards was evaluated using smoke density and harmful gas testing methods. The results of each test were as follows. Non-fire retardant wallcovering was rejected by Korea standards. However, B-s1.d0 in Europe. Smoke density testing and harmful gas by domestic combustion processing on the same sample showed that the smoke density increased about 4.3 times more than before, and the harmful gas test showed that the suspension of the post-processing sample slowed earlier than the non-processed sample.

Biodegradability of Viscose Rayon and Lyocell Fibers (비스코스 레이온과 리오셀의 생분해성)

  • Yoon Chang Sang;Park Chung Hee;Kang Yun-kyung;Im Seung Soon
    • Journal of the Korean Society of Clothing and Textiles
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    • v.29 no.3_4 s.141
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    • pp.470-477
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    • 2005
  • This study was carried out to evaluate the biodegradability of viscose rayon and lyocell fibers, employing soil burial test, activated sludge test and enzymatic hydrolysis. Using X-ray analysis, crystallinity and morphology change was investigated. External changes after degradation were also observed by SEM and digital photographs. Vscose rayon fibers exhibited higher biodegadation than lyocell fibers, indicating that lower crystallinity favored the biodegradation. Among the biodegradability of lyocell fibers there was a tendency that fibers with lower crystallinity and higher moisture regain had higher values. When external changes after degradation being observed, it was shown that there were microorganisms growing on the surfaces of samples accompanying lading and weakening. From these results it was concluded that biodegradability of the specimens was most closely correlated to the moisture regain and crystallinity of fibers which reflects hydrophilicity and internal structure.