• Title/Summary/Keyword: Vacuum impregnation

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Support Effect of Arc Plasma Deposited Pt Nanoparticles/TiO2 Substrate on Catalytic Activity of CO Oxidation

  • Qadir, Kamran;Kim, Sang Hoon;Kim, Sun Mi;Ha, Heonphil;Park, Jeong Young
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.261-261
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    • 2013
  • The smart design of nanocatalysts can improve the catalytic activity of transition metals on reducible oxide supports, such as titania, via strong metal-support interactions. In this work, we investigatedtwo-dimensional Pt nanoparticle/titania catalytic systems under the CO oxidation reaction. Arc plasma deposition (APD) and metal impregnation techniques were employed to achieve Pt nanoparticle deposition on titania supports, which were prepared by multitarget sputtering and sol-gel techniques. APD Pt nanoparticles with an average size of 2.7 nm were deposited on sputtered and sol-gel-prepared titania films to assess the role of the titania support on the catalytic activity of Pt under CO oxidation. In order to study the nature of the dispersed metallic phase and its effect on the activity of the catalytic CO oxidation reaction, Pt nanoparticles were deposited in varying surface coverages on sputtered titania films using arc plasma deposition. Our results show an enhanced activity of Pt nanoparticles when the nanoparticle/titania interfaces are exposed. APD Pt shows superior catalytic activity under CO oxidation, as compared to impregnated Pt nanoparticles, due to the catalytically active nature of the mild surface oxidation and the active Pt metal, suggesting that APD can be used for large-scale synthesis of active metal nanocatalysts.

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Preservation and Identification for Wooden Ship Timber of Bonghwang-Dong, Gimhae, Korea (김해 봉황동 유적 출토 선박부재의 수종분석 및 보존처리)

  • Lee, Kwang Hee;Kim, Dong Yun
    • Journal of Conservation Science
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    • v.31 no.4
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    • pp.341-350
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    • 2015
  • The preservation has been conducted for wooden ship timber excavated from Bonghwang-Dong, Gimhae, Korea. The species were analyzed for conservation as pre-treatment. Outer panel was analyzed as Cinnamomum spp. and trapezoid wooden material, wooden wedge was Cryptomeria japonica D. Don.. Wooden ship timber have been treated by vacuum-freeze drying after impregnation with aqueous PEG#3,350 solution(almost 45%). The timber of Bonghwang-Dong ship is considered as Japanese ship that many data such as conformation of ship, location of site, japanese artifact of around site were confirmed. In addition, The ship timber give us the important information about the international trade with Japan.

Monitoring of a CFRP-Stiffened Panel Manufactured by VaRTM Using Fiber-Optic Sensors

  • Takeda, Shin-Ichi;Mizutani, Tadahito;Nishi, Takafumi;Uota, Naoki;Hirano, Yoshiyasu;Iwahori, Yutaka;Nagao, Yosuke;Takeda, Nobuo
    • Advanced Composite Materials
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    • v.17 no.2
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    • pp.125-137
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    • 2008
  • FBG (Fiber Bragg Grating) sensors and optical fibers were embedded into CFRP dry preforms before resin impregnation in VaRTM (Vacuum-assisted Resin Transfer Molding). The embedding location was the interface between the skin and the stringer in a CFRP-stiffened panel. The reflection spectra of the FBG sensors monitored the strain and temperature changes during all the molding processes. The internal residual strains of the CFRP panel could be evaluated during both the curing time and the post-curing time. The temperature changes indicated the differences between the dry preform and the outside of the vacuum bagging. After the molding, four-point bending was applied to the panel for the verification of its structural integrity and the sensor capabilities. The optical fibers were then used for the newly-developed PPP-BOTDA (Pulse-PrePump Brillouin Optical Time Domain Analysis) system. The long-range distributed strain and temperature can be measured by this system, whose spatial resolution is 100 mm. The strain changes from the FBGs and the PPP-BOTDA agreed well with those from the conventional strain gages and FE analysis in the CFRP panel. Therefore, the fiber-optic sensors and its system were very effective for the evaluation of the VaRTM composite structures.

NO REDUCTION PROPERTY OF Pt-V2O5-WO3/TiO2 CATALYST SUPPORTED ON PRD-66 CERAMIC FILTER

  • Kim, Young-Ae;Choi, Joo-Hong;Bak, Young-Cheol
    • Environmental Engineering Research
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    • v.10 no.5
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    • pp.239-246
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    • 2005
  • The effect of Pt addition over $V_2O_5-WO_3/TiO_2$ catalyst supported on PRO-66 was investigated for NO reduction in order to develop the catalytic filter working at low temperature. Catalytic filters, $Pt-V_2O_5-WO_3/TiO_2/PRD$, were prepared by co-impregnation of Pt, V, and W precursors on $TiO_2$-coated ceramic filter named PRD (PRD-66). Titania was coated onto the pore surface of the ceramic filter using a vacuum aided-dip coating method. The Pt-loaded catalytic filter shifted the optimum working temperature from $260-320^{\circ}C$(for the catalytic filter without Pt addition) to $190-240^{\circ}C$, reducing 700 ppm NO to achieve the $N_x$ slip concentration($N_x\;=\;NO+N_2O+NO_2+NH_3$) less than 20 ppm at the face velocity of 2 cm/s. $Pt-V_2O_5-WO_3/TiO_2$ supported on PRD showed the similar catalytic activity for NO reduction with that supported on SiC filter as reported in a previous study, which implies the ceramic filter itself has no considerable interaction for the catalytic activity.

The Inertia Friction properties of the Carbon/Carbon Composites Manufactured Using a Coal-tar Pitch (콜타르 핏치를 이용하여 제조된 탄소/탄소 복합재의 관성제동 마찰특성)

  • 이진용;서동수;임연수;이승구;박종규
    • Journal of the Korean Ceramic Society
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    • v.35 no.7
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    • pp.740-748
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    • 1998
  • The inertia friction properties of C/C composites manufactured by the processes of pressure and at-mospheric carbonizaton with a commerciallized and two kinds of modified coal-tar pitch as a matrix pre-cursor were investigated. The modifications of a pitch such as the introduction of mesophase and the ad-dition of sulphur into a raw pitch were not effective for a impregnation efficiency conducted in a vacuum and at the same time in a pressure of 5kg/cm2 due to the increase of the pitch viscosity. There was not a difference in the densification increment between the pitch modifications however it was revealed that a pressure carbonization was more advantageous than an atmospheric in the densification and the formation of anisotropic carbon matrix. The friction and wear propertis of C/C having higher degree of matrix cry-stallization higher density and hardness of friction surface showed superiority. As the braking energy was increased the friction coefficients were decreased and reached almost same level at the high kinetic energy of 99.6kJ. The wear trends at 99.6kJ were different from the behaviors of friction ceofficient under the same energy in which an oxidation wear is being considered along with a mechnical wear although the wear rates were almost similar to the friction coefficient at the low energy.

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VPI Varnishing Technology Effects on Frequency Characteristics of an Air Core Inductor Used in LISN Circuit Application

  • Kanzi, Khalil;Kanzi, Majid;Nafissi, Hamidreza
    • Journal of international Conference on Electrical Machines and Systems
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    • v.2 no.1
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    • pp.57-64
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    • 2013
  • The functional characteristic of LISN circuit, which is used for measurements of conductive noise in mains power line, is basically related to frequency characteristics of passive elements like inductors used in the circuit as well as the frequency response of inductors is highly related to the resins used in the varnishing process. The significant problem in determination of an inductor's frequency characteristic is the intrinsic resistance, inductance and parasitic capacitance. In this triplet, the parasitic capacitance is the major limiting factor of inductor's frequency range. This capacitance depends on inductor design parameters and materials filling the spaces of coil like resin and its coherency after curing process. In this paper, two similar inductors were designed and built. The first inductor was not varnished while the second one was varnished with VPI technology. VPI, or Vacuum, Pressure, Impregnation technology is one of the most reliable methods performing good insulating conditions for electrical circuits and windings based on resins. The measured results show that implying varnishing technology does not significantly affect the frequency response. However, due to mechanical solidity aspects and improved environmental protection, it is better to varnish the inductors.

The Insulation Test of Varnish (바니쉬의 절연성 평가)

  • Kim, Jeong-Hun;Shin, Beak-Chul;Kim, Sung-Pil;Lee, Soo-Woon;Lee, Jong-Pil;Hong, Jin-Woong
    • Proceedings of the KIEE Conference
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    • 1999.11d
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    • pp.950-952
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    • 1999
  • In this paper, we are studied a electrical properties study with P.D.GEORGE/STER LING Co. P.B 302-LV-2 POLYBUTADIENE RESIN which is used for VPI(Vacuum Pressure Impregnation)processing of field magnet and armature of traction motor in Korean national railroad at present was carried out its FT-IR (Fourier Transform Infra-Red) volume resistivity characteristics. The varnishes were experimented with the temperature range form $25[^{\circ}C]$ to $180[^{\circ}C]$ and applied voltage were supplied at 100, 250, 500, 1,000[V]. In this condition, the volume resistivity for specimens were measured. From the above study, the following data obtained for volume resistivity. It can be confirmed that velume resistivity with the increase of temperature is lower rapidly from room temperature to $130[^{\circ}C]$, and it is lower slowly at temperature higher than $130[^{\circ}C]$. Volume resistivity value is higher, according as the specimen is thick gradually. As the applied voltage is higher in the same temperature, volume resistivity value is lower.

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Development of 13 Tesla Superconducting Magnet (13 Tesla급 초전도 마그네트의 개발)

  • Cho, Jeon-Wook;Lee, Eon-Yong;Jin, Hong-Bum;Kwon, Young-Kil;Ha, Dong-Woo;Oh, Bong-Hwan;Nah, Wan-Soo;Oh, Sang-Soo;Ryu, Kang-Sik
    • Proceedings of the KIEE Conference
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    • 1994.07a
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    • pp.195-198
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    • 1994
  • The design and construction of a 13 Tesla / 46 mm bore superconducting magnet is presented. The system consists of an 5 Tesla outer NbTi coil with a bore I.D. of 144m, a winding O. D. of 208mm and the length of 200mm which is connected in series with a 200mm long insert coil constructed of multi filamentary $Nb_3Sn$. The insert coil was reacted after winding. Also, epoxy impregnation is accomplished at $Nb_3Sn$ coil using a low viscosity crack resistant epoxy which is forced into the coil with a series of vacuum and over atmosphere pressure cycle.

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Analysis of On-Line Partial Discharge in Air-Coolded Gas Turbine Generator (공랭식 가스터빈 발전기의 운전중 부분방전 분석)

  • Lee, Eun-Chun;Kong, Tae-Sik;Kim, Jae-Chul;Kim, Hee-Dong
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.28 no.7
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    • pp.41-47
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    • 2014
  • The on-line partial discharge (PD) in stator windings of air-cooled gas turbine (GT) generator (119.2MVA, 13.8kV) is measured and analyzed in this paper. This generator was designed by global vacuum pressure impregnation (VPI). The generator failed two times at top bar (16T) of phase B in the stator slot. Six epoxy-mica capacitors were installed in three phases of GT generator. On-line PD test was performed on GT generator using turbine generator analyzer (TGA). TGA showed that the normalized quantity number (NQN) and the PD magnitude($Q_m$) were high in phase B. Internal discharges were generated in phases A, B and C. The trend analysis of NQN and $Q_m$ value are obtained in order to monitor the insulation condition in GT generator stator windings. Phases A and C were in good condition. But phase B had deteriorated significantly

Design of 16 Tesla Superconducting Magnet (16 Tesla급 초전도 마그네트의 설계)

  • Kwon, Young-Kil;Cho, Jeon-Wook;Lee, Eon-Yong;Jin, Hong-Bum;Ha, Dong-Woo;Oh, Bong-Hwan;Ryu, Kyung-Woo;Oh, Sang-Soo;Ryu, Kang-Sik
    • Proceedings of the KIEE Conference
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    • 1995.07a
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    • pp.141-143
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    • 1995
  • The design of a 16 tesla/ 45mm bore superconducting magnet is presented. The system consists of an 8.2 tesla(at 4.2K) outer NbTi coil with a bore I.D. of 261mm, a winding O.D. of 453mm and the length of 430mm which is connected in series with a 5.6 tesla(at 4.2K) middle and a 4.7 tesla(at 4.2K) inner insert coil constructed of multifilamentary $Nb_{3}Sn$. The middle and inner insert coil will be reacted after winding. Also, epoxy impregnation will be accomplished at $Nb_{3}Sn$ coils using a low viscosity crack resistant epoxy which is forced into the coil with a series of vacuum and over atmosphere pressure cycle.

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