• Title/Summary/Keyword: Vapor absorption

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Noncondensable gas's influence in waster vapor absorption accompanying interfacial disturbance into aqueous solution of LiBr

  • Dong-Ho RIE;Keun-Oh Lee
    • Journal of the Korean Society of Safety
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    • v.7 no.2
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    • pp.63-70
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    • 1992
  • The aim of this research is to obtain a basic quantitative understanding of the effect of a noncondensable gas on the absorption of water vapor by a $H_2O$ / LiBr combination with n-octanol as the surfactant. Nonflowing aqueous solutions of LiBr (40,45,50 mass%) were exposed to saturated water vapor following the addition of an n-octanol sufactant (0.01 and 0.6 mass%). A small amount of a noncondensable gas (air) was allowed into the absorber (0.03 volume%) and its effect was analyzed by measuring the amount of water vapor absorbed. This study will aid to predict the performance of heat pump and safety operating condition when the noncondensable gas is not allowed in the absorber The results indicate that, in the presence of small amounts of a noncondensable gas, vapor absorption enhancement ratios are less than half o( those obtained under the same experimental conditions when a noncondensable gas is not present (1). The presence of a noncondensable gas causes the partial vapor pressure of air to increase at the vapor / liquid interface, which results in an instability of vapor absorption rate nd. hence, in an inhibition of interfacial disturbance.

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Comparison of Notation Items for Chemical Occupational Exposure Limits (화학물질에 대한 직업적 노출기준의 표기 항목 비교)

  • Phee, Young Gyu;Kim, Seung Won;Ha, Kwonchul
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.30 no.2
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    • pp.226-235
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    • 2020
  • Objectives: This study was to investigate the signs and notations of skin absorption, carcinogenicity, germ cell mutagenicity, and reproductive toxicity in the occupational exposure limits of Korea and of other advanced countries. Methods: Information on occupational exposure limits in Korea, the USA, the UK, Germany, and Japan was investigated through the Internet, and items marked as carcinogenicity and skin absorption were compared by country. Results: Legal occupational exposure limits have been greatly simplified. However, in the case of HSE WEL, skin absorption, carcinogenicity classification, sensitization, and in the case of DFG MAK, skin absorption, carcinogenicity, pregnancy risk group, germ cell mutagenicity, airway and skin sensitization, photo contact sensitization, and vapor pressure were provided. Conclusions: It is desirable to indicate the carcinogenicity and skin absorption within permissible limits, and to include information on critical effects in chemical substance exposure limits to uphold the right to know of industrial hygienists and workers in Korea. It is also necessary to clarify the precautions, limitations and protections for skin absorption.

Performance Characteristic of the Compression-Absorption Hybrid Heat Pump Cycles (흡수압축 하이브리드 히트펌프 사이클의 성능특성)

  • Yoon J. I.;Kwon O. K.;Yang Y. M.
    • Journal of the Korean Institute of Gas
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    • v.3 no.1
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    • pp.14-20
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    • 1999
  • This study describes the results of Coefficient of Performance(COP) analysis by cycle simulation for two types of absorption-compression hybrid cycle using the Water/Lithium Bromide solution pair. These types are basic hybrid systems introducing a mechanical compression process into the refrigerant vapor phase of the single effect absorption cycle. In absorption-compression hybrid cycles, coefficient of performance is improved compared with absorption cycle. Hybrid cycle Type 2 is considered as a key technology to support energy utilization system, given its capability of utilizing waste heat to drive system with a high level of efficiency.

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A STUDY OF THE MERCURY VAPOR MEASUREMENT DURING AMALGAM REMOVAL (충전(充塡)된 아말감 제거시(除去時) 발생(發生)되는 수은증기량(水銀蒸氣量) 측정(測定)에 관(關)한 연구(硏究))

  • Na, Keung-Kyun;Min, Byung-Soon;Choi, Ho-Young;Park, Sang-Jin
    • Restorative Dentistry and Endodontics
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    • v.10 no.1
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    • pp.85-92
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    • 1984
  • The aim of this study was to examine the influence of the speed of grinding and coolants on mercury vaporization during amalgam removal. Forty amalgam filled stone dies were stored at $37^{\circ}C$ and 100% relative humidity for 7 days prior to the beginning of the mercury vapor experiment and were divided into 4 different groups; In Group I; Used by high speed without coolant & evacuator during amalgam removal. In Group II; Used by high speed with coolant & evacuator during amalgam removal. In Group III; Used by low speed without coolant & evacuator during amalgam removal. In Group IV; Used by low speed with coolant & evacuator during amalgam removal. The amalgam specimens were removed in a 30-second time period and mercury vapor was collected with membrane filter at 27mm from the site of removal and 45 degree above there. Samples in Group II, IV were removed with coolant spray at a flow rate of 30 ml/min with high-velocity evacuator. Mercury vapor collected membrane filter was analysed by Atomic Absorption Spectrophotometer using cold vapor method. The results were as follows; 1. The mercury vapor levels were obtained all of the Groups. 2. The mercury vapor levels of the Group II, IV (with coolant & evacuator) were less than that of the Group I, III (without coolant & evacuator). 3. The highest mercury vapor level recorded during amalgam removal procedure was Group I (used by high speed without coolant & evacuator) and its record was $0.78{\pm}0.09\;mg/m^3$, which exceed the T.L.V. by 15 times. 4. The mercury vapor level of the Group IV (used by low speed with coolant & evacuator) was more than that of the Group II (used by high speed with coolant & evacuator), but its difference was not significant, statistically. (p > 0.05)

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Preparation of Honeycomb Carbon Dioxide Adsorbent Impregnated $K_2CO_3$ and Its Characterization ($K_2CO_3$를 담지시킨 고체 허니컴 이산화탄소 흡수제의 제조 및 이의 특성 평가)

  • Lee, Dong-Chul;Kim, Jin-Bae;You, Yoon-Jong
    • Applied Chemistry for Engineering
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    • v.23 no.6
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    • pp.624-629
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    • 2012
  • To capture and recover carbon dioxide ($CO_2$), we impregnated honeycomb made of ceramic paper with $K_2CO_3$ and its absorption characteristics of $CO_2$ were investigated. The absorption amount of $CO_2$ on the honeycomb absorbent impregnated with $K_2CO_3$ was 13.8 wt% at a constant temperature ($70^{\circ}C$) and relative humidity (66%) condition. Because the absorption amount of $CO_2$ achieved almost the same loading ratio of $K_2CO_3$ (17.6 wt%), the absorption reaction of $CO_2$ by $K_2CO_3$ on the honeycomb absorbent seems to be going smoothly. In addition, $CO_2$ absorption breakthrough characteristics of the honeycomb absorbent were analyzed at the temperature range of $50{\sim}80^{\circ}C$, and the water vapor was fed to an absorption column before the feeding of $CO_2$ or simultaneously with $CO_2$. As a result, the absorption capacity of $CO_2$ was more enhanced using the water vapor supplying before $CO_2$ than that of simultaneous supplying. It was confirmed by temperature programmed desorption analysis that the $KHCO_3$ produced by the absorption reaction of $K_2CO_3$ and $CO_2$ is regenerated by the desorption of $CO_2$ at a temperature of about $128^{\circ}C$.

Study on Performance of Water Vapor-Permeation Through Hydrophilic Polymer Membranes (친수성 고분자 막을 이용한 수증기 투과 성능에 관한 연구)

  • Rhim Ji-Won;Yun Tae-Il;Seo Moo-Young;Cho Hyun-Il;Ha Seong-Yong
    • Membrane Journal
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    • v.16 no.2
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    • pp.115-122
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    • 2006
  • In this study the membrane preparation and water vapor permeation of the hydrophilic polymer materials, polyaminosiloxane and polyhydroxylsiloxane, used as the coating materials for the preparation of asymmetric flat and hollow fiber membranes were investigated. And the water vapor permeation towards air permeation and their permselectivity were intensively studied for the resulting Resin A/Resin C (coupling agent) and Resin B/Resin C membranes. The water vapor permeability for 3 wt% Resin C introduced into Resin A (Resin A/Resin C) membrane was higher than for 1 and 5 wt% membranes and also water vapor permeability increased with increasing operating temperatures. In addition, at this content of 3 wt% Resin C, the absorption capability became maximum through dynamic equilibrium absorption experiment. Water vapor permeability, 43578 Barrer (1 Barrer = $10^{-10}cm^3(STP){\cdot}cm/cm^2{\cdot}s{\cdot}cmHg$) and 53000 Barrer, and the selectivity of $P(H_2O)P(Air)$, 101.3 and 102.6 were shown at 25 and $35^{\circ}C$, respectively.

Relative Absorption Edges of GaN/InGaN/GaN Single Quantum Wells and InGaN/GaN Heterostructures by Metalorganic Chemical Vapor Deposition (유기금속화학기상증착법으로 성장된 GaN/InGaN/GaN 단양자 우물층과 InGaN/GaN 이종접합 구조의 광학적 특징)

  • Kim, Je-Won;Son, Chang-Sik;Jang, Yeong-Geun;Choe, In-Hun;Park, Yeong-Gyun;Kim, Yong-Tae;Ambacher, O.;Ctutzmann, M.
    • Korean Journal of Materials Research
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    • v.9 no.1
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    • pp.42-45
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    • 1999
  • The room temperature optical transmission spectra of GaN /InGaN/GaN single quantum wells (SQW) and InGaN/GaN heterostructures grwon by low pressure metalorganic chemical vapor deposition have been measured. The dependence of the absorption edges of the GaN/InGaN/GaN SQW on the well width has been determined from the transmission spectra. The result shows that the absorption edge of GaN/InGaN/GaN SQW shifts towards lower energy as increasing the well width. The dependence of the absorption edges of the InGaN/GaN heterostructures on InN mole fraction has also been determined from the transmission spectra. The result is compared with calculated values obtained from Vegards's laws. Our result shows a good agreement with the calculated values.

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Surface morphology modification of vertically-aligned carbon nanotubes by water vapor exposure

  • Adil, Hawsawi;Jeong, Goo-Hwan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.238.2-238.2
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    • 2015
  • Surface modification of vertically-aligned carbon nanotube (VACNT) is essential in order to meet specific demands for particular applications such as field emission displays, heat dissipation device and potential sun energy conversion due to their superior electrical and thermal conductivity and strong light absorption. In this study, we observe the effect of exposure to water vapor on a different lengths of the surfaces of VACNT. The study was conducted on three different lengths of the VACNT: short length around $200{\mu}m$, medium-length around $500{\mu}m$, and high length around 1 mm. Water exposure time ranges between 2-10 min and temperature of the water ranges from 60 to 120 oC. The result of water vapor exposure mainly show that increasing the exposure time and water temperature give rise to increase of the speed of change on the surface of the VACNT. Especially, the shorter VACNT change their surface morphology most rapidly.

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Preparation and dielectric properties of polyimide thin films by vapor deposition polymerization method (진공증착중합에 의한 Polyimide 박막의 제조와 유전특성)

  • 이덕출;김형권
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.45 no.3
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    • pp.380-385
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    • 1996
  • Thin films of polyamic acid(PAA) were fabricated by vapor deposition polymerization(VDP) from pyromellitic dianhydride(PMDA) and 4,4'-diamino diphenyl ether(DDE). Thin films of polyimide(PI) were obtained by curing PAA, and their dielectric properties have been measured. The uniform thin films of PI formed by curing PAA at 300 .deg. C for 1 hr. which was confirmed by Fourier transform Infrared spectroscopy(FT-IR) absorption at 720, 1380, 1780c $m_{-1}$. Relative permittivity and tan .delta. were 3.9 and 0.008 at 10kHz, respectively. (author). 8 refs., 11 figs., 1 tab.1 tab.

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Characteristics of Absorption and Heat Transfer for Film Falling along a Vertical inner Tube (1st Report, Characteristics of Absorption) (수직관내(垂直管內)를 흘러내리는 액막식(液膜式) 흡수기(吸收器)의 흡수(吸收) 및 열전달특성(熱傳達特性) (제(第) 1 보(報), 흡수특성(吸收特性)))

  • Ohm, K.C.;Kashiwagi, T.;Seo, J.Y.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.5 no.1
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    • pp.1-9
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    • 1993
  • Mass transfer coefficients were measured for water vapor absorption into a LiBr-Water solution of 60wt% flowing down an absorber of vertical tube type. The absorber is copper tube of 25mm inner diameter and 1000mm length. The film Reynolds number were varied in the range of 35~130. The solution is fed from the top of the pipe, and the conditions of solution are supercooled liquid and superheated liquid. As results, the flowrates of LiBr solution which takes peak value of average absorption mass flux exist. Mass transfer coefficients decrease with increasing the flowrate of LiBr solution, and the decrease rate in the case of supercooled liquid is large as compared with that in the case of superheated liquid. But the absorption rate of supercooled liquid is decidedly superior to that of superheated liquid.

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