• Bulletin of the Korean Chemical Society
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• v.23 no.1
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• pp.75-80
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• 2002

Cycle life tests have been carried out to evaluate the influence of safety valve pressure on valve regulated lead/acid batteries under deep cycling applications. Batteries were cycled at 5 hour rates at 100% DOD, and safety valve pressure was set to 1.08 and 2.00 bar, respectively. The batteries lost 248.3 g and 235.3 g of water for each case after about 1,200 cycles, but the cyclic performances of the batteries were comparable. Most of the gas of the battery during discharging was hydrogen, and the oxygen concentration increased to 18% after 3 hours of charging. The micro structure of the positive active materials was completely changed and the corrosion layer of the positive grid was less than $50{\mu}m$, regardless of the pressure of the safety valve after cycle life tests. The cause of discharge capacity decrease was found to be water loss and the shedding of the positive active materials. The pressure of safety valve does not give little effect to the cyclic performances and the failure modes of the gelled electrolyte valve-regulated lead acid batteries.

• Bulletin of the Korean Chemical Society
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• v.29 no.5
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• pp.998-1002
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• 2008

The gel electrolytes were prepared with sulfuric acid and phosphoric acid, where hydrophilic fumed silica was used as a gelling agent. The influences of gel electrolyte on performance of the valve regulated lead acid (VRLA) batteries were investigated employing capacity tests, electrochemical impedance spectroscopy and scanning electron microscopy. The initial capacities of the sulfuric gel VRLA batteries were higher than that of phosphoric gel VRLA batteries. The sulfuric gel VRLA battery using 1.210 specific gravity of sulfuric acid with hydrophilic fumed silica exhibited the highest capacity of 0.828Ah. In the impedance measurements, the ohmic and charge transfer resistances for the phosphoric gel VRLA batteries were higher thanthat of sulfuric gel batteries. The morphology of electrodes of phosphoric gel VRLA batteries were more deteriorated in the SEM image.

• The Transactions of the Korean Institute of Electrical Engineers P
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• v.58 no.2
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• pp.214-220
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• 2009

Battery is one of the emergency power and its reliability is a very important to keep up the minimum of building capabilities in case of interruption of electric power. This paper, a comparison was made between three different types of instrument on 30 valve regulated lead acid(VRLA) TYPE 12[V]/100[AH] batteries, and then their indicated measured values(impedance/conductance) were compared with the measured capacity of the battery. As a result, Measured value of instrument is strongly related to battery's capacity in the same group battery and Impedance/Conductance guide line for diagnosis of lead-acid battery's state of health(SOH) is a different from each battery guoup.

• Journal of the Korean Applied Science and Technology
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• v.21 no.2
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• pp.164-173
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• 2004

The capacity and long life of gel electrolyte batteries is connected with gas recombination producting $PbO_2$ and Pb electrode. We prepared with sulfuric acid gel electrolyte to know gel characteristics per density to assemble valve regulated lead-acid (VRLA) batteries. We studied on actions of sulphuric acid gel electrolyte by measuring electrolyte dispersion using Brewster-angle microscope (BAM), charge-discharge cycle, and electrode structure using scanning election microscope (SEM). Sulphuric acid density 1.210 showed excellent gel dispersion in sol condition, electrode condition after fifty cycles in this study.

• Korean Chemical Engineering Research
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• v.56 no.6
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• pp.779-783
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• 2018

In this work, Mathematical modeling was carried-out to predict the charging/discharging characteristics of VRLA (Valve regulated lead acid) battery, which is mainly used as a 12 V lead acid battery for automobile. And It also carried-out how it's characteristics would be changed due to aging. A mathematical modeling technique, which has been mainly used to predict behavior of Lithium-ion batteries, is applied to commercial 70 Ah VRLA battery. The modeling result of Voltage was compared with result of constant current charge / discharge test. From this, it can be seen that the NTGK model can be applied to the lead acid battery with high accuracy. It was also found that the aging of lead-acid battery can be predicted by using it.

• The Transactions of The Korean Institute of Electrical Engineers
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• v.59 no.2
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• pp.248-254
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• 2010

This paper deals with implementation of the laboratory-scale microgrid using energy storage system. Also, this paper develops a simulation model of the microgrid with same parameters on the laboratory-scale microgrid using PSCAD/EMTDC. The experimental results show good agreement with the simulation results. This shows the validity of the simulation model. A valve regulated lead acid (VRLA) battery is used to store energy. Energy storage system with fast response is able to maintain power quality of sensitive load within the microgrid.

• Journal of the Korean Applied Science and Technology
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• v.25 no.4
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• pp.518-524
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• 2008

In this study, positive plates of lead acid battery of Pb-Ca alloy and Pb-Ca-Sn alloy were fabricated and the mechanical characteristics of positive plates were measured. This study observed how the changes of content of Ca & Sn affect interface corrosion which is located in between grid & active materials and lead acid batteries as well. The mechanical characteristics of grid alloy is better when Ca is 0.05 wt.% then 0.1 wt.%. This study said that the corrosion rate between the active material based on the charge/discharge cycle of lead acid battery and grid interface is much faster than a grid which contains Sn. And furthermore, according to the study the rate 30 of Sn/Ca which is added to grid shows the best performance.

• Proceedings of the KIEE Conference
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• 2002.07b
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• pp.1382-1384
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• 2002

The flooded type battery is used for solar lighting system. Because the characteristic of flooded type battery is the short life time, the maintenance cost is high. So the using flooded type battery in this system is inappropriate. The valve regulated lead acid batter.(VRLA) is the maintenance free and cycle service purpose. This paper presents the development of control system and monitoring system to applied VRLA battery for maintenance free and long life time in system.

• Journal of the Korean Applied Science and Technology
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• v.20 no.4
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• pp.296-308
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• 2003

The capacity and long life of gel electrolyte batteries is connected with gas recombination producting $PbO_2$ and Pb electrode. We were prepared with phosphoric acid gel electrolyte to know gel characteristics per density to assemble VRLA batteries. We studied by measuring electrolyte dispersion using Brewster-angle microscope(BAM), charge-discharge cycle and electrode structure using scanning election microscope(SEM) per electrolyte density. As a results, phosphoric acid density 1.210 was excellent gel dispersion in sol condition, electrode condition after fifty cycles in this study.

• Journal of the Korean Electrochemical Society
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• v.11 no.1
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• pp.33-36
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• 2008

In the present study, impedance spectrometry has been used for predicting State-of-Charge (SoC) of gel type, Valve Regulated Lead Acid (VRLA), battery. The impedance measurements of VRLA battery (2V/1.2 Ah) at various SoC were made over the frequency range from 100kHz to 10mHz with an amplitude 10 mV. The impedance parameters have been evaluated by the analysis of the data using an equivalent circuit and a complex non-linear least squares (CNLS) fitting method. The charge transfer resistance values and double layer capacitance values of the positive electrode were higher than those of the negative electrode. The gel resistance values increased with decreasing in SoC. This indicates that the gel resistance is an important parameter for predicting SoC of VRLA battery.