• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1996년도 추계학술대회 논문집
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• pp.187-190
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• 1996

Conducting polymers have band structures similar to those of inorganic semiconductors such as silicon. Several electronic devices have been constructed with conjugated polymers, mainly Schottky diodes and Metal-Insulator-Semiconductor Field-Effect Transistors (MISFET's). Organic semiconductor has been reported as active materials in MISFET's.$^{1.4}$ In our laboratory, $\alpha$-Sexithiencyl ($\alpha$-6T) has been synthesized and purified by sublimation method. In this study, thin films of $\alpha$-Sexithienyl were prepared on various substrates in ultra-high vacuum chamber by vacuum evaporation method, so called OMBD(Organic Molocular Beam Deposition).$^{7.9}$ The $\alpha$-Sexithienyl thin films were deposited with various deposition conditions. The crystalline structure, and molecular orientation of these films have being studied by using UV/Vis. spectroscopy and X-Ray Diffractometry.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1997년도 하계학술대회 논문집 C
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• pp.1391-1392
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• 1997

The thin films of $\alpha$-Sexithiophene($\alpha$-6T) were deposited by Organic Molecular Beam Deposition(OMBD) technique. The $\alpha$-6T was synthesized and Purified by the sublimation method The thin films of the $\alpha$-6T were deposited under various deposition conditions. The effects of deposition rate substrate temperature, and vacuum pressure on the formation of these films have been studied. The molecular orientations of $\alpha$-6T films were investigated with the polarized electronic absorption spectroscopy. The molecules in the $\alpha$-6T film deposited at a low deposition rate under a high vacuum were almost aligned Perpendicular to the substrate. The film deposited at an elevated substrate temperature(${\sim}90^{\circ}C$) showed higher conductivity than deposited at room temperature.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 1997년도 추계학술대회 논문집
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• pp.518-520
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• 1997

Recently, thiophene oligomer with short chain lengths has received much attention as model compounds for facilitating better understanding of electronic and optical properties of polymers, because oligomer is well-defined chemical systems and its conjugation chain length can be exactly controlled. Moreover, organic this films based on conjugated thiophene oligomer have potential for application to electronic and optoelectronic devices such as MISFETs(metal-insulator-semiconductor field-effect transistors) and LEDs(light-emitting diodes). However, there is little knowledge on electronic and structural properties of linear-conjugated oligothiophenes in solid states, compared with those in solutions. $\alpha$-sexithienyl($\alpha$-6T) thin-films were deposited by OMBD(Organic Molecular Beam Deposition) technique, where the $\alpha$-6T was synthesized and purified by the sublimation method. The $\alpha$-6T films were deposited under various conditions. The effects of deposition rate, substrate temperature, and vacuum pressure on the formation of these films have been studied. The molecules in the $\alpha$-6T film deposited at a low deposition rate under a high vacuum were aligned almost perpendicular to the substrate. The $\alpha$-6T films deposited at an elevated substrate temperature showed higher conductivity than the film deposited at room temperature. Electrical characterization of these films will be also executed by using four-point probe measurement technique.

• 한국진공학회지
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• 제7권4호
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• pp.361-367
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• 1998

유기 박막 트렌지스터의 활성층으로 사용하기 위하여 공액성 소중합체인 $\alpha$ -sexithiophene($\alpha$-6T)이라는 시료를 가지고 유기 분자선 증착법(OMBD)을 이용하여 박막 을 제작하였으며 $\alpha$-6T박막의 성막 조건에 따른 박막의 분자 배향, 결정구조 그리고 표면 특성을 알아보기 위해 angle-resolved UV/visible absorption spectroscopy, X-ray diffractometry(XRD) 그리고 atomic force microscopy(AFM)를 이용하였으며 그 분석 결과 성막 조건에 관계없이 모두 monoclinic한 결정구조를 갖으나, 초고진공, 낮은 성막 속도, 기 판의 온도가 높은 조건일 경우 $\alpha$-6T 분자들이 기판에 수직적으로 배열한다는 것을 확일할 수 있었다.

• 대한기계학회논문집B
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• 제26권2호
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• pp.288-301
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• 2002

A vacuum freeze drying experiment of skim milk solution in a cylindrical container is conducted to investigate the multi-dimensional drying characteristics of the process during the primary drying stage. Temperature histories at several positions are measured under the same process condition that is carefully controlled. Then the measured temperature histories at different positions are combined to produce instantaneous temperature distribution fields inside the cylindrical container. Along with the temperature measurement, the mass reduction history of the skim milk solution is also measured. From the measured temperature distribution curved configurations of sublimation interfaces and 2-dimensional heat transfer is inferred. The freeze drying under the present experimental setup is simulated with a calculation program that is based on a finite volume method with a moving grid system. Good agreements between the numerical and experimental results are observed. The present experimental results and the numerical approaches can be useful information in developing the analysis tools for practical vacuum freeze drying processes.

• 대한화학회지
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• 제23권5호
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• pp.325-328
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• 1979

트란스-1,2-비스피라질에틸렌(BPE)과 테트라메틸에틸렌(TME)용액에 빛을 쪼이면 이에대응한 탄화수소와는 달리 자유라디칼중간체를 거쳐 광첨가반응이 일어난다. 이 광첨가반응은 BPE의 $^1(n,\;{\pi}^*)$ 상태가 어느정도 자유라디칼 성격을 띄어 TME로 부터 알릴위치에 있는 수소원자를 탈취하여 일어난다. 주생성물을 대롱 크로마토그래피와 진공분별승화법으로 분리하여 2,3-디메틸-5,6-비스피라질-2-헥센임을 밝혔다.

• 전자공학회논문지A
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• 제32A권7호
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• pp.85-93
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• 1995

In this study, phthalocyanine thin films were prepared by vacuum sublimation method and investigated sensing characteristics of the films. The phthalocyannies used for the prepaation of the NO$_{x}$ sensors were metal-free Pc(H$_{2}$Pc) and metal Pc(CuPc, CoPc, PbPc). And the substrate temperatures maintained during the fomation of Pc films were varied between R.T. and 200$^{\circ]C$, and the base pressure was 5${\times}10^{6}$ torr. The relationships between NO$_{2}$ sensing properties and SEM analyses as a function of substrate temperatures during the formation of the films were investigated. Among the Pc films, PbPc film showed the best sensing characteristics. Particularlly, the PbPc films prepared at 70$^{\circ]C$ of the substrage temperature showen good sensitivity of 85% to 1ppm NO$_{2}$ gas at operating temperature 190$^{\circ]C$ and response time was about 24 seconds.

• 대한화학회지
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• 제13권1호
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• pp.83-88
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• 1969

By the three-step synthesis of alkyltropolone from five-membered cyclopentadiene, as described in Part Ⅰ, methyltropolone has been prepared. From the hydrolysis product of dichloroketene-methylcyclopentadiene cycloadduct, ${\beta}$-(Ⅰ) and ${\gamma}$-methyltropolone (Ⅱ) were separated, with the first predominating, by means of repeated fractional recrystallization and fractional vacuum sublimation. The total yield of these methyltropolones in the hydrolysis step was about 40%. Comparison of this result with those obtained in part Ⅰ revealed the following order as the relative readiness of their preparation: tropolone > methyltropolone > ethyltropolone. The reason for formation of the isomeric (Ⅱ) was discussed by an interpretation of NMR spectrum of cycloadduct in the unsaturation and methylgroup region.

• Bulletin of the Korean Chemical Society
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• 제30권12호
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• pp.2895-2898
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• 2009

The complete structural characterization of dehydrodivanillin, an important natural product of interest to the food, cosmetics and aroma industries, has been carried out using multi-dimensional NMR spectroscopic techniques, and its previously $reported^{13}$C-NMR values have been reassigned. Dense and granular thin films of dehydrodivanillin have been grown by sublimation under high vacuum and studied using Scanning Electron Microscopy (SEM), electrical and optical techniques. The transmittance spectra of the films indicate a wide optical band gap of more than 3 eV. Typical J-V characteristics of Glass/ITO/dehydrodivanillin/Al structure exhibited moderate current densities ${\sim}10^{-4}\;A/cm^2$ at voltages > 25 V with an appreciable SCLC mobility of the order of $10^{-6}\;cm^2$/V-s.

• Food Science and Biotechnology
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• 제14권3호
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• pp.428-432
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• 2005

To compare volatile compounds in bulgogi cooked by different heating procedures, bulgogi was prepared by convection oven, electric pan and charcoal grill. A total of 61 volatile compounds, consisting of 4 pyrazines, 10 sulfur-containing compounds, 7 carbonyls, 7 alcohols, 7 aliphatic hydrocarbons, 25 terpene hydrocarbons, and 1 miscellaneous compound, were tentatively identified in bulgogi cooked by the three heating methods. Comparatively, the difference in volatile compounds identified in bulgogi using the three different heating methods was not significant, except for sulfur-containing compounds and carbonyls which were detected at higher levels in the bulgogi cooked by convection oven than in that cooked by the other two heating methods. On the other hand, some compounds, such as furfural, benzaldehyde, and (E,E)-2,4-decadienal, were detected only in the bulgogi cooked by charcoal.