• 한국염색가공학회지
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• 제18권6호
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• pp.63-68
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• 2006

In synthetic/spandex blends fibers, contents of the synthetic fiber by percentage is higher than those of spandex. Thus, the dyeing process of the blends fiber is mainly focused on the synthetic fiber, but not the spandex. In this study, we used several series of vat dyes for dyeing the nylon/spandex blend fabrics and their dyeing properties(fk value) were investigated at various reduction agents, temperatures, pH which have the potential for deep shade dyeing effects. The formamidinesulfinic acid were found to be effective to increase the fk values of the blend fiber compared to sodium hydrosulfite and Rongalit C. Higher temperature($100^{\circ}C$) and lower pH(pH 4) were observed as suitable conditions for maximum fk values.

• 한국염색가공학회지
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• 제14권5호
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• pp.284-293
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• 2002

Nylon 6 and polyester taffeta fabrics are dyed in aqueous medium with vat dyes such as Indanthren Red FBB, Mikethren Blue ACE and Mikethren Blue HR varying the compositions of sodium hydrosulfite and NaOH. Also nylon UMF nonwoven and polyester UMF knitted fabrics are dyed with metal complex and disperse dyes as a reference, and the wash and rubbing fastnesses for these dyes are investigated. In vat dyeing of polyester and nylon taffeta, an optimum composition of sodium hydrosulfite/NaOH is existed at a range of 1∼2wt%/0.2wt%. A good build-up property for Mikethren Blue ACE on nylon 6 UMF nonwoven fabric is shown at high temperature. Vat dyeing of polyester with Mikethren Blue Ace shows a good color shade in a higher temperature, while dyeing with Mitsui Blue HR shows low temperatures. Vat dyes In dyeing of both nylon 6 UMF nonwoven and polyester UMF knitted fabrics have a better wash fastnesses compared with metal complex or disperse dyes.

• Fibers and Polymers
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• 제6권3호
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• pp.244-249
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• 2005

enVix is a novel regenerated cellulosic fiber, which is prepared from cellulose diacetate fiber using environmentally friendly manufacturing process. Vat dyeing properties of the enVix were investigated and compared with those ofregular viscose rayon. The enVix exhibited better dyeability than viscose rayon. The colour yields of vat dyes on the enVix were found to be dependent on dyeing temperature as well as the amount of levelling agent and salt. Good build-up and good to excellent fastness properties were obtained on the en Vix fabric.

• 한국염색가공학회지
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• 제22권2호
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• pp.88-93
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• 2010

Using extracted sepia melanin powder by repeated treatments with aqueous sodium hydroxide and acetic acid solutions, vat dyeing of wool and cotton fabrics was carried out under various dyeing conditions including concentration of melanin, alkali, reducing agent and salt, as well as dyeing time and temperature. A K/S of 25.3 for wool fabrics was obtained at the optimal dyeing condition with 9% owf melanin, 0.5g/L NaOH and 56g/L $Na_2S_2O_4$ without salt at $80^{\circ}C$ for 90minutes. The vat dyeing of sepia melanin was applicable to both cotton and wool fabrics but the wool showed higher dyeability. The color fastness properties of the dyed wool and cotton fabrics were excellent to washing, rubbing and light irradiation.

• 한국염색가공학회지
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• 제21권2호
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• pp.1-6
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• 2009

Recently, polyester is widely used in textile fabrics due to its application potentials in various fields. It is known that askin fabric is prepared with mainly polyester and is enjoyed with various end uses such as marine clothing, underwear, shirts, swimming suits and so on. For this purpose, color fastness should be considered with great importance during its wet processing step. In this context, vat dyes were very much attracted due to the advantage of superior fastness property. Thus, we have used indigo dye towards askin fabric dyeings and investigated corresponding properties namely, dyeing temperature, concentration of dye, reducing agent amount and alkali amount. The results showed that higher color strengths of indigo dyeing on askin fabric were obtained at $110^{\circ}C$, 8% o.w.f, 3g/l, 5g/l, respectively. The color fastness to washing was considerable generally.

• 한국염색가공학회지
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• 제19권3호
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• pp.12-17
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• 2007

In this study, we have investigated properties and behaviors of the indigo vat dyeings on synthetic fibers, namely PET and PTT/Spandex. In addition, indigo vat dyeing conditions such as dyeing temperature, dye concentration and pH were optimized. The finding results show that higher color strengths of indigo dyeings on the two types of applied fibers were obtained at $110^{\circ}C$ and $90^{\circ}C$, respectively. Furthermore, acid leuco dyeings on the fiber substrates using acetic acid and formic acid show higher dye uptake with compared to alkali leuco counterparts.

• 한국염색가공학회지
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• 제13권4호
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• pp.241-248
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• 2001

Natural indigo dyeing has been used mainly on cellulosic fibers and silk during the course of history in Korea. In order to extend the usage of this one of the most important natural dyes, its dyeability on wool fabrics has been studied to find out the optimum dyeing condition for wool fiber which is susceptible to alkaline medium. The dyeing method used was hydrosulphite vat of extracted dye. K/S values of dyed fabrics were investigated to analyze the dyeability of natural indigo on wool fibers and colors were measured through $L^*,\;a^*,\;b^*$ and Munsell Values. Highest K/S values were obtained at the temperature of 60(C and pH 7 to 8. The Munsell Values for hue of wool fabrics dyed with extracted indigo powder using hydrosulphite vat fell mostly in PB range. As the dyebath pH increased, blueness increased. Different dyeing conditions resulted in change of colors of dyed fabrics due to the difference in amounts of indigotin and indirubin contents within the dyed fiber as shown by HPLC.

• 한국염색가공학회지
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• 제30권1호
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• pp.20-28
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• 2018

The near infrared ray camouflage fabric has a near infrared ray reluctance similar to the surrounding environment and has a camouflage effect on the surrounding environment. Synthetic fibers used in military uniforms are difficult to have gastrointestinal function as general commercial dyes, unlike cellulose fibers, which use some commercial vat dyes to impart infrared gastrointestinal function. In this study, we optimized the adsorption pH, temperature and time for NIR dye application for polyester fabrics, and established the optimum concentration for the evaluation of adsorption build-up characteristics. In addition, it is difficult to adsorb it since the polyester material has a dense crystal structure and the NIR dye is bulky. Therefore, a swelling agent used for dyeing meta-aramid fibers with high Tg and high crystallinity was introduced as a separate preparation to increase the affinity to polyester, which is a hydrophobic fiber, to thereby obtain an excellent adsorption rate. As a result of comparing before and after using swelling agent, the adsorption rate difference was 10 times or more when compared with before.

• Environmental Engineering Research
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• 제25권4호
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• pp.529-535
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• 2020

The present study investigated the photodegradation of synthetic organic dye; violet-3B, without and with the addition of C-N-codoped TiO₂ catalyst using a visible halogen-lamp as a light source. The catalyst was synthesized by using a peroxo sol-gel method with free-organic solvent. The effects of initial dye concentration, catalyst dosage, and pH solution on the photodegradation of violet-3B were examined. The efficiency of the photodegradation process for violet-3B dye was higher at neutral to less acidic pH. The kinetics reaction rate of photodegradation of violet-3B dye with the addition of C-N-codoped TiO₂ followed pseudo-first order kinetics represented by the Langmuir-Hinshelwood model, and increasing the initial concentration of dyes decreased rate constants of photodegradation. Photodegradation of 5 mg L^-1 violet-3B dye achieved 96% color removal within 240 min of irradiation in the presence of C-N-codoped TiO₂ catalyst, and approximately 44% TOC was removed as a result of the mineralization.

• 한국의류산업학회지
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• 제15권2호
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• pp.192-201
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• 2013

This study explores the culture surrounding the dyeing of royal garments in the late Joseon Dynasty. The findings of this study are as follows. First, several dyes were used to color royal garments, such as jicho, honghwa, danmok, simhwang, sambo, goehwa, chija, and namjong. Mordants such as maesil, hwanghoemok, yeohoe, and baekban were also used with the dyes. Second, the Sangeuiwon (尙衣院) was the department in charge of the purchasing of dyes and the entire dyeing practice. It was the Seonhyecheong (宣惠廳) and the Hojo (戶曹) who provided revenue to the Sangeuiwon through a wongong, regular tribute, and a bokjeong (supplementary tribute). Additionally, additional dyes, if found to be insufficient, could be provided by the Hojo. Every year the Hojo provided jicho, honghwa, and danmok to the Sangeuiwon, and sometimes imported namjong from China. Third, royal garments were, in most cases, dyed by the Sangeuiwon's professional dyers and court ladies belonging to the sewing department in each palace. Naenongpo (內農圃) eunuchs were in charge of the indigo crops of each palace. Finally, more dye was used in royal garments than in the clothes of commoners to obtain a deeper shade of color. In addition, dyers tried to achieve a clear and vivid tone in their garments. Silk which absorbed color relatively easily, was dyed inside the palace using an ice vat filled with fresh indigo leaves; however, cotton was difficult to dye and was sent to professional indigo dyers outside the palace.