• Journal of the Korean Chemical Society
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• v.42 no.1
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• pp.9-15
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• 1998

The geometrical parameters, vibrational frequencies, and IR intensities of dimethyldioxirane had been investigated using high level ab initio quantum mechanical methods with various basis sets. The polarization function decreases C-O and C-C bond distances significantly and the electron correlation effect increases those bond lengths slightly, while other bond lengths and bond angles are relatively stable for basis set size and correlation effect. The experimental and other theoretical vibrational frequencies and IR intensities of dimethyldioxirane will be compared and discussed with our high level theoretical predictions.

• Journal of the Korean Society for Precision Engineering
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• v.6 no.4
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• pp.136-144
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• 1989

This paper presents the vibrational characteristics of linear damped vibrational systems with a linear dynamic absorber. The amplitude ratios of main vibrational system are derived from the equation of motion for the system, and optimal natural frequency ratio and damping ratio of dynamic absorber are obtained by computer simu- lation, which minimize the amplitude ratio of main vibrational system for the whole range of the frequency ratio. And, the effects of the parameters on the amplitude ratios are investigated. As the results, the effect of the natural frequency ratio on the amplitude ratio of main vibrational system is more important than that of the damping ratio of dynamic absorber as damping ratio of main vibrational system becomes larger. For the case of large damping ration of main vibrational system becomes larger. For the case of large damping ratio of main vibration system, the amplitude ratios are not decreased dramationally in spite of inoreasing mass ratio.

• Bulletin of the Korean Chemical Society
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• v.34 no.2
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• pp.553-557
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• 2013

The stretching vibration of OH of ice Ih is studied by Car-Parrinello molecular dynamics in regarding the effect of mixed H/D contamination while the vibrational spectrum is considered by velocity-velocity autocorrelations of the sampled ensemble. When hydrogen atoms are immersed randomly into the deuterated ice, a typical vibrational frequency of OH stretching mode is observed to be similar to that from the pure $H_2O$ ice. When focusing on the correlation of isolated neighboring OH stretching, a narrower and blue shifted peak is observed at the high frequency range as a result of the screening from the complex many body correlations by $D_2O$ environment. It is also specifically related to the symmetric intermolecular correlations between neighboring OH stretching modes. More enhanced high frequency range can be explained by the expansion of such two body correlations to collective many body correlations among all possible OH stretching modes. This contribution becomes important when it involves in chemical interactions via excitation of such vibrational states.

• The Transactions of the Korean Institute of Electrical Engineers P
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• v.59 no.4
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• pp.440-443
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• 2010

This paper deals with the method of vibration measurement of a gun barrel structure using mechanical filter. When a bullet with high speed is moving within a gun barrel type structure with low bending vibration frequencies, it is difficult to measure the bending vibration signals of the structure. For example, noncontact type sensors such as displacement or velocity sensor are not appropriate for the measurement of vibrational signals because of the movement effect of the equipment frame through the moving structures or effect of the ground vibration. One of contact type sensors such as accelerometer is profitable for measurement of vibrational signals because of its wide measurement ranges. In the case of a gun barrel structure including high vibrational signals like shock waves, however, it is necessary to propose vibration measurement method filtering high frequencies. The purpose of the paper is to propose the proper vibrational measurement technique filtering high frequencies of a gun barrel type structure.

• Journal of the Korean Chemical Society
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• v.42 no.2
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• pp.161-171
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• 1998

The geometrical parameters, vibrational frequencies, and IR intensities for primary ozonide (POZ), secondary ozonide (SOZ) and carbonyl oxide as the intermediates of alkene-ozone reaction have been predicted using high level ab initio quantum mechanical method with various basis sets. In general, the polarization function decreases bond lengths and bond angles, while the electron correlation effect increases bond lengths slightly. The electronic structure of carbonyl oxide has been predicted to be zwitterionic structure and energy difference between zwitterionic and diradical structure is evaluated to be 22.4 kcal/mol at TZ2P CISD level of theory. The experimental vibrational frequencies and IR intensities of POZ and SOZ will be compared and discussed with our high level theoretical predictions.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2005.10a
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• pp.539-542
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• 2005

In this study, we investigated the influence of vibrational stimulation on postural control. To study the effect, the sway of the center of pressure was observed fur two different visual conditions and for three different patterns of vibrational stimulation on plantar area. The two visual conditions were normal condition with visual feedback and blind condition with both eyes closed. The three vibrational stimulations were white noise, constant vibration, and vibration with amplitude modulations (sine curve modulation). The experimental results showed that the sway of the center of pressure distinctively reduced with white noise vibrational stimulation. This result showed that it's possible to use vibrational stimulation for improving the ability of postural control.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2007.05a
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• pp.181-184
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• 2007

This paper deals with the method of vibration measurement of a gun barrel structure using mechanical filter. When a bullet with high speed is moving within a gun barrel type structure with low bending vibration frequencies, it is difficult to measure the bending vibration signals of the structure. For example, noncontact type sensors such as displacement or velocity sensor are not appropriate for the measurement of vibrational signals because of the movement effect of the equipment frame through the moving structures or effect of the ground vibration. One of contact type sensors such as accelerometer is profitable for measurement of vibrational signals because of its wide measurement ranges. In the case of a gun barrel structure including high vibrational signals like shock waves, however, it is necessary to propose vibration measurement method filtering high frequencies. The purpose of the paper is to propose the proper vibrational measurement technique filtering high frequencies of a gun barrel type structure.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.15 no.2
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• pp.57-65
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• 2016

The suspension system of a subway vehicle is composed of $1^{st}$ and $2^{nd}$ springs. The suspension system is the most important parameter in determining the vibration ride comfort. If the $1^{st}$ suspension spring is designed as a spring with strong stiffness to improve the running stability at high speed, it causes vehicle vibrations. In this paper, by testing and analyzing changes of the characteristics of Chevron springs, which have been the primary suspension springs used for about 20 years, we study how changing the characteristics affects vehicle acceleration and ride comfort. The lateral and longitudinal vibrational ride comfort index levels were lower than the vertical ones. Therefore, as increasing the stiffness of Chevron springs has the greatest effect on the vertical vibrational ride comfort index level, a countermeasure for vertical vibration reduction is needed when the stiffness increases owing to aging. Finally, maintenance guidelines, including the replacement time for the Chevron rubber, were proposed based on these findings.

• Journal of KSNVE
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• v.9 no.3
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• pp.517-524
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• 1999

Mathematical formulas for multi-dimensional isolation analysis via vibrational power transmission can be derived in a rather simple form when the wave effects of the isolators are completely neglected. With increase of frequency range of interest, however, the wave effects play a very important role and hence cannot be neglected. The formulas get involved accordingly. In this study, a method of equivalent stiffness modeling of the isolators to include the wave effects is proposed in such a way that not only the complexity of the mathematical expressions but also that of experiments of necessity can be reduced. This method is illustratively applied to a two-dimensional vibration isolation system with nonrigid source and base structures.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.28 no.12
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• pp.1494-1500
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• 2004

A zero-dimensional direct simulation Monte Carlo(DSMC) model is developed for simulating diatomic gas including vibrational kinetics. The method is applied to the simulation of two systems: vibrational relaxation of a simple harmonic oscillator and translational-rotational-vibrational energy exchange process under heating and cooling. In the present DSMC method, the variable hard sphere molecular model and no time counter technique are used to simulate the molecular collision kinetics. For simulation of diatomic gas flows, the Borgnakke-Larsen phenomenological model is adopted to redistribute the translational and internal energies.