• 한국응용과학기술학회지
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• 제25권3호
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• pp.332-340
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• 2008

Two component polyurethane (PU) flame retardant coatings were prepared by blending trichloro modified polyesters (TCMPs) and isophorone diisocyanate isocyanurate. TCMPs were synthesized by polycondensation of trichlorobenzoic acid (TCBA), a flame retardant component, with adipic acid, 1,4 butanediol, and trimethylolpropane. The content of TCBA was varied in 10, 20, and 30 wt% for the reaction. Theses new flame retardant coatings showed various properties comparable to other non flame retardant coatings. Moreover, we carried out the combustion test and the flammability test for our flame retardant coatings. The results of vertical burning test for the coatings containing more than 20 wt% of TCBA were determined as no burn. The results of flammability test for the coatings with 20 wt% and 30 wt% of TCBA contents indicated the limiting oxygen index (LOI) values of 26% and 29% respectively, which implied relatively good flame retardancy.

• 한국안전학회지
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• 제13권3호
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• pp.119-125
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• 1998

In long vertical duct, the aspect of second flame in laminar flame propagating through lycopodium-air mixtures and the behavior of dust particles in neighborhood in front of flame have been examined experimentally. In order to trace the development of second flame to its origin, the velocity and vorticity distribution of dust particles in front of flame were measured by using with the real-time PIV system. The velocity of particles was approximately zero at the central part of flame front and the ahead of the flame leading edge, but maximum near the duct wall. The flame velocity of second flame and the movement of leading flame edge depend mainly on behavior of dust particles by the flow distribution of temperature and pressure.

• 한국화재소방학회논문지
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• 제18권2호
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• pp.34-40
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• 2004

층류 비예혼합 분류 화염에서 다양한 주파수와 강도로 외부에서 유동장에 자극을 주었을 때 화염의 배출특성과 거동에 대해서 실험적으로 조사하였다. 먼저 일정한 관 공명 주파수에서 가진 강도를 가변시켜 난류화염 된 부상화염에서 질소산화물 배출 지수($EINO_x$)를 측정하였다. 또한, 가진 강도가 일정한 상태에서 주파수를 0 Hz에서 높은 주파수인 2 KHz까지 다양한 주파수 조건으로 가진된 한 경우에도 질소산화물의 배출지수를 측정하였다. 큰 가진 강도의 관공명 주파수로 가진된 경우 부상된 난류화염에서 $NO_x$ 배출 특성은 다음과 같이 크게 세 가지 형태의 특성을 보였다. Group I의 화염에서는 공간적인 섭동이 크며 비교적 화염길이가 길고 높은 $NO_x$ 배출 특성을 보였으며 Group II에서는 상대적으로 짧은 길이와 좁은 폭의 화염거동에 낮은 $NO_x$배출 특성을 보였다. Group III에서는 약간 긴 화염길이에 매우 큰 화염체적으로 상당한 높이까지 시ㆍ공간적으로 섭동이 큰 운동양태로 부상되는 거동과 가장 높은 $NO_x$ 배출 특성을 보였다.

• 조명전기설비학회논문지
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• 제23권5호
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• pp.58-65
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• 2009

전력선이 통과하는 지역에서 발생된 산불은 계통 섬락사고의 원인이 되고 있다. 본 연구에서는 연소화염에 의한 전력선의 절연내력 저하특성을 알아보기 위해 직류 및 교류 전압 인가 시, 연소화염과 고전압 도체의 수평거리(s)를 변화시켰을 때, 수직형 모델 전력선에 대한 섬락특성을 조사하였다. 실험 결과, 수평거리(s)가 작은 범위에서는 화염이 모델선로의 섬락전압을 크게 감소시킬 수 있는 것으로 나타났다. 이러한 섬락전압의 저하요인을 해석하기 위해 화염주변의 상대공기밀도가 고려되었으며, 화염이 존재하는 경우에는 그 영향이 매우 크게 나타남을 알 수 있었다.

• 한국연소학회:학술대회논문집
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• 한국연소학회 2004년도 제29회 KOSCI SYMPOSIUM 논문집
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• pp.117-123
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• 2004

The burning characteristics of interacting coal particles in a convective flow are numerically investigated at various Reynolds numbers. The transient combustion of 2-dimensionally arranged particles, both the fixed particle distances of 5 radii to 20 radii horizontally and 3 radii to 24 radii vertically, is studied. The results obtained from the present numerical analysis reveal that the transient flame configuration and retardation of particle temperature augmentation with the horizontal or vertical particle spacing substantially influence devolatilization process and carbon conversion ratio of interacting particles. Volatile release and carbon conversion ratio of the second particle with decreasing horizontal and vertical particle spacing decrease gradually, whereas those of the first particle with decreasing vertical particle spacing increases due to flow acceleration. When the vertical particle spacing is smaller than $6R_{o}$, volatile release and carbon conversion ratio of the second particle decrease greatly due to reduction of flame penetration depth.

• 한국분무공학회지
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• 제3권4호
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• pp.43-49
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• 1998

In order to clarify the effect of equivalence ratio and kinds of fule in flame structure, a numerical simulation of triple flame developed in a co-flowing methane-air and air stream was carried out by the elementary chemical reaction mechanism. The following conclusions were obtained. Equivalence ratio at which the apparent burning velocity is maximum is a little larger than that of the one-dimensional premixed flame. Apparent burning velocities are two times higher than that of the one-dimensional premixed flame for the methane-air. The flame thrusts out forward in the downstream of the boundary between mixture and air stream, and a part of the flow is bent and forks out in this protruding flame so that a triple flame is originated; this triple flame is composed of fuel rich and lean premixed flame branches and a diffusion flame branch. Near the equivalence ratio at which the burning velocity of rule-dimensional premixed flame is the largest the effect of one-dimensional premixed flame becomes large and the fuel rich premixed flame advances and becomes vertical to the flow direction.

• 한국건축시공학회:학술대회논문집
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• 한국건축시공학회 2022년도 봄 학술논문 발표대회
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• pp.235-236
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• 2022

In the present study, the effect of horizontal vent position on fire phenomena in the enclosure with vertical and horizontal vents was examined using numerical simulation. Case 1 indicates the condition that the horizontal vent is in the center of the ceiling. Case 3 indicates the condition that the horizontal vent is far away from the vertical vent. Case 2 indicates the condition that the horizontal vent is installed between Case 1 and Case 3. The temperature distribution, smoke layer temperature, velocity distribution, and mass flow rate of horizontal vent flow were analyzed. In Case 2, the temperatures were lowest and the mass flow rate through the horizontal vent was largest. This is because the flame is inclined by the inflow through the vertical vent. Hence, to determine the proper horizontal vent location for the high smoke ventilation performance, the inflow through the vertical vent and its effect on flame behavior should be considered.

• 한국화재소방학회:학술대회논문집
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• 한국화재소방학회 2008년도 추계학술논문발표회 논문집
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• pp.283-288
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• 2008

Since installing a balcony can significantly reduce the spread of fire, fire spread to the upper levels was confirmed, comparing the cases with and without balcony extension. It was confirmed that the fire can spread not only to the next higher level but also to two levels higher due to the outburst of flame which reached a significant temperature in the case without balcony, while the possibility of fire spread to the upper level reduced considerably with the balcony. this study is compared and analyzed to vertical diffusion appearance of an externally venting flame. An installed balcony is also applied to fire test 6.54kW to analyze about effect of a balcony.

• 대한전기학회:학술대회논문집
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• 대한전기학회 2001년도 하계학술대회 논문집 C
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• pp.1735-1737
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• 2001

The occurrence of fires under transmission lines is responsible for a great number of power line outages. In this paper, the ac flashover voltages and the corona onset voltages of a needle-plane electrode gap of vertical arrangement in the presence of flame were investigated. We also observed the corona discharge current and variation of shapes in flame with increasing the applied voltages. We found that the corona onset voltages and the flashover voltages were drastically decreased with the position of flames and gap length of electrodes, and observed that the deflection or fluctuation phenomena in the shape of flames.

• Macromolecular Research
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• 제16권7호
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• pp.620-625
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• 2008

A novel nitrogen-phosphorus compound, diphenyl piperazine-1,4-diylbis(methylphosphinate)(DPPMP) was synthesized via a two step reaction and its flame retarding efficiency as a single component additive was investigated. The success of synthesis was confirmed by FTIR and $^1H$ and $^{31}P$ NMR analysis. The product was mixed with polycarbonate (PC), poly(butylene terephtalate) (PBT), ethylene-vinyl-acetate copolymer (EVA), and acrylonitrile-butadiene-styrene copolymer (ABS). The flame-retarding efficiency was evaluated using the limiting oxygen index (LOI) and the UL-94 vertical test methods. The addition of DPPMP enhanced the flame retardancy of the polymers and the V-0 ratings were obtained for the polymers examined in this study at a loading of 7-30 wt%. The gas-phase flame retardancy mode of action was suggested for this material from the thermogrametry experiment results.