• Geomechanics and Engineering
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• v.28 no.5
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• pp.477-491
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• 2022

In the present study, the effects of thermal loading on the buckling and resonance frequency of graphene platelets (GPL) reinforced nano-composites are examined. Functionally graded (FG) material properties are considered in thickness direction for the thermal responses of the composite. The equivalent material properties are obtained using Halphin-Tsai nano-mechanical model for composite layers. Moreover, the effects of nano-scale sizes are taken into account, employing functionally modified couple stress (FMCS) parameter. In this regard, for the first time, it is demonstrated that at certain values of GPL weight fraction, thermal buckling occurs. In obtaining results of vibrational behavior, both analytical solution and deep neural network (DNN) methods are used. The DNN method needs low computational costs to predict the resonance behavior. A comprehensive parametric study is conducted to indicate the effects of several geometrical, material, and loading conditions on the vibrational and buckling behavior of cylindrical shell structures made of GPL-nanocomposites. It is shown that the effect of temperature change on the occurrence of buckling is vital while it has a negligible impact on the resonance frequency of the structure. Moreover, the size-dependency of the results is demonstrated, and it cannot be neglected in nano-scales.

• Bulletin of the Korean Chemical Society
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• v.18 no.8
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• pp.819-823
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• 1997

The luminescence and photoexcitation spectra of cis-[Cr(cyclam)(NO3)2]NO3·½ H2O (cyclam=1,4,8,11-tetraazacyclotetradecane) taken at 77 K are reported. The infrared and visible spectra at room-temperature are also measured. The vibrational intervals of the electronic ground state are extracted from the far-infrared and emission spectra. The ten electronic bands due to spin-allowed and spin-forbidden transitions are assigned. With observed transitions, a ligand field analysis has been performed to determine the bonding property of nitrate group in the chromium(Ⅲ) complex. According to the results, it is found that nitrate ligand has weak σ- and π-donor properties toward chromium(Ⅲ).

• Bulletin of the Korean Chemical Society
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• v.19 no.5
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• pp.553-557
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• 1998

Density functional theory calculations are reported for the carbon clusters bonded with two oxygen atoms $OC_No$ (n=2-6). The structures, vibrational frequencies and dipole moments are computed by BLYP theory with the 6-311G* basis set. Good agreement is obtained between the computed and experimentally observed properties. The ground states of these molecules are shown to be linear. Cyclic structures with higher energy are also predicted.

• Structural Engineering and Mechanics
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• v.64 no.6
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• pp.683-693
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• 2017

According to a generalized nonlocal strain gradient theory (NSGT), dynamic modeling and free vibrational analysis of nanoporous inhomogeneous nanoplates is presented. The present model incorporates two scale coefficients to examine vibration behavior of nanoplates much accurately. Porosity-dependent material properties of the nanoplate are defined via a modified power-law function. The nanoplate is resting on a viscoelastic substrate and is subjected to hygro-thermal environment and in-plane linearly varying mechanical loads. The governing equations and related classical and non-classical boundary conditions are derived based on Hamilton's principle. These equations are solved for hinged nanoplates via Galerkin's method. Obtained results show the importance of hygro-thermal loading, viscoelastic medium, in-plane bending load, gradient index, nonlocal parameter, strain gradient parameter and porosities on vibrational characteristics of size-dependent FG nanoplates.

• Proceedings of the KIEE Conference
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• 2001.07c
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• pp.1521-1523
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• 2001

In this paper, High quality factor and fine dielectric loss was resulted on specimen added 0.5wt% $MnO_2$ after compared and analyzed dielectric and piezoelectric properties following that added each 0 $\sim$ 0.9wt% of $Fe_2O_3$, $Nb_2O_5$, and $MnO_2$ on dopant at PSN-PT in two material disposition ceramics with research still is not completed to material investigation to increase high power piezoelectric actuator device efficiency. And, a measuring method and the experimental results of the temperature rise under the high vibrational velocity are also described.

• Journal of Photoscience
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• v.7 no.1
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• pp.21-26
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• 2000

The photoemission and excitation spectra of cis-[Cr(cyclam)F$_2$]ClO$_4$ (cyclam = 1,4,8,11-tetraazacy-clotetradecane) taken at 77 K are reported. The 298 K mid- and far-infrared spectra are also measured. The vibrational intervals of the electronic ground state are extracted from the far-infrared and emission spectra. The ten electronic bands due to spin-allowed and spin-forbidden transitions are assigned. The zero-phonon line In the excitation spectrum splits into two components by 169 cm$^{1}$, and the large $^2$E$_{g}$ splitting can be reproduced by the ligand field theory. According to the ligand field analysis, we can confirm that nitrogen atoms of the cyclam ligand have a strong c-donor character, and fluoride ligand also has strong $\sigma$- and $\pi$-donor properties toward chromium(III) ion.n.

• Journal of the Korean Society of Industry Convergence
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• v.16 no.3
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• pp.69-74
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• 2013

Finasteride, ($5{\alpha}$, $17{\beta}$)-N-(1,1-dimethylethyl)-3-oxo-4-azaandrost-1-ene-17-carboxamide), is a 5a-reductase enzyme inhibitor. This enzyme converts testosterone to the more potent androgen, a-dihydrotestosterone. This molecules a logical medical treatment for benign prostatic hyperplasia (BPH), as it induced a reduction in serum dihydrotestosterone and prostatic specific antigen levels with a concomittant increase in blood testosterone concentration . Despite its widespread use, little has been published concerning its molecular properties. Therefore, in this study, in order to explain characteristics of finasteride, total energy, net charge, vibrational mode of melatonin are calculated by PM3 methods of HyperCam 8.0.

• Bulletin of the Korean Chemical Society
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• v.35 no.2
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• pp.531-538
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• 2014

The quantum mechanical properties of a series of oligo-para-phenylenes (2-11) were characterized using DFT B3LYP/6-311G(d,p) calculations. The global minimum among the various torsional conformers of an oligo-p-phenylene is calculated to be a twist conformation. A less stable planar conformation, in which all the dihedral angles in oligo-p-phenylene are restricted to be planar, has also been calculated. The total electronic energies, normal vibrational modes, Gibbs free energies, and HOMOs and LUMOs of the two different conformations (twisted and planar) of the oligo-p-phenylenes were analyzed. The energy differences between the HOMOs and LUMOs of the substrates are in accord with the maximum absorption peaks of the experimental UV spectra of 2-6. The calculated normal vibrational modes of 2-6 were comparable with their experimental IR spectra.

• Transactions on Electrical and Electronic Materials
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• v.9 no.2
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• pp.79-83
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• 2008

The dampness by treating the surface with polyethylene terephthalate (PET) film was measured to grasp the plasma parameters and was observed the surface condition with an atomic force microscope (AFM) to find the causes of the dampness. Also, the vibrational and rotational temperatures in the plasma were calculated after identifying the radicals within the plasma by analyzing the emission spectral with an emission spectrum. The hydrophilic properties were enhanced, by treating the surface of the PET film with non-equilibrium atmospheric discharge plasma. When the rotational temperature was 0.22 to 0.31 eV within the plasma, surface modification control could be easily carried out to surface treatment of PET film on non-equilibrium atmospheric pressure plasma.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2000.11a
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• pp.667-673
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• 2000

A number of issues related with the vibrational behavior of pretwisted rotating beams featuring anisotropic properties and incorporating adaptive capabilities are considered in this paper. The adaptive capabilities are provided by a system of piezoactuators bonded or embedded into the structure. Based on the converse piezoelectric effect and on the out of phase activation, boundary control moments are pizoelectrically induced at the beam tip. A feedback control law relating the induced bending moments with the kinematical response quantities appropriately selected is used, and its beneficial effects, considered in conjunction with that of the beam anisotropy and structural pretwist upon the eigenvibration characteristics are highlighted