• Title/Summary/Keyword: Vertical diffusion coefficient

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On the Crystal Growth of Gap by Synthesis Solute Diffusion Method and Electroluminescence Properties. (합성용질확산법에 의한 GaP결정의 성장과 전기루미네센스 특성)

  • Kim, Seon-Tae;Mun, Dong-Chan
    • Korean Journal of Materials Research
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    • v.3 no.2
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    • pp.121-130
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    • 1993
  • The GaP crystals were grown by synthesis solute diffusion method and its properties were investigated. High quality single crystals were obtained by pull-down the crystal growing ampoule with velocity of 1.75mm/day. Etch pits density along vertical direction of ingot was increased from 3.8 ${\times}{10^4}$c$m^{-2}$ of the first freeze to 2.3 ${\times}{10^5}$c$m^2$ of the last freeze part. The carrier concentration and mobilities at room temperature were measured to 197.49cc$m^2$/V.sec and 6.75 ${\times}{10^{15}}$c$m^{-3]$, respectively. The temperature dependence of optical energy gap was empirically fitted to $E_g$(T)=[2.3383-(6.082${\times}{10^{-4}}$)$T^2$/(373. 096+TJeV. Photoluminescence spectra measured at low temperature were consist with sharp line-spectra near band-gap energy due to bound-exciton and phonon participation in band edge recombination process. Zn-diffusion depth in GaP was increased with square root of diffusion time and temperature dependence of diffusion coefficient was D(Tl = 3.2 ${\times}{10^3}$exp( - 3.486/$k_{\theta}$T)c$m^2$/sec. Electroluminescence spectra of p-n GaP homojunction diode are consisted with emission at 630nm due to recombination of donor in Zn-O complex center with shallow acceptors and near band edge emission at 550nm. Photon emission at current injection level of lower than 100m A was due to the band-filling mechanism.

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Parameter Estimation of Coastal Water Quality Model Using the Inverse Theory (역산이론을 이용한 연안 수질모형의 매개변수 추정)

  • Cho, Hong-Yeon;Cho, Bum-Jun;Jeong, Shin-Taek
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.17 no.3
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    • pp.149-157
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    • 2005
  • Typical water quality (WQ) parameters defined in the governing equation of the WQ model are the pollutant loads from atmosphere and watersheds, pollutant release rates from sediment, diffusion coefficient and reaction coefficient etc. The direct measurement of these parameters is very difficult as well as requires high cost. In this study, the pollutant budget equation including these parameters was used to construct the linear simultaneous equations. Based on these equations, the inverse problems were constructed and WQ parameter estimation method minimizing the sum of squared errors between the computed and observed amounts of the mass changes was suggested. WQ parameters, i.e., the atmospheric pollutant loads, sediment release rates, diffusion coefficients and reaction coefficient, were estimated using .this method by utilizing the vertical concentration profile data which has been observed in Cheonsu Bay and Ulsan Port. Values of the estimated parameters show a large temporal variation. However, this technique is persuasive in that the RHS (root mean square) error was less than $5.0\%$ of the observed value ranges and the agreement index was greater than 0.95.

Characterization and Comparison of Doping Concentration in Field Ring Area for Commercial Vertical MOSFET on 8" Si Wafer (8인치 Si Power MOSFET Field Ring 영역의 도핑농도 변화에 따른 전기적 특성 비교에 관한 연구)

  • Kim, Gwon Je;Kang, Ye Hwan;Kwon, Young-Soo
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.4
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    • pp.271-274
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    • 2013
  • Power Metal Oxide Semiconductor Field Effect Transistor's (MOSFETs) are well known for superior switching speed, and they require very little gate drive power because of the insulated gate. In these respects, power MOSFETs approach the characteristics of an "ideal switch". The main drawback is on-resistance RDS(on) and its strong positive temperature coefficient. While this process has been driven by market place competition with operating parameters determined by products, manufacturing technology innovations that have not necessarily followed such a consistent path have enabled it. This treatise briefly examines metal oxide semiconductor (MOS) device characteristics and elucidates important future issues which semiconductor technologists face as they attempt to continue the rate of progress to the identified terminus of the technology shrink path in about 2020. We could find at the electrical property as variation p base dose. Ultimately, its ON state voltage drop was enhanced also shrink chip size. To obtain an optimized parameter and design, we have simulated over 500 V Field ring using 8 Field rings. Field ring width was $3{\mu}m$ and P base dose was $1e15cm^2$. Also the numerical multiple $2.52cm^2$ was obtained which indicates the doping limit of the original device. We have simulated diffusion condition was split from $1,150^{\circ}C$ to $1,200^{\circ}C$. And then $1,150^{\circ}C$ diffusion time was best condition for break down voltage.

A Study on Accuracy a Passive NO2 Sampler (NO2간이포집기(簡易捕集器) 정도(精度)에 관(關)한 연구(硏究))

  • Chun, Man-Young;Kang, Gong-Unn;Kim, Hui-Kang
    • Journal of Korean Society for Atmospheric Environment
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    • v.8 no.2
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    • pp.93-99
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    • 1992
  • Recently a passive $NO_2$ samplers have been frequently used for the measurement of $NO_2$ concentration in the atmosphere because of its simplicity and high accuracy. But these samplers have a defect that the amount of $NO_2$ adsorbed is increased by wind. In this study, the inlet of sampler was covered with a draft shield made by 325 mesh stainless sieve to eliminate the effect. But it was expected that $NO_2$ diffusion was interrupted by the draft shield. In order to conform this phenomenon, samplers with and without draft shield were exposed to a box filled with 1-1.1ppm $NO_2$. The result indicated that draft shield nearly did not disturb $NO_2$ diffusion. To protect samplers from dust, sunshine, precipitation and vertical wind effects, these samplers were placed into a shelter during the field test. The data obtained in this study was compared with the data from the ambient air monitoring network. The coefficient of correlation(r) between the two data was 0.9995 for the test period of up to 35days. The results of this study indicate that the type of $NO_2$ samplers with draft shield in shelter used in this study can be used for measuring $NO_2$ concentrations in the ambient air relatively for a long period over 30 days.

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Global Ocean Data Assimilation and Prediction System 2 in KMA: Operational System and Improvements (기상청 전지구 해양자료동화시스템 2(GODAPS2): 운영체계 및 개선사항)

  • Hyeong-Sik Park;Johan Lee;Sang-Min Lee;Seung-On Hwang;Kyung-On Boo
    • Atmosphere
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    • v.33 no.4
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    • pp.423-440
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    • 2023
  • The updated version of Global Ocean Data Assimilation and Prediction System (GODAPS) in the NIMS/KMA (National Institute of Meteorological Sciences/Korea Meteorological Administration), which has been in operation since December 2021, is being introduced. This technical note on GODAPS2 describes main progress and updates to the previous version of GODAPS, a software tool for the operating system, and its improvements. GODAPS2 is based on Forecasting Ocean Assimilation Model (FOAM) vn14.1, instead of previous version, FOAM vn13. The southern limit of the model domain has been extended from 77°S to 85°S, allowing the modelling of the circulation under ice shelves in Antarctica. The adoption of non-linear free surface and variable volume layers, the update of vertical mixing parameterization, and the adjustment of isopycnal diffusion coefficient for the ocean model decrease the model biases. For the sea-ice model, four vertical ice layers and an additional snow layer on top of the ice layers are being used instead of previous single ice and snow layers. The changes for data assimilation include the updated treatment for background error covariance, a newly added bias scheme combined with observation bias, the application of a new bias correction for sea level anomaly, an extension of the assimilation window from 1 day to 2 days, and separate assimilations for ocean and sea-ice. For comparison, we present the difference between GODAPS and GODAPS2. The verification results show that GODAPS2 yields an overall improved simulation compared to GODAPS.

Numerical Experiment for the formation of the Yellow Sea cold Water mass (황해저층냉수의 형성에 관한 수치실험)

  • AN, HUI SOO;LEE, HYUN CHUL
    • 한국해양학회지
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    • v.28 no.2
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    • pp.101-106
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    • 1993
  • A simple three-dimensional cubic model is applied to the formation of the Yellow Sea Cold Water Mass in Summer. We studied how the tidal mixing and the Kuroshio Water Mass affect the formation of the Yellow Sea cold Water. The tidal mixing effect is parameterized into the vertical diffusion coefficient because of the technical difficulties in the numerical model In this study, the thermal front along the coast could be formed only by the tidal mixing effect. However, the southern front of the Yellow Sea Cold Water Mass has to consider the warm Kuroshio water. the resultant shows the opposite temperature distribution in upper layer and lower layer. the center of the model is warmer in the upper layer and colder in the lower layer than the coast. The resultant circulation pattern is also reverse, clockwise circulation in the upper layer and counter-clockwise circulation in the lower layer.

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Unsteady Mass Transfer Around Single Droplet Accompanied by Interfacial Extraction Reaction of Succinic Acid (숙신산 추출반응이 일어나는 단일 액적계에서의 비정상상태 물질 전달)

  • Jeon, Sangjun;Hong, Won Hi
    • Korean Chemical Engineering Research
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    • v.50 no.6
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    • pp.1021-1026
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    • 2012
  • The transient mass transfer in a single droplet system consisting of 1-octanol (continuous phase)/aqueous succinic acid solution (dispersed phase) was investigated in the presence of chemical reaction, which is acid/anion exchange reaction of succinic acid and tri-n-octylamine (TOA). This succinic acid extraction by TOA can be considered to occur at the interface between organic and aqueous phase, that is, heterogeneous reaction system. The basic properties of the system such as viscosity, density, distribution coefficient, terminal velocity of droplet, and diffusion coefficient were measured experimentally or calculated theoretically, and used for theoretical calculation of characteristic parameters of mass transfer later. The effects of succinic acid concentration on the terminal velocity was negligible in the existence of TOA, although the terminal velocity increases with succinic acid concentration in the absence of TOA. On the contrary, the terminal velocity decreases with TOA concentration. While droplets falls through organic phase, the trajectory of droplets is observed to oscillate around its vertical path. A mass trnasfer cell was prepared to monitor the mass transfer behavior in a single droplet and used to measure the mean concentration of succinic acid inside droplet. The results are expressed with dimensionless parameters. Under 50 g/L succinic acid condition, the system with 0.1 mol/kg TOA showed that the molar flux decreases in proportion to the decrease of concentration gradient, while in the case of 0.5 mol/kg TOA Sh increases rapidly with time indicating the molar flux of succinic acid decreases relatively slowly compared to the decrease in concentration gradient.