• Journal of Korean Society for Atmospheric Environment
• /
• v.20 no.3
• /
• pp.411-419
• /
• 2004

Titania particles are widely used as a photocatalyst to treat various contaminants in air and water. Titania particles were formed by vapor-phase oxidation of titanium tetraisopropoxide (TTIP) in a tube furnace between 773 and 1,273 K. The effect of process variables such as furnace temperature, flow rate of carrier air, and flow rate of sheath air on powder size and phase characteristics was investigated using a scanning mobility particle sizer (SMPS), transmission electron microscopy (TEM) and X-ray diffraction (XRD). The size distribution of synthesized titania particles was characterized with mode diameter and peak concentration. The mode diameter ranging from 20 to 80 nm decreased with increasing flow rates of sheath air and carrier air, and increased with increasing furnace temperature. The peak concentration increased with increasing flow rates of sheath air and carrier air The best synthetic condition for high production rate can be derived from the experimental data set represented by mode diameter and peak concentration. The crystal structure of synthesized titania particles was found to be anatase phase, ensuring high photocatalytic potential.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
• /
• v.16 no.2
• /
• pp.194-201
• /
• 2004

In the present study, the improvement of absorption characteristics on combined heat and mass transfer process in a falling film of a vertical absorber by change of geometric parameters were studied experimentally and analytically. The energy and diffusion equations are solved simultaneously to give the temperature and concentration variations at the liquid solution-refrigerant vapor interface and at the wall. Absorption behaviors of heat and mass transfer were analyzed through falling film of the LiBr aqueous solution contacted by refrigerant vapor in the absorber. Effects of film Reynolds number, geometric parameters by insert device (spring) and flow pattern on heat and mass transfer performances have been also investigated. Especially, effects of the flow pattern by geometric parameters have been considered to observe the total heat and mass transfer rates through falling film along the absorber. As a numerical and experimental result, maximum absorption rate was shown at the wave-flow by insert device (spring). The error ranges between experiment and analysis were from 5.8 to 12％ at Re$_{f}$ > 100.0.

• Journal of the Semiconductor & Display Technology
• /
• v.22 no.2
• /
• pp.35-39
• /
• 2023

Silicon oxide thin films have been deposited by plasma-enhanced chemical vapor deposition in SiH4 and N2O plasma along the variation of the gas flow ratio. Optical emission spectroscopy was employed to monitor the plasma and ellipsometry was employed to obtain refractive index of the deposited thin film. The atomic ratio of Si, O, and N in the film was obtained using XPS depth profiling. Fourier Transform Infrared Spectroscopy was used to analyze structures of the films. RI decreased with the increase in N2O/SiH4 gas flow ratio. We noticed the increase in the Si-O-Si bond angles as the N2O/SiH4 gas flow ratio increased, according to the analysis of the Si-O-Si stretching peak between 950 and 1,150 cm-1 in the wavenumber. We observed a correlation between the optical emission intensity ratio of (ISi+ISiH)/IO. The OES intensity ratio is also related with the measured refractive index and chemical composition ratio of the deposited thin film. Therefore, we report the added value of OES data analysis from the plasma related to the thin film characteristics in the PECVD process.

• Nuclear Engineering and Technology
• /
• v.55 no.12
• /
• pp.4561-4569
• /
• 2023

A correct understanding of vibration-based degradation is crucial from the standpoint of maintenance for Steam Generators (SG) as crucial mechanical equipment in nuclear power plants. This study has established a novel approach to developing a model for investigating tube bundle degradation according to crack growth caused by two-phase Flow-Induced Vibration (FIV). An important step in the approach is to calculate the two-phase flow field parameters between the SG tube bundles in various zones using the porous media model to determine the velocity and vapor volume fraction. Afterward, to determine the vibration properties of the tube bundles, the Fluid-Solid Interaction (FSI) analysis is performed in eighteen thermal-hydraulic zones. Tube bundle degradation based on crack growth using the sixteen most probable initial cracks and within each SG thermal-hydraulic zone is performed to calculate useful lifetime. Large Eddy Simulation (LES) model, Paris law, and Wiener process model are considered to model the turbulent crossflow around the tube bundles, simulation of elliptical crack growth due to the vibration characteristics, and estimation of SG tube bundles degradation, respectively. The analysis shows that the tube deforms most noticeably in the zone with the highest velocity. As a result, cracks propagate more quickly in the tube with a higher height. In all simulations based on different initial crack sizes, it was observed that zone 16 experiences the greatest deformation and, subsequently, the fastest degradation, with a velocity and vapor volume fraction of 0.5 m/s and 0.4, respectively.

• Journal of Advanced Marine Engineering and Technology
• /
• v.27 no.1
• /
• pp.108-116
• /
• 2003

In this paper, the experimental results of condensation heat transfer were reported for the plate and shell heat exchangers(P&SHE) using R-l34a. An experimental refrigerant loop has been established to measure the condensation heat transfer coefficient of R-l34a in a vertical P&SHE. Two vertical counter flow channels were formed in the P&SHE by three plates of geometry with a corrugated trapezoid shape of a chevron angle of 45$^{\circ}$. Downflow of the condensing R-l34a in one channel releases heat to the cold up flow of water in the other channel. The effect of the refrigerant mass flux, average heat flux, system pressure and vapor quality of R-l34a on the measured data were explored in detail. The results indicate that at a higher vapor quality the condensation heat transfer coefficients are significantly higher. Condensation heat transfer coefficients were increased when the refrigerant mass flux was increased. A rise in the average heat flux causes an slight increase in the hr. Finally, at a higher system pressure the hr is found to be lower. Correlation is also provided for the measured heat transfer coefficients in terms of the Nusselt number.

• Journal of Powder Materials
• /
• v.11 no.6 s.47
• /
• pp.515-521
• /
• 2004

Fe(C) nanocapsules were prepared by the chemical vapor condensation(CVC) process using the pyrolysis of iron pentacarbonyl $(Fe(CO)_5)$. Their characterizations were studied by means of X-ray diffraction, X-ray photoelectron spectrometer and transmission electron microscopy. The long-chained Fe(C) nanocapsules hav-ing the mean size of under 70 nm could be obtained below $1100^{\circ}C$ in different gas flow rates. The particle size of the powders was increased with increasing decomposition temperature, but it was decreased with increasing CO gas flow rate. The Fe powders produced at $500^{\circ}C$ consisted of three layers of ${\alpha}$-Fe/$Fe_3C$/amorphous phases, but it had two phase core-shell structure which consited of $Fe_3C$ phase of core and graphite of shell at $1100^{\circ}C$.

• Proceedings of the KSME Conference
• /
• 2003.11a
• /
• pp.472-477
• /
• 2003

This study was performed to investigate the behavior of vapor phase of fuel mixtures with different piston cavity diameters in a optically accessible engine. The images of vapor phases were measured in the motoring engine using exciplex fluorescence method. The conventional engine was modified as GDI engine with swirl flow. Fuel was injected into atmospheric nitrogen to prevent quenching phenomenon by oxygen. Injection pressure is 5.1MPa. Two dimensional spray fluorescence image of vapor phases was acquired to analyze spray behavior and fuel distribution inside of cylinder. Three injection timings were set at BTDC $180^{\circ}$, $60^{\circ}$and $60^{\circ}$. With a fuel injection timing of BTDC $60^{\circ}$, fuel-rich mixture was concentrated in near the cavity center. With a fuel injection timing of BTDC $60^{\circ}$, fuel-rich mixture level in the center region was highest in the S-type during the late compression stroke. With a fuel injection timing of BTDC $180^{\circ}$, fuel was not affected in a piston cavity and generally distributed as homogeneous mixture.

• Mass Spectrometry Letters
• /
• v.5 no.4
• /
• pp.120-123
• /
• 2014

The interference of water vapor on the chemical ionization (CI) of hydroxyl radicals (OH) by sulfur hexafluoride ion ($SF_6{^-}$) was investigated using a flow tube system coupled to a high-pressure CI mass spectrometer. Water vapor, which is required to study heterogeneous reactions of OH under real tropospheric conditions, transforms the reagent ion $SF_6{^-}$ into $SF_4O^-$ and $F^-(HF)_n$, resulting in a substantial loss in CI sensitivity. Therefore, under humid conditions, peaks corresponding to OH are drastically diminished, while those corresponding to OH-water complex ions ($[OH(H_2O)_n]^-$) are enhanced. $[OH(H_2O)_3]^-$ was observed as the major OH species. The obsercation of $[OH(H_2O)_n]^-$ by isolating humid conditions to the CI region and preliminary ab initio calculations suggested that $[OH(H_2O)_n]^-$ ions were produced from reactions between OH ions ($OH^-$) and water molecules. An additional helium buffer flow introduced into the CI region reduced loss of the reagent ion and resulted in a partial recovery of OH peak intensities under humid conditions.

• Korean Journal of Materials Research
• /
• v.23 no.12
• /
• pp.702-707
• /
• 2013

High-quality ${\beta}$-silicon carbide (SiC) coatings are expected to prevent the oxidation degradation of carbon fibers in carbon fiber/silicon carbide (C/SiC) composites at high temperature. Uniform and dense ${\beta}$-SiC coatings were deposited on carbon fibers by low-pressure chemical vapor deposition (LP-CVD) using silane ($SiH_4$) and acetylene ($C_2H_2$) as source gases which were carried by hydrogen gas. SiC coating layers with nanometer scale microstructures were obtained by optimization of the processing parameters considering deposition mechanisms. The thickness and morphology of ${\beta}$-SiC coatings can be controlled by adjustment of the amount of source gas flow, the mean velocity of the gas flow, and deposition time. XRD and FE-SEM analyses showed that dense and crack-free ${\beta}$-SiC coating layers are crystallized in ${\beta}$-SiC structure with a thickness of around 2 micrometers depending on the processing parameters. The fine and dense microstructures with micrometer level thickness of the SiC coating layers are anticipated to effectively protect carbon fibers against the oxidation at high-temperatures.

• Journal of the Korean institute of surface engineering
• /
• v.41 no.2
• /
• pp.43-47
• /
• 2008

Cubic boron nitride(c-BN) films were deposited on tungsten carbide insert tool by microwave plasma enhanced chemical vapor deposition(MPECVD) from a gas mixture of triethyl borate$(B(C_2H_5O)_3)$, ammonia $(NH_3)$, hydrogen$(H_2)$ and argon(Ar). The qualities of deposited thin film were investigated by x-ray diffrac-tion(XRD), field emission scanning electron microscopy(FE-SEM) and micro Raman spectroscope. The surface morphologies of the synthesised BN as well as crystallinity appear to be highly dependent on the flow rate of $B(C_2H_5O)_3$ and $(NH_3)$ gases. The deposited film had more crystallized phases with 5 scem of $B(C_2H_5O)_3$ and $(NH_3)$ gases than with 2 sccm, and the phase was identified as c-BN by micro Raman spectroscope and XRD. The adhesion strength were also increased with increasing flow rates of $B(C_2H_5O)_3$ and $(NH_3)$ gases.