• 한국결정성장학회지
• /
• 제19권1호
• /
• pp.39-47
• /
• 2009

The effects of thermo-solutal convection on mercurous chloride system of ${Hg_2}{Cl_2}$, and Ne during physical vapor transport are numerically investigated for further understanding and insight into essence of transport phenomena, For $10\;K{\le}{\Delta}T{\le}30\;K$, the growth rate slowly increases and, then is decreased gradually until ${\Delta}T$=50 K, The occurrence of this critical point near at ${\Delta}T$=30 K is likely to be due to the effects of thermo-physical properties stronger than the temperature gradient corresponding to driving force for thermal convection. For the range of $10\;Torr{\le}P_B{\le}300\;Torr$, the rate is second order-exponentially decayed with partial pressures of component B, $P_B$. For the range of $5{\le}M_B{\le}200$, the rate is second order-exponentially decayed with a function of molecular weight of component B, $M_B$. Like the case of a partial pressure of component B, the effects of a molecular weight arc: reflected through the binary diffusivity coefficients, which are intimately related with suppressing the convection flow inside the growth enclosure, i,e., transition from convection to diffusion-dominant flow mode as the molecular weight of B increases. The convective mode is near at a ground level, i,e., on earth (1 $g_0$), and the convection is switched to the diffusion mode for $0.1\;g_0{\le}g{\le}10^{-2}g_0$, whereas the diffusion region ranges from $10^{-2}g_0$ up to $10^{-5}g_0$.

• 공업화학
• /
• 제26권6호
• /
• pp.746-752
• /
• 2015

본 연구에서는 $Hg_2Cl_2-NO$의 물리적 승화법 공정에서의 확산-대류에 미치는 에스펙트 비율(길이/폭)의 영향에 대한 것이다. 원료물질 영역과 결정영역에서의 온도 차 20 K, 벽에서의 선형 온도분포를 가진 계에서, 대류의 영향 때문에, 총몰플럭스와 상호계면에서의 비균일성에 관하여서는, 에스펙트 비율이 2인 경우가 비율이 5인 경우보다 상당히 크다. 지상중력 하에서의 최고 총몰플럭스는 지상중력의 0.1 상태에 비하여 대략 2배 정도 크다. 에스펙트 비율을 2에서 5로 증가시켰을 때, 확산-대류형이 대류형으로 전이되며, 또한 확산의 강도도 확산-대류형의 강도를 지배하게 된다.

• 대한기계학회:학술대회논문집
• /
• 대한기계학회 2001년도 춘계학술대회논문집D
• /
• pp.360-364
• /
• 2001

Numerical Aanlysis is made on the thermal performance of micro heat pipe in a axial flat grooved channel. The flow of liquid and vapor is investigated in trapezoidal grooves and the effect of variable shear stress along the interface of the liquid and vapor considered. The results from this study are obtained in the axial variation of pressure difference between vapor and liquid, contact angle, velocity of liquid and vapor and so forth. In addition, maximum heat transport capacity of micro-heat pipe is provided by varying the operation temperature, and compared with that from Schneider and Devos's model in which the interfacial shear stress is neglected.

• 한국진공학회:학술대회논문집
• /
• 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
• /
• pp.364.1-364.1
• /
• 2016

We report the characteristics of individual ultra-long SnO2 nanowires(NWs) grown on sapphire(0001) substrates by vapor transport method. NWs, with typical lengths of >$400{\mu}m$, grew in the form of NW bundles under a hydrogen reducing atmosphere, without metal catalysts. The individual NWs were examined using high-resolution X-ray diffraction, transmission electron microscopy, and micro-Raman spectroscopy. The results revealed that the SnO2 NWs grew as high-quality, tetragonal-rutile-phase single crystals with mosaic distributions of $0.02^{\circ}$ and $0.026^{\circ}$ in the (101) and (110) planes, respectively.

• 한국결정성장학회지
• /
• 제28권4호
• /
• pp.148-151
• /
• 2018

물리기상이동법(Physical Vapor Transport(PVT) method)을 적용하여 질화알루미늄 단결정을 성장하였다. 자체적으로 성장하고 제조한 직경 33 mm 크기의 종자결정을 사용하여 직경 46 mm, 길이 7.6 mm 크기의 벌크단결정을 성장하였으며, 성장 온도는 $1950{\sim}2100^{\circ}C$, 성장 압력은 0.1~1 atm의 범위에서 조절하여 반복 성장을 통하여 성장한 결과를 보고하고자 한다.

• 한국결정성장학회지
• /
• 제27권2호
• /
• pp.80-88
• /
• 2017

In this research a time dependent thermal and solutal convection was computationally investigated for the physical vapor transport of the mixture of $Hg_2Cl_2-I_2$ system with for the convective regime from thermal Rayleigh number of $2.16{\times}10^6$ up to $1.7{\times}10^7$ with marching time to a steady state problem. With time marching, the convective cells are decreased for the thermal Rayleigh number of $2.16{\times}10^6$, and increased for the thermal Rayleigh number of $1.7{\times}10^7$. The convective flow structures are found to be essentially time independent on the horizontal orientation of the enclosure with respect to the gravity vector, and on the other hand, time dependent on the vertical orientation of the enclosure with respect to the gravity vector.

• 한국결정성장학회지
• /
• 제7권4호
• /
• pp.560-566
• /
• 1997

Seeded vapor transport법에 의해 성장된 ZnSe 결정내에서 전위거동을 살펴보았다. (111)과 (100) ZnSe wafer의 etch pit 형상을 관찰하였고 성장된 결정이 높은 전위밀도를 가지면 전위들이 lineage와 cellular 두 가지 형태로 배열됨을 알았다. Seed로부터 측방성장된 부위에서 전위밀도의 변화는 없었으나 수직 성장방향으로는 전위밀도가 감소하였고, 같은 wafer내에서 전위밀도는 wafer center 지역의 전위밀도가 edge부위의 전위밀도 보다 낮았다. 성장된 결정의 평균 전위밀도는 $4{\times}10^4 /\textrm{cm}^2$이었다.

• 한국결정성장학회지
• /
• 제28권2호
• /
• pp.63-68
• /
• 2018

Natural convection of a two dimensional laminar steady-state incompressible fluid flow in a rectangular enclosure has been investigated numerically for low aspect ratios with the physical vapor transport crystal growth. Results show that for aspect ratio (Ar = L/H) range of $0.1{\leq}Ar{\leq}1.5$, with the increase in Grashof number by one order of magnitude, the total mass flux is much augmented, and is exponentially decayed with the aspect ratio. Velocity and temperature profiles are presented at the mid-width of the rectangular enclosure. It is found that the effect of Grashof number on mass transfer is less significant when the enclosure is shallow (Ar = 0.1) and the influence of aspect ratio is stranger when the enclosure is tall and the Grashof number is high. Therefore, the convective phenomena are greatly affected by the variation of aspect ratios.

• 대한기계학회:학술대회논문집
• /
• 대한기계학회 2003년도 추계학술대회
• /
• pp.73-78
• /
• 2003

The InP thin films grown by metalorganic chemical vapor deposition (MOCVD) are widely used to optoelectronic devices such as laser diodes, wave-guides and optical modulators. Effects of various parameters controlling film growth rate such as gas-phase reaction rate constant, surface reaction rate constant and mass diffusivity are numerically investigated. Results show that at the upstream region where film growth rate increases with the flow direction, diffusion including thermal diffusion plays an important role. At the downstream region where the growth rate decreases with flow direction, film deposition mechanism is revealed as a mass-transport limited. Mass transport characteristics are also studied using systematic analyses.

• 한국지하수토양환경학회:학술대회논문집
• /
• 한국지하수토양환경학회 1996년도 경북지부 결성 및 추계학술발표회 논문집
• /
• pp.50-53
• /
• 1996

This paper reports the experimental results for the determination of the overall partition coefficient of VOCs in unsaturated soil, A chromatographic method was used for the determination of gaseous partition coefficients to natural soil under various water content conditions. The equilibrium vapor pressure of water over saturated salt solution was used to fix the relative humidity of the air and control the water content of the soil systems. The transport behavior was studied for dichloromethane, trichloroethane and dichlorobenzene pollutants, with log octanol-water partition coefficients(log $K_{ow}$ ) which range from 1.25 to 3.39, or water to soil partitioning which varies by 135 times; water solubility constants which vary by 3 times; and vapor pressures which range from 1 to 362 torr. Water content of the soil had a pronounced effect on the effective partition coefficient(between gas and soil + water stationary phase) as well as on the effective dispersion coefficient.