• Journal of the Korean Chemical Society
• /
• v.45 no.4
• /
• pp.293-297
• /
• 2001

The existing vapor pressure measurements reported in the literature for parahydrogen between the triple point and the critical point have been employed to establish the constants and exponent of the following equation in the form of reduced vapor pressure and reduced temperature: ln $lnP_r=2.64-{\frac{2.75}{T_r}}+1.48129lnT_r+0.11T^5_r$Only the normal boiling point ($T_b$= 20.268K), the critical pressure ($P_c$= 1292.81 kPa), and the critical temperature ($T_c$= 32.976K) are necessary to calculate the vapor pressure for an overall average deviation of 0.21% for 153 experimental vapor pressure data.

• Design & Manufacturing
• /
• v.14 no.2
• /
• pp.1-6
• /
• 2020

Recently, research and commercialization related to the field of cell-based therapeutic drug development has been actively conducted. In order to maintain cell viability and prevent contamination, refrigeration preservation devices, such as CRF (controlled rate freezer) or vapor type LN2 tanks have been developed. On the other hand, the storage container for liquid nitrogen tanks currently on sale minimizes the flow structure to prevent structural defects when stored in a liquid nitrogen tank having a high thermal conductivity than vapor nitrogen. If the cell-based treatment drug is stored in the gaseous LN2 tank as it is, the cell survival after thawing is greatly reduced. It was estimated that the existing storage container structure was a factor that prevented the rapid entry and circulation of gaseous nitrogen into the container. Therefore, this study intends to propose a new supercellular storage container model that can maintain the mechanical strength while maximizing the fluid flow structure. To this end, we estimated that the structural change of the storage container effects on the equivalent stress formed around the through-holes of them when exposed to a cryogenic environment using thermal-structural coupled field analysis. As a result of storage experiments in the gas phase tank of the cell-based therapeutic agent using the developed storage container, it was confirmed that the cell growth rate was improved from 66% to 77%, which satisfied the transportation standards of the FDA(Food and Drug Administration) cell-based therapeutic agent.

• Transactions of the Korean hydrogen and new energy society
• /
• v.34 no.5
• /
• pp.549-554
• /
• 2023

In this paper, three kinds of studies have been completed to obtain highly purified carbon dioxide having more than 7N purity as an electronic grade quality. PRO/II with PROVISION release January 2023 from AVEVA company was used, and Peng-Robinson equation of the state model with Twu's alpha function was selected for the modeling of the cryogenic distillation process. When using LN2 cold heat, we can obtain highest recovery of carbon dioxide as a bottom product for a cryogenic distillation column.

• Journal of the Korean Vacuum Society
• /
• v.8 no.2
• /
• pp.93-101
• /
• 1999

The purposed of this paper is to investigate the electrical and thermal stability of Polyvinylidene fluoride(PVDF) organic thin films prepared by the vapor deposition method. The differential scanning calorimetry curve of the PVDF organic thin films prepared by increasing substrate temperature showed that the melting curve increased from $128^{\circ}C$ to $142^{\circ}C$. This result implied that the PVDF organic thin film prepared by increasing substrate temperature increased intermolecular force in the crystalline region. The anomalous properties in dielectric constant and dielectric loss at low frequency and high temperature were described for PVDF organic thin film containing impurity carriers. It was confirmed that in view of electric conductive characteristics the ohm's law is satisfied in the range of lower electric field and ln J was proportional to the electric field ln E as like the conventional property of ionic conduction in the range of higher electric field. It was confirmed that major carrier of conductivity was ions. The electrical stability was improved according to an increase of the substrate temperature. On the basis of this experimental result, it could be observed that the optimum temperature of substrate for the electrical and thermal stability was at $105^{\circ}C$.

• Clinical and Experimental Reproductive Medicine
• /
• v.17 no.1
• /
• pp.81-85
• /
• 1990

We cryopreserved mouse morulae by a simple ultra-rapid method of freezing embryos directly in $LN_2$ after holding 2min in a $LN_2$ vapor, and thawed them in $37^{\circ}C$ water bath. The time requirements for permeation and dehydration by 2.0 M glycerol and 0.2 M sucrose before freezing were studied. When the embryos were equilibrated for 10 min, the optimun post-thaw survival was obtained. Embryos those developed normally to blastocyst after in vitro culture for over 24hrs were regarded as survival ones. Two experiments to assess post-thaw survival following predehydration in various mixtures of glycerol and sucrose were also accomplished. When sucrose was held constant (0.2 M) and glycerol concentration varied (1.5-3.5 M), post-thaw survival was best (78.0%) in 3.0 M glycerol. When glycerol was held constant (3.0M) and sucrose concentration varied (0.0-1.0M), optimun post-thaw survival (78.0%) was found in 0.2 M sucrose.

• Journal of Biosystems Engineering
• /
• v.36 no.4
• /
• pp.267-272
• /
• 2011

The latent heat of vaporization in rough rice, brown rice, white rice and rice hull was calculated by Clausius-Clapeyron equation, which does not require complex constraints as in Othmer method. Equilibrium relative humidity and ratio of the latent heat of vaporization with ln$P_{\upsilon}$ and ln$P_S$ were estimated with moisture contents ranging from 10% (d.b.) to 36% (d.b.) with 2% (d.b.) increment and temperatures ranging from $10^{\circ}C$ to $50^{\circ}C$ with $2.5^{\circ}C$ increment. An empirical equation for calculating the latent heat of vaporization in rice was developed as a function of moisture content and temperature. The equation agreed well with the calculated results. The ratio for latent heat of vaporization were the greatest for white rice while they were similar among rough rice, brown rice and rice hull.

• Bulletin of the Korean Chemical Society
• /
• v.23 no.3
• /
• pp.459-468
• /
• 2002

Literature data measured by the author have been processed to report on the effect of solute structure on gas liquid partition coefficients of eleven normal, branched and cyclic alkanes ranging in carbon number from five to nine in sixty nine low molecular weight liquids. The alkane solutes are n-pentane(p), n-hexane(hx), n-heptane(hp), n-octane(o), n-nonane(n), 2-methylpentane(mp), 2,5-dimethylpentane(dp), 2,5-dimethylhexane(dh), 2,3,4-trimethylpentane(tp), cyclohexane(ch), and ethylcyclohexane(ec). The solvent set encompasses most of those studied by Rohrschneider as well as three homologous series of solvents (n-alkanes, 1-alcohols and 1-nitriles) and several perfluorinated alkanes and highly fluorinated alcohols. An excellent linear relationship was observed between lnK and the carbon number of n-alkanes. The effective carbon numbers of branched and cyclic alkanes were determined in a similar fashion to the method of Kovats index. We found that the logarithm of solute vapor pressure multiplied by solute molar volume was a perfect descriptor for the linear relationship with the median effective carbon number.

• Transactions of the Korean hydrogen and new energy society
• /
• v.34 no.5
• /
• pp.526-534
• /
• 2023

To evaluate the risk of leakage when using liquid hydrogen, a leakage test was conducted using liquid nitrogen in an outdoor environment rather than a laboratory environment. To assume a real-scale continuous leak, liquid nitrogen was allowed to leak for 5 minutes through a pipe with a diameter of 25.4 mm at a design spill rate of 60 L/min. The measurement system consisted of devices for climate conditions, LN2 spread and vapor clouds. The main experimental results are the liquid pool radius and the concentration of vapor cloud, and the radius of the liquid pool was compared with the numerical analysis results.

• Transactions of the Korean hydrogen and new energy society
• /
• v.9 no.4
• /
• pp.169-176
• /
• 1998

An experimental study on effect of vapor-cooled heat stations in a 5.5 liter cryogenic vessel has been performed. The cryogenic vessel is made of stainless steel of thickness of 1mm and insulated by the combined insulation of vacuum, MLI(multi-layer insulation) and vapor-cooled radiation shield. Vapor-cooled heat stations are also constructed based on the 1-dimensional thermal analysis to reduce the heat inleak through a filling tube. Thermal analysis indicates that the vapor-cooled heat stations can substantially enhance the performance of vessel for cryogenic fluids with high $C_p/h_{fg}$ where $C_p$ the specific heat and $h_{fg}$ the heat of vaporization, such as $LH_2$ and LHe. The experimental results for $LN_2$ shows that the total heat inleak into inner vessel consists of 14% radiation and 86% conduction through the filling tube. Therefore, it is expected that the conduction heat in leak of the vessel for high $C_p/h_{fg}$ cryogenic fluids can be significantly reduced. powders. The amount of copper coating was 20wt%. In order to examine corrosion behavior of the electrodes, the corrosion current and the current density, in 6M KOH aqueous solution after removal of oxygen in the solution, were measured by potentiodynamic and cyclic voltamo methods. The results showed that Co in the alloy increased corrosion resistance of the electrode whereas Ni decreased the stability of the electrode during the charge-discharge cycles. The electrode used Si sealant as a binder showed a lower corrosion current density than the electrode used PTFE and the electrode used Cu-coated alloy powders showed the best corrosion resistance.

• Journal of the Korean Vacuum Society
• /
• v.13 no.3
• /
• pp.109-113
• /
• 2004

Zn diffusions in InP have been studied by electrochemical capacitance voltage. The InP layer was grown by metal organic chemical vapor deposition, and $Zn_3P_2$ thin film was deposited on the epitaxial substrates. The samples annealed in a rapid thermal annealing. It is demonstrated that surface hole concentration as high as $1\times10^{19}\textrm{cm}^{-3}$ can be achieved. When the Zn diffusion was carried at $550^{\circ}C$ and 5-20 min., the diffusion depth of hole concentration moves from 1.51$\mu\textrm{m}$ to 3.23 $\mu\textrm{m}$, and the diffusion coeffcient of Zn is $5.4\times10^{-11}\textrm{cm}^2$/sec. After activation, the concentration is two orders higher than that of untreated sample at 0.30 $\mu\textrm{m}$ depth. As the annealing time is increase, the hole concentration remains almost constant, except deep depth. It means that excess Zn interstitials exist in the doped region is rapidly diffusion into the undoped region and convert into substitutional When the thickness of $SiO_2$ thin film is above 1,000$\AA$, the hole concentration becomes stable distribution.