• Applied Chemistry for Engineering
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• v.28 no.1
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• pp.1-7
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• 2017

Polydimethylsiloxane (PDMS) can be deposited on various substrates using chemical vapor deposition process, which results in the formation of PDMS thin films with thickness below 5 nm. PDMS layers can be evenly deposited on surfaces of nanoparticles composed of various chemical compositions such as $SiO_2$, $TiO_2$, ZnO, C, Ni, and NiO, and the PDMS-coated surface becomes completely hydrophobic. These hydrophobic layers are highly resistant towards degradation under acidic and basic environments and UV-exposures. Nanoparticles coated with PDMS can be used in various environmental applications: hydrophobic silica nanoparticles can selectively interact with oil from oil/water mixture, suppressing fast diffusion of spill-oil on water and allowing more facile physical separation of spill-oil from the water. Upon heat-treatments of PDMS-coated $TiO_2$ under vacuum conditions, $TiO_2$ surface becomes completely hydrophilic, accompanying formation oxygen vacancies responsible for visible-light absorption. The post-annealed $PDMS-TiO_2$ shows enhanced photocatalytic activity with respect to the bare $TiO_2$ for decomposition of organic dyes in water under visible light illumination. We show that the simple PDMS-coating process presented here can be useful in a variety of field of environmental science and technology.

• Analytical Science and Technology
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• v.33 no.1
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• pp.11-22
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• 2020

When extracting semi-volatile components of herbal medicines using hot water vapor, some substances may react with water vapor or oxygen, and some volatile substances may be lost, when using an organic solvent extraction method has the disadvantage that it may contain a non-volatile material and residual organic solvent. In addition, it is inefficient to separate semi-volatile substances from herbal medicines into each single component and conduct biological activity research for each component to determine the effective ingredient, and some components may be lost in the separation process. In this study, semi-volatile substances evaporated under two pressure-reduced conditions in Chinese herbal medicines such as Cnidii Rhizoma, Aucklandiae Radix and Amomum Fructus were separated by cooling with liquid nitrogen. Those were analyzed by gas chromatography-mass spectrometry (GC-MS) to identify the components, and this method may be used to study biological activities at the cellular level. The substances separated under reduced pressure, essential oil obtained by simultaneous distillation extraction (SDE) method and substances by using solid phase micro-extraction (SPME) from Cnidii Rhizoma, Aucklandiae Radix and Amomum Fructus were analyzed by GC-MS. In the case of Cnidii Rhizoma and Aucklandiae Radix, there were some differences among the essential oil components obtained by SDE and those identified by low temperature capture (CT) and SPME method, these were believed to be produced by some volatiles reacting with water or oxygen at the boiling point temperature of water.

• Journal of Korean Society on Water Environment
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• v.27 no.2
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• pp.167-177
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• 2011

Billions of barrels of briny produced water are generated in the United States every year during oil and gas production. The first step toward recovering or reusing this water is to remove the hazardous organics dissolved in the briny produced water. Biological degradation of hazardous volatile compound could be possible regardless of salinity if they were extracted from briny water. In the current work, the effectiveness of a vapor phase biofilter to degrade the gas-phase contaminants (benzene, toluene, ethylbenzene and xylenes, BTEX) extracted from briny produced water was evaluated. The performance of biofilter system responded well to short periods when the BTEX feed to the biofilter was discontinued. To challenge the system further, the biofilter was subjected to periodic spikes in inlet BTEX concentration as would be expected when it is coupled to a Surfactant-Modified Zeolite (SMZ) bed. Results of these experiments indicate that although the BTEX removal efficiency declined under these conditions, it stabilized at 75% overall removal even when the biofilter was provided with BTEX-contaminated air only 8 hours out of every 24 hours. Benzene removal was found to be the most sensitive to time varying loading conditions. A passive, granular activated carbon bed was effective at attenuating and normalizing the peak BTEX loadings during SMZ regeneration over a range of VOC loads. Field testing of a SMZ bed coupled with an activated carbon buffering/biofilter column verified that this system could be used to remove and ultimately biodegrade the dissolved BTEX constituents in briny produced water.

• Journal of the Korean Solar Energy Society
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• v.32 no.3
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• pp.170-177
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• 2012

To apply the nanofluids into the general vapor compression cycle, basically have to know the thermal properties including thermal conductivity and dynamic viscosity. And needs to show the dispersion characteristics for various nanofluids and concentrations. So, firstly this study showed experimentally the thermal properties for various concentration (0.1%~0.7%, as mass balance) and temperature($20^{\circ}C{\sim}40^{\circ}C$) on $Al_2O_3$, $TiO_2$, and CuO nanofluids using base fluid as POE oil that has used in the scroll compressor for various refrigeration system. From the results, the dynamic viscosity of nanofluids was considerably changed from the base POE oil. And, the dispersion characteristics of various nanofluids using the simple methods like as analyzing the RGB value or measuring the sinking height of nanofluids were showed experimentally. Through the results, the dispersion characteristics of $Al_2O_3$ nanofluid was better than those of $TiO_2$, and CuO nanofluids not considering the real refrigeration cycle rurming conditions.

• Journal of Advanced Marine Engineering and Technology
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• v.29 no.1
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• pp.49-59
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• 2005

The evaporation heat transfer experiments are conducted with the shell and plate heat exchanger (S&PHE) without oil in the refrigerant loop using R-410A. An experimental refrigerant loop has been established to measure the evaporation heat transfer coefficient h. of R-410A in a vertical S&PHE. Two vertical counter flow channels were formed in the S&PHE by three plates haying a corrugated trapezoid shape of a $45^{\circ}C$ chevron angle. UP flow of the boiling R-410A in one channel receives heat from the hot down flow of water in the other channel The effects of the refrigerant mass flux. average heat flux. refrigerant saturation temperature and vapor qualify are explored in detail. Similar to the case of a plate heat exchanger. even at a very low Reynolds number, the flow in the S&PHE remains turbulent. The Present data shows that the evaporation heat transfer coefficients of R-410A increased with the vapor qualify. The results indicate a rise in the refrigerant mass flux caused an increase in the h.. Raising the imposed wall heat flux is found to slightly improve h., while h, is found to be lower at a higher refrigerant saturation temperature. Based on the present data. empirical correlation of the evaporation heat transfer coefficient is proposed.

• Fire Science and Engineering
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• v.34 no.2
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• pp.86-93
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• 2020

This study aims to maintain the safety of an outdoor storage tank through the fundamental case analysis of explosion and fire accidents in the storage tank. We consider an accident caused by the explosion of fire inside the tank, as a result of the gradual spreading of the residual fire generated by wind lamps flying off a workplace in the storage tank yard. To determine the cause of the accident, atmospheric diffusion conditions were derived through CCTV image analysis, and the wind direction was analyzed using computational fluid dynamics. Additionally, the amount of oil vapor inside the tank when the floating roof was at the lowest position, and the behavior of the vapor inside the tank when the floating roof was at the highest position were investigated. If the cause of the explosion in the storage tank is identified and the level of the storage tank is maintained below the internal floating roof, dangerous liquid fills the storage tank, and the vapor in the space may stagnate on the internal floating roof. We intend to improve the operation procedure such that the level of the storage tank is not under the Pontoon support, as well as provide measures to prevent flames from entering the storage tank by installing a flame arrester in the open vent of the tank.

• Journal of Korea Soil Environment Society
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• v.5 no.1
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• pp.13-23
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• 2000

The effects of operating condition of soil vapor extraction system and the characteristics of site on the remediation of oil contaminated soil were investigated. Thorough investigation showed that the site was contaminated with gasoline leaked from underground storage tank and the maximum concentration of BTEX and TPH were 1,081 ppm and 5,548 ppm respectively. The leaked gasoline were diffused to 6m deep and the area and volume of the polluted soil were assumed to 170$m^2$ and 1,000$\textrm{m}^3$respectively. The site were consisted of three different vertitical layers, the top reclaimed sandy soil between the earth surface and 3~4m deep, middle silty sand between 3~4m and 6m deep, and the bottom bedrock below the 6m deep. The air pemeability of soil was measured to 1.058-1.077$\times$10$^{-6}$ $\textrm{mm}^2$ by vacuum pump tests. The groundwater which level was 3~4m deep was observed in some areas of this site. The soil vapor extraction system which had 7.5 HP vacuum pump and 8 extraction wells was constructed in this site and operated at 8 hrs/day for 100 days. The BTEX was removed with above 90% efficiency where no groundwater and silty sand were observed. On the contrary, the efficiency of BTEX and TPH were dramatically decreased where groundwater and silty sand were observed. The flow rate of soil air induced by soil vapor extraction system was reduced in deeper soil.

• Journal of the Korean Society for Precision Engineering
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• v.25 no.9
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• pp.32-37
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• 2008

Freestanding hydride vapor phase epitaxy grown GaN(Gallium Nitride) substrates subjected to various polishing methods were characterized for their surface and subsurface conditions, Although CMP(Chemical Mechanical Polishing) is one of the best approaches for reducing scratches and subsurface damages, the removal rate of Ga-polar surface in CMP is insignificant($0.1{\sim}0.3{\mu}m$/hr) as compared with that of N-polar surface, Therefore, conventional MP(Mechanical Polishing) is commonly used in the GaN substrate fabrication process, MP of (0001) surface of GaN has been demonstrated using diamond slurries with different abrasive sizes, Diamond abrasives of size ranging from 30nm to 100nm were dispersed in ethylene glycol solutions and mineral oil solutions, respectively. Significant change in the surface roughness ($R_a$ 0.15nm) and scratch-free surface were obtained by diamond slurry of 30nm in mean abrasive size dispersed in mineral oil solutions. However, MP process introduced subsurface damages confirmed by TEM (Transmission Electronic Microscope) and PL(Photo-Luminescence) analysis.

• Journal of Korean Society for Atmospheric Environment
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• v.34 no.5
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• pp.651-658
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• 2018

Particulate matter (PM) emitted from fossil fuel-combustion facilities can be classified as either filterable or condensable PM. The U.S. Environmental Protection Agency (EPA) defined condensable PM as material that is in the phase of vapor at the stack temperature of the sampling location which condenses, reacts upon cooling and dilution in the ambient air to form solid or liquid in a few second after the discharge from the stack. Condensable PM passed through the filter media and it is typically ignored. But condensable PM was defined as a component of primary PM. This study investigates the change of condensable PM according to the variation in the sulfur dioxide of combustion gas. Domestic oil boilers were used as the source of emission ($SO_2$) and the level of $SO_2$ concentration (0, 50, 80, and 120 ppm) was adjusted by diluting general light oil and marine gas oil (MGO) that contains sulfur less than 0.5%. Condensable PM was measured as 2.72, 6.10, 8.38, and $13.34mg/m^3$ when $SO_2$ concentration in combustion gas were 0, 50, 80, and 120 ppm respectively. The condensable PM tended to increase as the concentration of $SO_2$ increased. Some of the gaseous air pollutants emitted from the stack should be considered precursors of condensable PM. The gas phase pollutants which converted into condensable PM should reduced for condensable PM control.

• Journal of Advanced Marine Engineering and Technology
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• v.35 no.7
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• pp.946-956
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• 2011

The main objectives of this study are to analyze the leaked gas dispersion and quantify the potential overpressures due to vapor cloud explosions in order to identify the most significant contributors to risk by using Computational Fluid Dynamics (CFX & FLACS) for gas fuelled ships. A series of CFD simulations and analyses have been performed for the various gas release scenarios in a closed module, covering different release rates and ventilating methods. This study is specially focused on the LNG FGS (Fuel Gas Supply) system recently developed for the propulsion of VLCC crude oil carriers by shipyards. Most of work presented is discussed on the gas dispersion from leaks in the FGS room, and shows some blast prediction validation examples.