• Title/Summary/Keyword: Vapor behaviors

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Microstructure and Magnetic properties of $Ti_{1-x}Co_xO_2$ Magnetic semiconductor thin films by Metal Organic Chemical Vapor Deposition (유기금속화학기상증착법으로 제조된 자성반도체 $Ti_{1-x}Co_xO_2$ 박막의 미세구조 및 자기적 특성)

  • Seong, Nak-Jin;Yoon, Soon-Gil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.07a
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    • pp.155-159
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    • 2003
  • Polycrystalline $Ti_{1-x}Co_xO_2$ thin films on $SiO_2$ (200 nm)/Si (100) substrates were prepared using liquid-delivery metalorganic chemical vapor deposition. Microstructures and ferromagnetic properties were investigated as a function of doped Co concentration. Ferromagnetic behaviors of polycrystalline films were observed at room temperature, and the magnetic and structural properties strongly depended on the Co distribution, which varied widely with doped Co concentration. The annealed $Ti_{1-x}Co_xO_2$ thin films with $x{\leq}0.05$ showed a homogeneous structure without any clusters, and pure ferromagnetic properties of thin films are only attributed to the $Ti_{1-x}Co_xO_2$ (TCO) phases. On the other hand, in case of thin films above x=0.05, Co clusters formed in a homogeneous $Ti_{1-x}Co_xO_2$ Phase, and the overall ferromagnetic (FM) properties depended on both $FM_{TCO}$ and $FM_{Co}$. Co clusters with about 10nm-150nm size decreased the value of Mr (the remanent magnetization) and increased the saturation magnetic field.

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Effect of Wavy Flow of Vertical Falling Film on the Absorption Performance (흡수성능에 미치는 수직 액막 파동의 영향에 관한 연구)

  • 김정국;조금남
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.16 no.2
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    • pp.194-201
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    • 2004
  • In the present study, the improvement of absorption characteristics on combined heat and mass transfer process in a falling film of a vertical absorber by change of geometric parameters were studied experimentally and analytically. The energy and diffusion equations are solved simultaneously to give the temperature and concentration variations at the liquid solution-refrigerant vapor interface and at the wall. Absorption behaviors of heat and mass transfer were analyzed through falling film of the LiBr aqueous solution contacted by refrigerant vapor in the absorber. Effects of film Reynolds number, geometric parameters by insert device (spring) and flow pattern on heat and mass transfer performances have been also investigated. Especially, effects of the flow pattern by geometric parameters have been considered to observe the total heat and mass transfer rates through falling film along the absorber. As a numerical and experimental result, maximum absorption rate was shown at the wave-flow by insert device (spring). The error ranges between experiment and analysis were from 5.8 to 12% at Re$_{f}$ > 100.0.

Effect of $Al_2O_3/Fe$ Ratio on Characteristics of Carbon Nanotubes Prepared by Catalytic Chemical Vapor Deposition

  • Jung, Sung-Sil;Lee, Dae-Yeol;Chung, Won-Sub;Park, Ik-Min
    • Carbon letters
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    • v.5 no.2
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    • pp.81-87
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    • 2004
  • The effect of compositions of $Al_2O_3$ in the mixed $Fe/Al_2O_3$ catalysts on the synthetic behaviors of carbon nanotubes (CNTs) by catalytic chemical vapor deposition (CCVD) process was investigated in wide range of the mixture ratios of support materials. CNTs were synthesized with $Fe/Al_2O_3$ catalysis under the condition of 40 min in synthetic time, and 923 K of synthetic temperature using $C_2H_4$ and $H_2$ as synthetic and carrier gas, respectively. The carbon yield with the content of $Al_2O_3$ showed in a parabolic curve and the maximum carbon yield was 40 wt.% of $Al_2O_3$. As the mixture ratio of $Al_2O_3$ increased, decreasing tendency was observed in the diameter of CNTs. Specific surface areas of CNTs were increased with the increase of the mixture ratio of $Al_2O_3$.

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An Experimental Study on the Characters of Bullet Proof for Al and Ti Alloy (Al합금과 Ti합금의 방탄특성에 관한 실험적 연구)

  • Sohn Se Won
    • Transactions of the Korean Society of Automotive Engineers
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    • v.13 no.4
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    • pp.113-120
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    • 2005
  • In order to investigate the characteristics of penatration and the effect of surface treatment in A15052-H34, Al5082-Hl31 and titanium alloy laminates which were treated by anodizing and PVD(Physical Vapor Desposition) method, ballistic tests were conducted. Thickness of surface membrane in A15052-H34, Al5082-Hl31, were $25{\mu}m$ and that of titanium $0.9{\mu}m$ respectively. Surface hardness test was conducted using micro Vicker's hardness tester. Resistance to penetration is determined by the protection ballistic limit(V50), a statistical velocity with $50\%$ probability for complete penetration. Fracture behaviors and ballistic tolerance, described by penetration modes, are observed from the results of V50 test and Projectile Through Plate(PTP) test at velocities greater than protection ballistic limit, respectively. Present experimental results derived from this research help to optimize laminate impact behavior by varing the laminate thickness and surface treated materials.

Fracture Behaviors of SiCf/SiC Composites Prepared by Hybrid Processes of CVI and PIP (화학침착법과 고분자함침 열분해법의 복합공정으로 제조한 SiCf/SiC 복합체의 제조 공정에 따른 파괴거동)

  • Park, Ji Yeon;Han, Jangwon;Kim, Daejong;Kim, Weon-Ju;Lee, Sea Hoon
    • Journal of the Korean Ceramic Society
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    • v.51 no.5
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    • pp.430-434
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    • 2014
  • $SiC_f$/SiC composites were prepared using the hybrid process of chemical vapor infiltration (CVI) and polymer impregnation and pyrolysis (PIP). Before the application of PIP, partially matrix-filled preform composites with different densities were fabricated by control of chemical vapor infiltration time and temperature. The changes of the final density of the $SiC_f$/SiC composites had a tendency similar to that of preform composites partially filled by CVI. Composites with lower density after the CVI process had a larger increment of density during the PIP process. Three types of microstructures were observed on the fractured surface of the composite: 1) well pulled-out fibers and lower density, 2) slightly pulled-out fibers and higher density, and 3) only bulk SiC. The different fractions and distributions of the microstructures could have an effect on the mechanical properties of the composites. In this study, $SiC_f$/SiC composites prepared using a hybrid process of CVI and PIP had density values in the range of $1.05{\sim}1.44g/cm^3$, tensile strength values in the range of 76.4 ~ 130.7 MPa, and fracture toughness values in the range of $11.2{\sim}13.5MPa{\cdot}m^{1/2}$.

High Temperature Tribology Behavior of 4YSZ Coatings Fabricated by Air Plasma Spray (APS) and Electron Beam Physical Vapor Deposition (EB-PVD) (플라즈마 용사 및 전자빔 물리기상 증착법으로 제조된 4YSZ 코팅의 고온마찰마모 거동)

  • Yang, Young-Hwan;Park, Chan-Young;Lee, Won-Jun;Kim, Sun-Joo;Lee, Sung-Min;Kim, Seongwon;Kim, Hyung-Tae;Oh, Yoon-Suk
    • Journal of the Korean institute of surface engineering
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    • v.46 no.6
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    • pp.258-263
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    • 2013
  • 4 mol% Yttria-stabilized zirconia (4YSZ) coatings are fabricated by Air Plasma Spray (APS) and Electron Beam Physical Vapor Deposition (EB-PVD) with top coating of thermal barrier coating (TBC). NiCrAlY based bond coat is prepared as 150 ${\mu}m$ thickness by conventional APS (Air Plasma Spray) method on the NiCrCoAl alloy substrate before deposition of top coating. Each 4YSZ top coating shows different tribological behaviors based on the inherent layer structures. 4YSZ by APS which has splat-stacked structure shows lower friction coefficient but higher wear rate than 4YSZ by EB-PVD which has columnar structure. For 4YSZ by APS, such results are expected due to the sliding wear accompanied with local delamination of splats.

Epitaxial Growth of Graphene by Surface Segregation and Chemical Vapor Deposition on Ru(0001) Studied with Scanning Tunneling Microscopy (주사형 탐침 현미경을 이용한 Ru(0001) 위 그래핀의 에피탁시얼 성장 조건에 대한 연구)

  • Jang, Won-Jun;Kahng, Se-Jong
    • Journal of the Korean Vacuum Society
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    • v.22 no.6
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    • pp.285-290
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    • 2013
  • Epitaxial graphene on metal substrates provides excellent platforms to study its atomic and electronic structures, and can be grown either by surface segregation of carbon or by chemical vapor deposition. The growth behaviors of the two methods, however, have not been directly compared each other. Here, we studied domain structures of graphene grown by three different methods, surface segregation, post-annealing with adsorbed ethylene, and high-temperature dose of ethylene, using scanning tunneling microscopy. The first two methods resulted in graphene regions with areas of $100nm^2$, whereas the third method showed large area graphene (> $10^4nm^2$) with regular hexagonal Moire patterns, implying that high-temperature dose of ethylene is preferable for further studies on graphene such as additional growth of organic molecules.

Water Vapor Sorption Behavior of Some Agricultural Products Produced in Korea (일부(一部) 한국산(韓國産) 농산물(農産物)의 등온흡습곡선(等溫吸濕曲線)에 관(關)한 연구(硏究))

  • Rhee, Chul;Maeng, Young-Sun
    • Korean Journal of Food Science and Technology
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    • v.15 no.4
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    • pp.315-320
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    • 1983
  • The water vapor sorption isotherms for a great variety of agricultural products were determined by using the standard salt solution technique at the temperatures of $25^{\circ},\;35^{\circ}\;and\;45^{\circ}C$. The B.E.T. monomolecular layer moisture contents were evaluated from experimental data on the sorption isotherms, and an analysis was made of the thermodynamic functions for water vapor sorption behaviors with respect to the storage stability of dehydrated foods. It may be concluded that the variation of entropy with moisture content of some agricultural products and seaweeds investigated would be a guide for the elucidation of the storage stability of dehydrated foods.

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A Fundamental Study on the Investigation of Bubbling Phenomenon in the Injector for the Development the LPDi Engine (액상 LPG 직접 분사식 기관 개발을 위한 인젝터 내 기포발생현상의 원인 규명에 관한 기초연구)

  • Noh, Ki-Chol;Lee, Jong-Tai
    • Transactions of the Korean Society of Automotive Engineers
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    • v.14 no.6
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    • pp.1-8
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    • 2006
  • One of the most important subjects to develop a LPDi engine is to suppress the bubble generated inside the liquid LPG direct injector. For the purpose of this, the analogy visualization injector to visualize the generation and behaviors of bubble is manufactured, and the bubbling phenomenon and behaviors of bubble are visualized and investigated according to the change of the temperature around an injector wall, fuel pressure and a needle configuration. As results, it was found that the bubble inside the injector is generated around an injector hole and after rising by buoyancy it disappears around the top of a nozzle. The number of bubbles generated is little changed regardless of the lapse of time but it remarkably increases as the temperature around the injector increases. Also, it was known that as the sac volume in LPDi injector decreases the generation of bubble is more active and the rising velocity of bubble generated is increased.

A Study on the high velocity impact behavior of titanium alloy by PVD method (PVD처리한 티타늄 합금의 고속충격 거동에 관한 연구)

  • Sohn, Se-Won;Lee, Doo-Sung;Hong, Sung-Hee
    • Proceedings of the KSME Conference
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    • 2001.06a
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    • pp.567-572
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    • 2001
  • In order to investigate the fracture behaviors(penetration modes) and resistance to penetration during ballistic impact of Titanium alloy laminates and nitrified Titanium alloy laminates which were treated by PVD(Physical Vapor Deposition) method, ballistic tests were conducted. Evaporation, sputtering, and ion plating are three kinds of PVD method. In this research, Ion plating was used to achieve higher surface hardness and surface hardness test were conducted using a Micro vicker's hardness tester. Resistance to penetration is determined by the protection ballistic limit($V_{50}$), a statistical velocity with 50% probability for complete penetration. Fracture behaviors and ballistic tolerance, described by penetration modes, are respectfully observed at and above ballistic limit velocities, as a result of $V_{50}$ test and Projectile Through Plates (PTP) test methods. PTP tests were conducted with $0^{\circ}$ obliquity at room temperature using 5.56mm ball projectile. $V_{50}$ test with $0^{\circ}$ obliquity at room temperature were conducted with projectiles that were able to achieve near or complete penetration during PTP tests. Surface hardness, resistance to penetration, and penetration modes of Titanium alloy laminates are compared to those of nitrified Titanium alloy laminates.

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