• Journal of Sensor Science and Technology
• /
• v.31 no.3
• /
• pp.175-179
• /
• 2022

The physical properties of biomaterials are important for their isolation and separation from body fluids. In particular, the precise evaluation of the multi-physical properties of single biomolecules is essential in that the correlation between physical and biological properties of specific biomolecule. However, the majority of scientific equipment, can only determine specific-physical properties of single nanoparticles, making the evaluation of the multi-physical properties difficult. The improvement of analytical techniques for the evaluation of multi-physical properties is therefore required in various research fields. In this study, we developed a motion-tracking algorithm to evaluate the multi-physical properties of single-nanoparticles by analyzing their behavior. We observed the Brownian motion and electric-field-induced drift of fluorescent nanoparticles injected in a microfluidic chip with two electrodes using confocal microscopy. The proposed algorithm is able to determine the size of the nanoparticles by i) removing the background noise from images, ii) tracking the motion of nanoparticles using the circular-Hough transform, iii) extracting the mean squared displacement (MSD) of the tracked nanoparticles, and iv) applying the MSD to the Stokes-Einstein equation. We compared the evaluated size of the nanoparticles with the size measured by SEM. We also determined the zeta-potential and surface-charge density of the nanoparticles using the extracted electrophoretic velocity and the Helmholtz-Smoluchowski equation. The proposed motion-tracking algorithm could be employed in various fields related to biomaterial analysis, such as exosome analysis.

• Advances in materials Research
• /
• v.11 no.2
• /
• pp.121-146
• /
• 2022

In the recent years, the use of agricultural waste in green cement mortar and concrete production has attracted considerable attention because of potential saving in the large areas of landfills and potential enhancement on the performance of mortar. In this research, microparticles of palm oil fuel ash (POFA) obtained from a multistage thermal and mechanical treatment processes of raw POFA originating from palm oil mill was utilized as a pozzolanic material to produce high-performance cement mortar (HPCM). POFA was used as a partial replacement material to ordinary Portland cement (OPC) at replacement levels of 0, 5, 10, 15, 20, 25, 30, 35, 40% by volume. Sand with particle size smaller than 300 ㎛ was used to enhance the performance of the HPCM. The HPCM mixes were tested for workability, compressive strength, ultrasonic pulse velocity (UPV), porosity and absorption. The results portray that the incorporation of micro POFA in HPCMs led to a slight reduction in the compressive strength. At 40% replacement level, the compressive strength was 87.4 MPa at 28 days which is suitable for many high strength applications. Although adding POFA to the cement mixtures harmed the absorption and porosity, those properties were very low at 3.4% and 11.5% respectively at a 40% POFA replacement ratio and after 28 days of curing. The HPCM mixtures containing POFA exhibited greater increase in strength and UPV as well as greater reduction in absorption and porosity than the control OPC mortar from 7 to 28 days of curing age, as a result of the pozzolanic reaction of POFA. Micro POFA with finely graded sand resulted in a dense and high strength cement mortar due to the pozzolanic reaction and increased packing effect. Therefore, it is demonstrated that the POFA could be used with high replacement ratios as a pozzolanic material to produce HPCM.

• Proceedings of the Korea Water Resources Association Conference
• /
• 2020.06a
• /
• pp.221-221
• /
• 2020

최근 기후 변화에 따라 국내 하천은 급격한 유량 증가로 인해 하상의 변화에 많은 영향을 미치고 있다. 특히, 홍수시 하상의 변화에 영향을 미치는 유량 및 유속, 하상재료의 종류 및 대표입경, 입자의 특성 등이 있으며, 이런 요인들은 하상재료의 유실에 영향력을 미치고 있다. 또한, 하상재료의 유실에 영향을 미치는 하상재료의 단위중량, 대표입경, 재료의 특성과 관련이 있으나, 현재 까지 다양한 연구가 진행되고 있지만, 하상재료의 한계조건에 영향을 미치는 관련된 연구는 국내에서 미비한 실정이다. 본 연구에서는 하상의 재료의 종류, 입자의 특성, 입자의 크기에 따라 재료가 가지는 한계 유속과 한계 소류력의 영향력을 파악하고자 진행하였다. 본 연구에서 사용된 실험 수로는 인제대학교에서 개발한 무경사형 고속수로(Jung. 2019)는 수조 제원 가로 1.5 m, 세로 0.95 m, 높이 2.4 m, 수로는 개수로의 형태로 총 길이 10 m, 폭과 높이는 각각 0.3 m인 무경사 고속수로에서 진행되었으며, 사용된 재료는 일반 하천에서 사용되고 있는 모래, 황토를 이용하여 적정 비율을 섞어 시료를 제작하였다. 제작된 시료는 하천설계기준에 제시되어 있는 재료에 대한 등급을 비교했을시, 2-3등급 사이의 재료로 판단되며, 모래와 황토의 비율이 50:50 일때 입도 분포가 가장 좋은 재료로 나타났으며, 제작된 시료를 수로에 삽입하여 유하 전후를 수위센서를 통해 세굴율을 측정하였다. 세굴 측정시 모래 100%로 제작된 시료가 가장 많은 세굴이 일어났으며, 모래 25%, 황토 75%로 이루어진 시료가 가장 적은 세굴이 일어났다. 바이오폴리머의 강도 증진을 보기 위해 세굴이 가장 심하거나, 세굴이 적은 재료에 바이오 폴리머를 섞어 추가 실험을 진행 하였다. 본 연구를 통해 친환경적인 하상재료의 한계유속, 한계소류력에 대한 안정성평가를 진행하여 재료의 안전성에 대해 평가하고 기초자료로 기여하고자 한다.

• Journal of Korean Society of Coastal and Ocean Engineers
• /
• v.26 no.1
• /
• pp.49-64
• /
• 2014

Seabed beneath and near the coastal structures may undergo large excess pore water pressure composed of oscillatory and residual components in the case of long durations of high wave loading. This excess pore water pressure may reduce effective stress and, consequently, the seabed may liquefy. If the liquefaction occurs in the seabed, the structure may sink, overturn, and eventually fail. Especially, the seabed liquefaction behavior beneath a gravity-based structure under wave loading should be evaluated and considered for design purpose. In this study, to evaluate the liquefaction potential on the seabed, numerical analysis was conducted using 2-dimensional numerical wave tank. The 2-dimensional numerical wave tank was expanded to account for irregular wave fields, and to calculate the dynamic wave pressure and water particle velocity acting on the seabed and the surface boundary of the structure. The simulation results of the wave pressure and the shear stress induced by water particle velocity were used as inputs to a FLIP(Finite element analysis LIquefaction Program). Then, the FLIP evaluated the time and spatial variations in excess pore water pressure, effective stress and liquefaction potential in the seabed. Additionally, the deformation of the seabed and the displacement of the structure as a function of time were quantitatively evaluated. From the analysis, when the shear stress was considered, the liquefaction at the seabed in front of the structure was identified. Since the liquefied seabed particles have no resistance force, scour can possibly occur on the seabed. Therefore, the strength decrease of the seabed at the front of the structure due to high wave loading for the longer period of time such as a storm can increase the structural motion and consequently influence the stability of the structure.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
• /
• v.15 no.1
• /
• pp.41-50
• /
• 2010

We have developed an in-situ benthic chamber (BelcI) for use in coastal studies that can be deployed from a small boat. It is expected that BelcI will be useful in studying the benthic boundary layer because of its flexibility. BelcI is divided into three main areas: 1) frame and body chamber, 2) water sampler, and 3) stirring devices, electric controller, and data acquisition technology. To maximize in-situ use, the frame is constructed from two layers that consist of square cells. All electronic parts (motor controller, pA meter, data acquisition, etc.) are low-power consumers so that the external power supply can be safely removed from the system. The hydrodynamics of BelcI, measured by PIV (particle image velocimetry), show a typical "radial-flow impeller" pattern. Mixing time of water in the chamber is about 30 s, and shear velocity ($u^*$) near the bottom layer was calculated at $0.32\;cm\;s^{-1}$. Measurements of diffusivity boundary layer thickness showed a range of $180-230\;{\mu}m$. Sediment oxygen consumption rate, measured in-situ，was $84\;mmol\;O_2\;m^{-2}\;d_{-1}$, more than two times higher than on-board incubation results. Benthic fluxes assessed from in-situ incubation were estimated as follows: nitrate + nitrite = $0.18\;{\pm}\;0.07\;mmol\;m^{-2}\;d^{-1}$ ammonium $23\;{\pm}\;1\;mmol\;m^{-2}\;d^{-1}$ phosphate = $0.09\;{\pm}\;0.02\;mmol\;m^{-2}\;d^{-1}$ and silicate = $23\;{\pm}\;1\;mmol\;m^{-2}\;d^{-1}$.

• Journal of the Korean Society for Marine Environment & Energy
• /
• v.19 no.1
• /
• pp.74-85
• /
• 2016

For the assessment of seawater exchange rates in Danghangpo bay, Dangdong bay, Wonmun bay, Gohyunsung bay, and Masan bay, which are small-scale inner bays of Jinhae bay, an EFDC model was used to reproduce the seawater flow of the entire Jinhae bay, and Lagrange (particle tracking) and Euler (dye diffusion) model techniques were used to calculate the seawater exchange rates for each of the bays. The seawater exchange rate obtained using the particle tracking method was the highest, at 60.84%, in Danghangpo bay, and the lowest, at 30.50%, in Masan bay. The seawater exchange rate calculated based on the dye diffusion method was the highest, at 45.40%, in Danghangpo bay, and the lowest, at 34.65%, in Masan bay. The sweater exchange rate was found to be the highest in Danghangpo bay likely because of a high flow velocity owing to the narrow entrance of the bay; and in the case of particle tracking method, the morphological characteristics of the particles affected the results, since once the particles get out, it is difficult for them to get back in. Meanwhile, in the case of the Lagrange method, when the particles flow back in by the flood current after escaping the ebb current, they flow back in intact. However, when a dye flows back in after escaping the bay, it becomes diluted by the open sea water. Thus, the seawater exchange rate calculated based on the dye diffusion method turned out to be higher in general, and even if a comparison of the sweater exchange rates calculated through two methods was conducted under the same condition, the results were completely different. Thus, when assessing the seawater exchange rate, more reasonable results could be obtained by either combining the two methods or selecting a modeling technique after giving sufficiently consideration to the purpose of the study and the characteristics of the coastal area. Meanwhile, through a comparison of the degree of closure and seawater exchange rates calculated through Lagrange and Euler methods, it was found that the seawater exchange rate was higher for a higher degree of closure, regardless of the numerical model technique. Thus, it was deemed that the degree of closure would be inappropriate to be used as an index for the closeness of the bay, and some modifications as well as supplementary information would be necessary in this regard.

• Korean Chemical Engineering Research
• /
• v.57 no.6
• /
• pp.874-882
• /
• 2019

In this study, the gasification characteristics of four types of unused woody biomass and one waste wood in a lab-scale bubbling fluidized bed gasifier (Diameter: 0.11 m, Height: 0.42 m) were investigated. Effect of equivalence ratio (ER) of 0.15-0.3 and gas velocity of $2.5-5U_0/U_{mf}$ are determined at the constant temperature of $800^{\circ}C$ and fuel feeding rate of 1 kg/h. The silica sand particle having an average particle size of $287{\mu}m$ and olivine with an average particle size of $500{\mu}m$ were used as the bed material, respectively. The average product gas composition of samples is as follows; $H_2$ 3-4 vol.%, CO 15-16 vol.%, $CH_4$ 4 vol.% and $CO_2$ 18-19 vol.% with a lower heating value (LHV) of $1193-1301kcal/Nm^3$ and higher heating value (HHV) of $1262-1377kcal/Nm^3$. In addition, it was found that olivine reduced most of C2 components and increased $H_2$ content compared to silica sand, resulting in cracking reaction of tar. The non-condensable tar decreases by 72% ($1.24{\rightarrow}0.35g/Nm^3$) and the condensable tar decreases by 27% ($4.4{\rightarrow}3.2g/Nm^3$).

• Journal of Korea Water Resources Association
• /
• v.50 no.1
• /
• pp.29-35
• /
• 2017

A vehicle rainfall sensor is made to control the operating speed of wipers depending on rainfall. Therefore this is the apparatus to determine the velocity phase of the wipers roughly based on the amount of rainfall. However, the technology which can judge the size of rainfall amount besides determining speed level of the wipers is developing according to the development of the function of rainfall sensor due to the development of technology. In this study, a rainfall measurement by using light scattering by precipitation particles was used. This measurement is to use light signal reflection from front glass and the bigger particle is the less detection of light by light scattering. The detection area of the rainfall sensor and detection channel were extended sizes to increase the accuracy of the rainfall. Also the W-S-R relational expression was developed by using a relationship between the specific precipitation (R) and the amount of sensor detection (S) when there is speed change of the wipers (W) and an indoor rainfall apparatus was used to convert sensing signal to rainfall. The signal system of vehicle rainfall sensor can be converted to the actual rainfall amount by using this formula and if this is provided to users then the vehicle observation network can produce higher-resolution than actual observation network can be produced.

• Applied Chemistry for Engineering
• /
• v.9 no.6
• /
• pp.852-856
• /
• 1998

Effects of packing materials on the pressure fluctuations in a fluidized bed have been analysed using statistical method to interpret fluidized bed behavior. The experiments were carried out in a fluidized bed of 6.7cm - ID, and the experimental variables were particle size and its distributions, fluidizing velocity, aspect ratio, and packing materials, etc. Screen packings are used as packing material, the properties of the pressure fluctuations in the fluidized bed were measured by a differential pressure transducer. The measured properties for the pressure fluctuations were the mean, the standard deviation, and the major frequency of the power spectral density functions, etc. The standard deviations of the pressure fluctuations have been slightly affected in the radial directions of fluidized bed, and almost constant in axial directions the height above 4.5cm of the distributor of fuidized bed without packing materials. The major frequency decreased with increaing packing size, whereas it showed maximum at 10% of packing materials. It has been found that the standard deviation of the pressure fluctuations can effectively explain the fluidized phenomena, and the packing materials severely affected the properties of the pressure fluctuations.

• Transactions of the Korean hydrogen and new energy society
• /
• v.25 no.6
• /
• pp.577-585
• /
• 2014

Nanorod and particle shape $CeO_2$ were synthesized via hydrothermal process and precipitation method, respectively, and used as supports of Pt catalyst for water gas shift (WGS) reaction. Three different durations (12, 48, and 96h) for hydrothermal process were applied for the preparation of nanorod type $CeO_2$. 1.0 wt% of Pt was loaded on the prepared supports with incipient wetness method prior to the catalytic activity tests that were carried out at a GHSV of $95,541h^{-1}$, and a temperature range of 200 to $360^{\circ}C$. Varying duration of hydrothermal process led to the difference in physical characteristics of $CeO_2$ nanorods, such as aspect ratio, BET surface area, pore diameter, and pore volume. Consequently, the catalytic activities of Pt/$CeO_2$ nanorods were affected by the physical characteristics of the supports and appeared to be in the order of Pt/$CeO_2$(12) > Pt/$CeO_2$(48) > Pt/$CeO_2$(96). The comparison of the catalytic activities and results of the analysis (XPS, XRD, SEM, BET and TPR) for the supports revealed that the activity of the catalysts depends on chemical states of the Pt and the support materials in the temperature range that is lower than $280^{\circ}C$. However, the activity is rather dependent on the physical characteristic of the supports because the increased gas velocity limits the mass transfer of reactants in micropores of the supports.