• Title/Summary/Keyword: Vapor phase

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Experimental Study on Two-Phase Flow Parameters of Subcoolet Boiling in Inclined Annulus

  • Lee, Tae-Ho;Kim, Moon-Oh;Park, Goon-Cherl
    • Nuclear Engineering and Technology
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    • v.31 no.1
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    • pp.29-48
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    • 1999
  • Local two-phase flow parameters of subcooled flow boiling in inclined annulus were measured to investigate the effect of inclination on the internal flow structure. Two-conductivity probe technique was applied to measure local gas phasic parameters, including void fraction, vapor bubble frequency, chord length, vapor bubble velocity and interfacial area concentration. Local liquid velocity was measured by Pilot tube. Experiments were conducted for three angles of inclination; 0$^{\circ}$(vertical), 30$^{\circ}$, 60$^{\circ}$. The system pressure was maintained at atmospheric pressure. The range of average void fraction was up to 10% and the average liquid superficial velocities were less than 1.3 m/sec. The results of experiments showed that the distributions of two-phase How parameters were influenced by the angle of channel inclination. Especially, the void fraction and chord length distributions were strongly affected by the increase of inclination angle, and flow pattern transition to slug flow was observed depending on the How conditions. The profiles of vapor velocity, liquid velocity and interfacial area concentration were found to be affected by the non-symmetric bubble size distribution in inclined channel. Using the measured distributions of local phasic parameters, an analysis for predicting average void fraction was performed based on the drift flux model and flowing volumetric concentration. And it was demonstrated that the average void fraction can be more appropriately presented in terms of flowing volumetric concentration.

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Integral Analysis of the Effects of Non-absorbable gases on the Heat Mass Transfer of Laminar Falling Film

  • Kim, Byong-Joo
    • International Journal of Air-Conditioning and Refrigeration
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    • v.6
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    • pp.56-66
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    • 1998
  • The absorption process of water vapor in a liquid film is an important process in LiBr-Water absorption system. The composition of the gas phase, in which a non-absorbable gas is combined with the absorbate, influences the transport characteristics. In the present work, the absorption processes of water vapor into aqueous solutions of lithium bromide in the presence of non-absorbable gas are investigated. The continuity, momentum, energy and diffusion equations for the solution film and gas are formulated in integral forms and solved numerically. It is found that the mass transfer resistance in gas phase increases with the concentration of non-absorbable gas. However the primary resistance to mass transfer is in the liquid phase. As the concentration of non-absorbable gas in the absorbate increases, the interfacial temperature and concentration of absorbate in solution decrease, which results in the reduction of absorption rate. The reduction of mass transfer rate is found to be significant for the addition of a small amount of non-absorbable gas to the pure vapor, especially at the outlet of tube where the non-absorbable gas accumulates. At higher non-absorbable gas concentration, the decrease of absorption rate seems to be linear to the concentration of non-absorbable gas.

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Selective regrowth of InP current blocking layer by chloride vapor phase epitaxy on mesa structures (Chloride VPE 법에 의한 메사 구조위에 InP 전류 차단막의 선택적 재성장)

  • 장영근;김현수;최훈상;오대곤;최인훈
    • Journal of the Korean Vacuum Society
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    • v.8 no.3A
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    • pp.207-212
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    • 1999
  • Undoped InP epilayers with high purity were grown by using $In/PCl_3/H_2$ chloride vapor phase epitaxy. It was found that the growth of InP homoepitaxial layer is optimized at the growth temperature of $630^{\circ}C$ and at the $PCl_3$ molar fraction of $1.2\times10^{-2}$. The carrier concentration of InP epilayer was less than $10^{14} {cm}^{-3}$ from the low temperature (11K) photoluminescence measurement. Growth behavior of undoped InP current blocking layer on reactive ion-etched (RIE) mesas has been investigated for the realization of 1.55 $\mu \textrm m$buried-heterostructure laser diode (BH LD), using chloride vapor phase epitaxy. On the base of InP homoepitaxy, InP current blocking layers were grown at the growth temperatures ranging from $620^{\circ}C$ to $640^{\circ}C$. Almost planar grown surfaces without edge overgrowth were achieved as the growth temperature increased. It implied that higher temperature enhanced the surface diffusion of the growth species on the {111} B planes and suppressed edge overgrowth.

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Corrosion Behavior of Ytterbium Silicates in Water Vapor Atmosphere at High Temperature for Environmental Barrier Coating Applications (환경차폐코팅용 이터븀 실리케이트의 고온 수증기부식 거동)

  • Min-Ji Kim;Jae-Hyeong Choi;Seongwon Kim
    • Journal of the Korean institute of surface engineering
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    • v.56 no.6
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    • pp.443-450
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    • 2023
  • SiC/SiCf CMC is vulnerable to water vapor corrosion at a high temperature of 1500℃. So, EBC (Environmental Barrier Coating) materials are required to protect Si-based CMCs. Ytterbium silicates are reported to have coefficient of thermal expansion (CTE) similar to that of the base material, such as SiC/SiCf CMC. When the EBC are materials exposed to high temperature environment, the interface between ytterbium silicates and SiC/SiCf CMC is not separated, and the coating purpose can be safely achieved. For the perspective of EBC applications, thermally grown oxide (TGO) layer with different CTE is formed by the reaction with water vapor in EBC, which leads to a decrease in life time. In this study, we prepare two types of ytterbium silicates to observe the corrosion behavior during the expose to high temperature and water vapor. In order to observe this behavior, the steam-jet furnace is prepared. In addition, phase formation of these ytterbium silicates is analyzed with microstructures by the before/after steam-jet evaluation at 1500℃ for 100 h.

A Numerical Model for Heat and Mass Transfer Processes within a Vertical Tube GAX Absorber (수직원관형 GAX 흡수기 내부의 열 및 물질전달과정에 대한 수치모델)

  • 천태식;정은수
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.12 no.1
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    • pp.102-111
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    • 2000
  • A numerical model which simulates the simultaneous heat and mass transfer within a vertical tube GAX absorber was developed. The ammonia vapor and the solution liquid are in counter-current flow, and the hydronic fluid flows counter to the solution liquid. The film thickness and the velocity distribution of the liquid film were obtained by matching the shear stress at the liquid-vapor interface. Two-dimensional diffusion and energy equations were solved in the liquid film to give the temperature and concentration, and a modified Colburn-Drew analysis was used for the vapor phase to determine the heat and mass fluxes at the liquid-vapor interface. The model was applied to a GAX absorber to investigate the absorption rates, temperature and concentration profiles, and mass flow rates of liquid and vapor phases. It was shown that the mass flux of water was negligible compared with that of ammonia except the region near the liquid inlet. Ammonia absorption rate increases rapidly near the liquid inlet and decrease slowly. Both the absorption rate of ammonia vapor and the desorption rate of water near the liquid inlet increase as the vapor mass flow rate increases, but the mass fluxes of the ammonia and the water near the liquid outlet decrease as the mass flow rate of the vapor increases.

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Influence of Mg Vapor Pressure on the $MgB_2$/Carbon Fiber Fabricated by Physical Vapor Deposition method

  • Li, Xiang;Ha, Hong-Soo;Kim, Cheol-Jin
    • Progress in Superconductivity and Cryogenics
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    • v.13 no.4
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    • pp.5-9
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    • 2011
  • We have fabricated the superconducting $MgB_2$/carbon fiber by physical vapor deposition method. Mg (Magnesium) and B (Boron) were simultaneously deposited on the carbon fiber using the RF-sputtering and thermal evaporation, respectively. To ensure the relatively high vapor pressure of Mg at the growth region and the subsequent phase stability of $MgB_2$ at the deposition temperature, inverted funnel-like guide made of Mg-foil was employed while one side of the guide were open for the sputtered B flux. Mg vapor pressure should be controlled precisely to secure the complete reaction. The $MgB_2$/carbon fiber showed a uniformly deposited thin layer with dense and well-formed grains. The $MgB_2$/carbon fibers in this study showed $T_c$~37.5K, $J_c$ ~ $2{\times}10^4\;A/cm^2$ in the 20K, 0T.

Flow Visualization of Oscillation Characteristics of Liquid and Vapor Flow in the Oscillating Capillary Tube Heat Pipe

  • Kim, Jong-Soo;Kim, Ju-Won;Jung, Hyun-Seok
    • Journal of Mechanical Science and Technology
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    • v.17 no.10
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    • pp.1507-1519
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    • 2003
  • The two-phase flow patterns for both non-loop and loop type oscillating capillary tube heat pipes (OCHPs) were presented in this study. The detailed flow patterns were recorded by a high-speed digital camera for each experimental condition to understand exactly the operation mechanism of the OCHP. The design and operation conditions of the OCHP such as turn number, working fluid, and heat flux were varied. The experimental results showed that the representative flow pattern in the evaporating section of the OCHP was the oscillation of liquid slugs and vapor plugs based on the generation and growth of bubbles by nucleate boiling. As the oscillation of liquid slugs and vapor plugs was very speedy, the flow pattern changed from the capillary slug flow to a pseudo slug flow near the annular flow. The flow of short vapor-liquid slug-train units was the flow pattern in the adiabatic section. In the condensing section, it was the oscillation of liquid slugs and vapor plugs and the circulation of working fluid. The oscillation flow in the loop type OCHP was more active than that in the non-loop type OCHP due to the circulation of working fluid in the OCHP. When the turn number of the OCHP was increased, the oscillation and circulation of working fluid was more active as well as forming the oscillation wave of long liquid slugs and vapor plugs in the OCHP. The oscillation flow of R-142b as the working fluid was more active than that of ethanol and the high efficiency of the heat transfer performance of R -142b was achieved.

Applications of Cryogenic Method to Water Vapor Sampling from Ambient Air for Isotopes Analysis (수증기 동위원소 측정을 위한 저온채집법에 대한 연구)

  • Kim, Songyi;Han, Yeongcheol;Hur, Soon-Do;Lee, Jeonghoon
    • Ocean and Polar Research
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    • v.38 no.4
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    • pp.339-345
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    • 2016
  • Stable water vapor isotopes have been utilized as a tracer for studying atmospheric global circulations, climate change and paleoclimate with ice cores. Recently, since laser spectroscopy has been available, water vapor isotopes can be measured more precisely and continuously. Studies of water vapor isotopes have been conducted over the world, but it is the early stage in south Korea. For vapor isotopes study, a cryogenic sampling device for water vapor isotopes has been developed. The cryogenic sampling device consists of the dewar bottle, filled with extremely low temperature material and impinger connected with a vacuum pump. Impinger stays put in the dewar bottle to change the water vapor which passes through the inside of impinger into the solid phase as ice. The fact that water vapor has not sampled completely leads to isotopic fractionation in the impinger. To minimize the isotopic fractionation during sampling water vapor, we have tested the method using a serial connection with two sets of impinger device in the laboratory. We trapped 98.02% of water vapor in the first trap and the isotopic difference of the trapped water vapor between two impinger were about 20‰ and 6‰ for hydrogen and oxygen, respectively. Considering the amount of water vapor trapped in each impinger, the isotopic differences for hydrogen and oxygen were 0.33‰ and 0.06‰, respectively, which is significantly smaller than the precision of isotopic measurements. This work can conclude that there is no significant fractionation during water vapor trapping.

Synthesis of Nano-sized Tungsten Carbide Powders by Vapor Phase Reaction of Tungsten Ethoxide (텅스텐 에톡사이드의 기상 반응을 이용한 초미립 WC 분말의 합성)

  • 가미다;하국현;김병기
    • Journal of Powder Materials
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    • v.10 no.1
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    • pp.1-5
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    • 2003
  • Nano-sized WC powders were synthesized by vapor phase reaction using the precusor of tungsten ethoxide under helium and hydrogen atmosphere. The phases of the powder were varied with reaction Bone and gas flow rate. The powder size was about 30nm in diameter, and the tungsten carbide powder was coated by carbon layer. The synthesis of nano-sized WC powders was promoted as the hydrogen gas flow rate became higher. Inversely, tungsten oxide was formed by increasing the flow rate of helium gas. The synthesized powders were analyzed by XRD, FE-SEM, carbon analyzer etc.

Preparation of Novel Sorbents for Gas-phase Mercury Removal

  • Lee, Si-Hyun;Rhim, Young-Jun;Park, Young-Ok
    • Carbon letters
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    • v.3 no.4
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    • pp.187-191
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    • 2002
  • In the present research, we prepared the activated carbon (AC) sorbents to remove gas-phase mercury. The mercury adsorption of virgin AC, chemically treated AC and fly ash was performed. Sulfur impregnated and sulfuric acid impregnated ACs were used as the chemically treated ACs. A simulated flue gas was made of SOx, NOx and mercury vapor in nitrogen balance. A reduced mercury adsorption capacity was obtained with the simulated gas as compared with that containing only mercury vapor in nitrogen. With the simulated gas, the sulfuric acid treated AC showed the highest performance, but it might have the problem of corrosion due to the emission of sulfuric acid. It was also found that the high sulfur impregnated AC also released a portion of sulfur at $140^{\circ}C$. Thus, it was concluded that the low sulfur impregnated AC was suitable for the treatment of flue gas in terms of stability and efficiency.

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