• Journal of the Korean Wood Science and Technology
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• 제42권4호
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• pp.357-366
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• 2014

백합나무 판재를 벽판재로 이용하기 위해 백합나무의 생재와 건조재에 대한 휘발성유기화합물(VOCs)과 알데히드류 방출 특성을 검토하였다. VOCs 및 formaldehyde를 포함한 aldehyde류의 방출량 측정은 다중이용시설 등의 실내공기질 관리법에 공시된 20 ${\ell}$ Chamber법에 따라 실시하였다. 백합나무의 생재 및 건조재에서는 30여 가지 이상의 VOCs가 검출되었다. 백합나무의 Total VOC 구성 비율 가운데 천연VOC (NVOC)의 비율은 11.1%로 다른 침엽수종과 비교하여 낮게 나타났다. 백합나무의 aldehyde류 분석 결과, 심재 및 변재에서 같은 3종(acetaldehyde, ketone, propionaldehyde)이 검출되었으며, formaldehyde의 방출량은 $4.01{\mu}g/m^3$ 이하로 나타났다. m-Tolualdehyde의 경우 백합나무 건조재의 심재에서만 $33.6{\mu}g/m^3$의 방출량을 보였으며, 심재와 변재 모두 ketone의 방출량이 가장 높게 나타났다. 백합나무 특유의 역한 냄새는 acetaldehyde와 propionaldehyde와 기타 VOCs에 의한 것으로 추정된다. 건조한 백합나무에서는 휘발성이 강한 ketone의 방출량이 증가하였다.

• 한국가구학회지
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• 제26권2호
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• pp.122-129
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• 2015

In previous study, VOC emission characteristics of coating materials for wood finishing were conducted and results showed that eco-friendly products has about 15~46% lower TVOC emission than typical products. In this study, lower TVOC emitted coating materials were applied on pine and then changes of VOC emission characteristics from pine with treatments were determined. Non-treated pine emitted $604.7{\mu}g/m^2h$ of TVOC that contained 66% of NVOC ($399.7{\mu}g/m^2h$). However, $V_2$ finished pine showed no NVOC emission rather than AVOC emission that consisted of Toluene, Ethylbenzene, m,p-Xylene, o-Xylene, 1,2,4- Trimethylbenzene. All coating materials inhibited ${\alpha}$-Pinene emission which originally from pine, but waterborne stain ($W_1$ and $W_3$) showed lower disruption of that emission. Moreover, $W_3$/wood showed higher NVOC emission such as ${\alpha}$-Terpinol, Terpinen-4-ol which are known as antioxidant substrates. Based on results, VOC emission characteristic of pine was significantly affected by coating materials with negatively in terms of ${\alpha}$-Pinene emission or positively in terms of NVOC emission. Therefore, coating material is important factor for indoor air quality when it would apply on wood products. For the future study, VOC emission characteristic of coated wood will be conducted continuously.

• 한국대기환경학회지
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• 제20권6호
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• pp.759-771
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• 2004

This study analyzed concentrations of volatile organic compounds (VOCs) produced from incineration of plastic wastes at $600^{\circ}C$. The plastic wastes used in this study included polyethyleneterephthlate (PETE), high density polyethylene (HOPE), polyvinyl chloride (PVC), low density polyethylene (LOPE), polypropylene (PP), polystyrene (PS) and other. Plastic wastes were heated from room temperature upto $600^{\circ}C$ providing the compressed air inside of a small-scale electric furnace for 90 minutes and then they were oxidized (incinerated) for 60 minutes at $600^{\circ}C$ maintaining the same air supply. VOCs emitted from the incineration process were sampled using an air sampling pump and Tedlar air bags for 150 minutes and then the components and concentrations of the VOCs were analyzed by a GC-MS. The most prominent chemical structure of the VOCs obtained from the incineration process of the HOPE, LOPE and PP, which include ethylene groups in their main chains, was identified as aliphatic hydrocarbons such as 1-hexene. However, aromatics such as benzene were major chemical structure from the incineration of PETE, PVC and PS which include benzene rings in their main chains. This study estimated the total VOC production from the incineration of the plastic wastes based on the real plastic waste production and the emission factors. 64% and 27% of the total VOC emissions consisted of aliphatic hydrocarbons and aromatics, respectively, which have double bonds within their molecular structure and thus a high ground level ozone formation potential.

• 해양환경안전학회:학술대회논문집
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• 해양환경안전학회 2005년도 춘계학술발표회
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• pp.111-118
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• 2005

국제해사기구(IMO)에서 1997년 9월 선박으로부터의 대기오염방지를 위한 협약(MARPOL 부속서VI)을 채택하여 U년 5월 19일 협약 발효를 앞두고 있다. 따라서 향후 선박으로부터 배출되는 배기가스 중에 포함된 아황산가스(SOx)와 질소산화물(No%)등 대기오염 물질의 배출 규제와 항만이나 터미널에서 유조선으로부터 휘발성유기화합물(VOCs) 배출금지 등의 규제가 강화될 것으로 예상된다. 본 연구는 이에 대한 대비와 관리방안을 모색하고자 외국에서 이용되는 선박의 배출오염물질 산정 방법을 이용하여 선박에서 배출되는 SOx, NOx의 배출량을 산정하였다. 또한 울산항 특성을 감안하여 액체화물 적$\cdot$양하시 발생되는 휘발성유기화합물(VOCs)의 양을 산정하는 방법에 대해 고찰하고 그 배출량을 산정하였다.

• 한국환경보건학회지
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• 제50권3호
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• pp.169-180
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• 2024

Background: CAPSS missing evaporate emissions of volatile organic compounds (VOCs) from liquid cargo loading and unloading at ports. It needs to be supplemented to improve air quality management and allow more effective policy formulation. Objectives: In this study, the VOC emissions from the loading and unloading of liquid cargo at ports, which are not included in CAPSS, were estimated. The results of this study were compared and analyzed with the emission levels as described by CAPSS, confirming the need for managing VOC emissions from the loading and unloading of liquid cargo. Methods: Methodology provided by the U.S. Environmental Protection Agency (EPA) was applied to estimate the VOC emissions from the loading and unloading of liquid cargo at ports. The types of liquid cargo loaded at unloaded at ports are diverse, but for this study emissions were estimated for 37 VOCs designated by the Ministry of Environment. Results: The estimated results for VOC emissions from liquid cargo loading and unloading at domestic ports was 112,079 tons/yr, which was confirmed to be 11% of the known CAPSS emissions. The highest emissions were found from the loading and unloading of naptha, and the port with the highest emissions was Ulsan Port. Conclusions: The results of the estimated VOC emissions from liquid cargo loading and unloading at ports confirmed the high emission levels. To protect the health of port workers and nearby residents, it is essential to manage the emission sources and undertake continuous research.

• 한국대기환경학회지
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• 제14권1호
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• pp.73-77
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• 1998

In this study, a total of 10 volatile organic compounds (VOCs) including BTEX were determined in the inside and outside of a highway thnnel in order to evaluate the emission profile of automobile exhaust with respect to the concentrations, relative ratio and correlation coefficient of target analytes. In addition to VOCs, CO $CO_2 and NO_2$ were measured simultaneously. The results of this study indicated that the most abundant compound was toluene followed by benzene and m+p-xylenes, and the correlation coefficients between VOCs except styrene were higher than 0.96. The concentration ratio of toluene, ethylbenzene, xylenes with respect to benzene measured in the inside of tunnel was 1.5, 0.13, 0.74, respectively. Such ratios were found to be very similar to those measured in tunnels in the USA.

• 분석과학
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• 제8권4호
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• pp.745-751
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• 1995

In this paper, several simulated devices were constructed for determining components of organic vapors emitting from decorative materials, daily use chemicals and from common behavior of human beings, such as smoking and cooking. The VOCs were preconcentrated on activated carbon and then desorbed by carbon disulphide. The results were obtained by GC/MS analysis and computer searching. It can be concluded that the categories of the sources and the components of organic vapors in indoor air are very complicated, and different sources of VOCs in indoor air have their own emission characteristics.

• 한국철도학회:학술대회논문집
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• 한국철도학회 2002년도 춘계학술대회 논문집
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• pp.572-576
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• 2002

Volatile Organic Compounds(VOCs) contribute to the formation of ozone and PAN which are injurious to health through complex photochemical reactions. Growing consumption of fossil fuels results in significant emission of VOCs and other air pollutants into the atmosphere. In this study, Ambient an grab samples of VOCs were collected at the platform and the concourse of six stations in the subway from February 21th to 28th. Among the total contents, Toluene (118.74 ppm) showed the highest concentration in the Indukwon station platform while other contents were measured low concentrations. Also, the platform concentrations were higher than the concourse concentrations through the whole contents.

• Asian Journal of Atmospheric Environment
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• 제4권2호
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• pp.63-71
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• 2010

The removal characteristics for aromatic and aliphatic VOCs by electron beam (EB) were discussed in terms of several removal variables such as initial VOC concentration, absorbed dose, background gas, moisture content, reactor material and inlet temperature. It was reviewed that only reactor material was an independent variable among the potential control factors concerned. It was also suggested that main mechanism by EB should be radical reaction for the VOC removal rather than that by primary electrons. It was discussed that the removal efficiency of benzene was lower than that of hexane due to a closed benzene ring. In the case of aromatic VOCs, it was observed that the decomposition of the VOCs with more functional groups attached on the benzene ring was much easier than those with less ones. As for aliphatic VOCs, it was also implied that the longer carbon chain was, the higher the removal efficiency became. An EB-catalyst hybrid system was discussed as an alternative way to remove VOCs more effectively than EB-only system due to much less by-products. This hybrid included supporting materials such as cordierite, Y-zeolite, and $\gamma$-alumina.

• KIEAE Journal
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• 제5권1호
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• pp.51-57
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• 2005

In this study, time-dependent concentration variations of VOCs from fixed furniture and Ondol floor widely used as finishing material of the floor were measured, and prediction equations were developed based on the measured results. VOCs were measured and analyzed based on EPA TO-17 and NIOSH 1500, 1501 method respectively, and GC/FID were used for the analysis of VOCs concentration. Measurements were carried out for 10 days after the installation of furniture and for 40 days after the installation of the floor in the residence constructed more than 10 years ago. In both case of floor and furniture installation, time-dependent concentration decay of VOCs can be properly converted into logarithmic scale. Especially in case of furniture, toluene showed the highest concentration and took longest time to decay. As a result of the prediction of VOCs concentration decay under different air change rate using estimated equations, concentration decay rate of indoor VOCs increased rapidly as the air change rate also increased.