• Title/Summary/Keyword: Viscoelasticity

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Effect of surfactant adsorption on the rheology of suspensions flocculated by associating polymers

  • Otsubo, Yasufumi;Horigome, Misao
    • Korea-Australia Rheology Journal
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    • v.15 no.4
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    • pp.179-185
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    • 2003
  • Associating polymers act as flocculants in colloidal suspensions, because the hydrophobic groups (hydrophobes) can adsorb onto particle surfaces and create intermolecular cross-linking. The steady-shear viscosity and dynamic viscoelasticity were measured for suspensions flocculated by multichain bridging of associating polymers. The effects of surfactant on the suspension rheology are studied in relation to the bridging conformation. The surfactant molecule behaves as a displacer and the polymer chains are forced to desorb from the particle surfaces. The overall effect of surfactant is the reduction of suspension viscosity. However, the additions of a small amount of surfactant to suspensions, in which the degree of bridging is low, cause a viscosity increase, although the number of chains forming one bridge is decreased by the forced desorption of associating polymer. Since the polymer chains desorbed from one bridge can form another bridge between bare particles, the bridging density over the system is increased. Therefore, the surfactant adsorption leads to a viscosity increase. The surfactant influences the viscosity in two opposing ways depending on the degree of bridging.

Numerical simulation of flow-induced birefringence in injection molded disk

  • Shyu, Goang-Ding;Avraam I. Isayev;Lee, Ho-Sang
    • Korea-Australia Rheology Journal
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    • v.15 no.4
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    • pp.159-166
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    • 2003
  • This study is an attempt to understand the birefringence and stress development in an injection molded disk. A computer code was developed to simulate all three stages of the injection molding process filling, packing and cooling by finite element method. The constitutive equation used here was compressible Leonov model. The PVT relationship was assumed to follow the Tait equation. The flow-induced birefringence was related to the calculated flow stresses through the linear stress-optical law. The predicted birefringence was in good agreement with the experimental results.

The Curved Interfacial Crack Analysis between Foam and Composite Materials under Anti-plane Shear Force (반평면 전단하중력을 받는 곡면형상을 가지는 폼과 복합재료 접합부의 계면크랙에 관한 연구)

  • 박상현;신재윤;전흥재
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2000.04a
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    • pp.101-104
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    • 2000
  • The general solution of the anti-plane shear problem for the curved interfacial crack between viscoelastic foam and composites was investigated with the complex variable displacement function and Kelvin-Maxwell model. The Laplace transform was applied to treat the viscoelastic characteristics of foam in the analysis. The stress intensity factor near the interfacial crack tip was predicted by considering both anisotropic and viscoelastic properties of two different materials. The results showed that the stress intensity factor increased with increasing the curvature of the curved interfacial crack and it also increased and eventually converged to a specific value with increasing time.

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Viscoelastic stress analysis of nonaxisymmetrically heated cylindrical tubes (비축대칭 열하중을 받는 원통튜브의 점탄성 응력해석)

  • 박진석;서금석;김종인
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.15 no.2
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    • pp.396-403
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    • 1991
  • A solution is presented for the computation of the elastic-creep stresses in a hollow cylinder subjected to nonaxisymmetric temperature distribution. The creep problem is treated by the Maxwell creep model. Laplace transformation is used for reformation of the governing equation of elastic problem and Hooke's law in a function of .gamma. , .theta. , and creep constant. The governing equation is set up using the Airy stress function which leads to the biharmonic equation. The solution is obtained by using Fourer series method and Laplace inverse method used to obtain the stress components which include the variation of time. This solution shows excellent agreement with Lamkin's and Boley & Weiner's solution. The viscoelastic stresses are also obtained for the fuel rob tube subjecting nonaxisymmetric thermal load.

Comparison of interpretation methods for large amplitude oscillatory shear response

  • Kim Hyung-Sup;Hyun Kyu;Kim Dae-Jin;Cho Kwang-Soo
    • Korea-Australia Rheology Journal
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    • v.18 no.2
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    • pp.91-98
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    • 2006
  • We compare FT (Fourier Transform) and SD (Stress Decomposition), the interpretation methods for LAOS (Large Amplitude Oscillatory Shear). Although the two methods are equivalent in mathematics. they are significantly different in numerical procedures. Precision of FT greatly depends on sampling rate and length of data because FT of experimental data is the discrete version of Fourier integral theorem. FT inevitably involves unnecessary frequencies which must not appear in LAOS. On the other hand, SD is free from the problems from which FT suffers, because SD involves only odd harmonics of primary frequency. SD is based on two axioms on shear stress: [1] shear stress is a sufficiently smooth function of strain and its time derivatives; [2] shear stress satisfies macroscopic time-reversal symmetry. In this paper, we compared numerical aspects of the two interpretation methods for LAOS.

Stability Improvement of the Ultra-High Speed Micro Turbocharger Supported by Air Foil Bearings (공기 포일 베어링으로 지지되는 초고속 마이크로 터보차져의 구동 안정성 향상에 관한 연구)

  • Kwak, Yong-Suk;Kim, Chang-Ho;Chung, Jin-Taek;Lee, Yong-Bok
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.32 no.7
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    • pp.541-548
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    • 2008
  • To improve the operational stability of the 100 Watts class Micro Gas Turbine, the air foil bearing with additional damping material has been investigated. The key of structure is that a viscoelastic material is coated under the top foil. The compliant foil journal bearing and thrust bearing are designed to withstand high load of vibrations at the operational speed 870,000 rpm. Test is executed in room temperature. Rotor has stably operated above 480,000 rpm. It is over 55% of the designed speed 870,000 rpm. Synchronous and subsynchronous vibrations are both well controlled. Vibration amplitude diminished over 50%. With the help of increased damping resulting from the viscoelasticity, the rotor stability of Micro turbocharger has been improved.

Study on the growth of vapor bubble in devolatilization of polymers

  • Kim, Chongyoup
    • Korea-Australia Rheology Journal
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    • v.11 no.3
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    • pp.247-253
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    • 1999
  • The growth of a spherical vapor bubble contained in a large body of upper convected Maxwell fluid is theoretically analyzed under the devolatilization condition of polymer by using a Galerkin FEM in the Lagrangian frame. Using the finite element technique, a fully explicit numerical scheme is developed both for the calculation of pressure distribution and for the tracking of bubble surface. Oscillatory behavior in bubble radius is observed during growth and the oscillatory behavior is found to be due to the interaction of mass transfer resistance and elasticity. It is found that the elasticity of fluid accelerates the growth and removal of volatile component. It is also found that the bubble growth in the devolatilization of polymers is affected by both mass transfer resistance and viscoelasticity of fluids.

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Study on Pad Properties as Polishing Result Affecting Factors in Chemical Mechanical Polishing (CMP공정에서 연마결과에 영향을 미치는 패드 물성치에 관한 연구)

  • 김형재;김호윤;정해도
    • Journal of the Korean Society for Precision Engineering
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    • v.17 no.3
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    • pp.184-191
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    • 2000
  • Properties of pad are investigated to find the relationship between the chemical mechanical polishing(CMP) results, such as material removal rate and within wafer non-uniformity(WIWNU), and its properties. Polishing pressure is considered as important factors to affect the results, so behavior of ordinary polymer is studied to define the polishing result affecting properties of pad. Experimental setup is devised to identify the behavior of pad and several different pads are used in chemical mechanical polishing experiments to verify the correlations between pad properties and polishing results. The results indicate that the viscoelastic properties of pad had relationships with the polishing results, and shows correlation between suggested properties of pad and polishing result.

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Paint Simulation System Representing the Paint Characteristics Reflecting Opinions of Audiences (감상자의 견해가 반영된 물감 특징을 표현하는 물감 시뮬레이션 시스템)

  • You, Mi
    • Journal of Korea Multimedia Society
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    • v.17 no.7
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    • pp.906-914
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    • 2014
  • There are many studies to create realistic paint effects and the research area still has attracted attention in these days. However, the consideration for the characteristics of the real paint effects from the point of viewers is not enough. In this paper, we extract the important paint features and survey the importance values. Based on the survey results, we suggest a new paint system. The paint system utilizes the paint simulation that reflects viscoelasticity and mixing suggested by You et al. (2013) and proposes the paint rendering method that represents the details of a paint, a solvent, and pigments. We survey the quality of our results and prove that our paint system is superior to the previous studies.

Prediction of birefringence distribution in cylindrical glass compression test (유리 압축 실험에서의 복굴절 분포 예측)

  • Lee J.;Na J.W.;Rhim S.H.;Oh S.I.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2004.05a
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    • pp.95-100
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    • 2004
  • An analysis using FEM simulation was conducted to predict residual stresses and birefringence in simple compressed cylindrical glass as a preliminary part of the optimum design determination of optical lenses. The FEM simulation with the Maxwell viscoelastic constitutive model was used to predict thermal induced residual stresses and birefringence during the compression test considering stress relaxation. Also the linear photoelastic theory was introduced to calculate birefringence from the residual stress state. The simulation results were in good agreement with deformation and birefringence distribution in the existing experimental result.

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