• Structural Engineering and Mechanics
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• 제78권1호
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• pp.67-75
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• 2021

This work studies the behaviour of a steel portal frame selection under fire exposure, considering both span lengths and fire exposure times as variables. Such structures combine carbon steel (S275), fireproof micro-alloyed steel (FR), and coatings of intumescent paint with variable thicknesses, improving thereby the flame retardant behaviour of the steel structure. Thus, the main contribution of this study is the optimization of the portal frames by combining both steels, analysing the resulting costs influence on the final dimensions. Besides, the topological optimization of each steel component within the structure is also defined, in accordance with the following variables: weather conditions, span, paint thickness, and cost of steel. The results mainly confirmed that using both FR and S275 grades with intumescent painting is the Pareto optimum when considering performance, feasibility and costs of such portal frames widely used for industrial facilities.

• 한국화재소방학회논문지
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• 제28권6호
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• pp.22-27
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• 2014

본 연구에서는 Fuel bed를 이용한 실험을 통하여 지표화 확산에 의한 온도 분포, 화염 높이, 복사열, 확산속도 등을 측정하였다. 실험 변수로는 수종, 풍속 및 경사도 등을 사용하였다. 수종으로는 침엽수종인 소나무 낙엽과 활엽수종인 굴참나무 낙엽을 사용하였다. 풍속은 터널식 방 구조에서 간이풍속 장치를 이용하여 1 m/s, 3 m/s, 5 m/s 풍속을 조절하여 실험하였다. 경사도는 Fuel bed의 기울기를 $0^{\circ}$, $10^{\circ}$, $20^{\circ}$, $30^{\circ}$로 변화시켜 가며 조절하였다. 온도 분포 및 확산속도를 측정하기 위하여 K-type 1.6 mm 열전대를 35개를 격자모양으로 배치하였다. 측정을 위하여 복사열량계를 사용하였으며 이외에도 비디오 카메라 및 열화상 카메라를 사용하였다.

• 한국안전학회지
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• 제21권2호
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• pp.29-34
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• 2006

It is revealed that these are correlated with the height of chamber deciding the turbulence extent. In the first experiment, It was examined about the effects of different multiple obstacles such as circular, triangular and square things with the rig that the dimension of original experimental rig was $700{\times}700{\times}200mm{\wedge}3$. Then the heights of chamber were increased from 200 to 1000mm. The dimensions of each obstacle were $70{\times}700{\times}{\wedge}2$ and rectangular vent area were $210{\times}700{\times}{\wedge}2$. In the second one, we performed to see the effects of locations of different multiple obstacles in 200, 500 and 800mm height from the bottom. The results are : The multiple triangular obstacles caused the highest overpressure while the lowest one was the multiple circle bars. Then, the triangular bars caused the highest flame acceleration while the circular obstacles was lowest too. The results showed that the critical height was 800mm due to the formation of turbulence. And the lesser $Av/V^{2/3}$ were small, the more pressure and pressure acceleration rate were increased.

• Journal of Preventive Medicine and Public Health
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• 제17권1호
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• pp.269-279
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• 1984

The optimum conditions for measuring cadmium content of less than 0.2ppm by flame atomic absorption spectrophotometry were investigated. The cadmium in urine was extracted by APDC-MIBK for the analysis by atomic absorption spectrophotometry after ashing them by a wet method. 1. Optimum conditions by APDC-MIBK and DDTC-MIBK extractions. The acidic aqueous solution was prepared with appropriate amount of 0.IN nitric acid, 5ml of 25% (W/V) sodium potasstum tartarate, 10ml of saturated ammonium sulfate, and 2ml of 2% APDC(or 1 ml of 5% DDTC) chelating agent. The total volume of solution was adjusted to 55 ml and pH to $2{\sim}10$ (or$7{\sim}10$). The aqueous solution was extracted with 10ml MIBK. Concentration of Triton X-100 did not effect the absorbance for APDC-MIBK extraction of cadmium, but absorbance decreased as the concentration increased for DDTC-MIBK extraction. The sensitivity and detection limits for the cadmium determination from APDC-MIBK extraction were 0.0038ppm and 0.0102, 0.0022ppm and 0.0116 for DDTC-MIBK, and 0.0132ppm and 0.0034 for 0.1N nitric acid. APDC-MIBK and DDTC-MIBK extractions were 3 times higher than 0.1N nitric acid for the sensitivity. 2. Excretion of cadmium in 24-hour urine by APDC-MIBK extraction. Determination of cadmium in urine by atomic absorption spectrophotometry of A.A. (Cd=2 mA) mode and B.C. (Cd=4 mA) mode and B.C. (Cd=4mA, $D_2=20mA$) mode showed some difference (p<0.05). The difference of cadmium determination and recovery according to method of standard additions and standard calibration curve method in urine was not significant (p>0.05, $93.48{\pm}11.78%,\;94.83{\pm}22.00%$). Excretion of cadmium in 24-hour urine collection from normal person and variance analysis within measurement variation was not significant (p>0.05), but between interindividual was significant (0.05). Determination of cadmium content by two different methods of flame atomic absorption spectrophotometry and dithizone colorimetry showed that the results from the two methods can be described by a regression line with a good correlation (y=1.0153x-0.2927, x=Cd by D.C., y=Cd by A.A.S., $r=0.8651^*$, p<0.01).

• 공업화학
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• 제20권2호
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• pp.234-240
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• 2009

마그네슘염과 알칼리를 출발물질로 하는 수산화마그네슘 제조에서 공정 변수가 생성되는 입자의 크기, 형상 및 응집도에 미치는 영향에 대해 완전 요인배치(full factorial) 실험계획법(Design of experiment)으로 연구하였다. 수열합성에서는 알칼리/$MgCl_2$ 몰 비가 낮을수록, $MgCl_2$ 농도와 수열처리 온도가 높을수록 평균입경은 커지고 1차 입자 크기와 2차 입자 크기가 유사하지만, 침전법으로 제조한 수산화마그네슘은 1차 입자의 응집현상으로 2차 입경은 커지며, 응집성은 알칼리원의 종류와 $MgCl_2$의 농도에 따라 달라졌다. 알칼리원의 종류에 따른 차이는 $NH_4OH$를 사용한 경우 NaOH를 사용한 것보다 입자의 크기가 커지고 분산성이 우수하였다. 크기 및 표면 상태가 다른 샘플을 선정하여 LDPE와 EVA 혼합수지에 혼합하여 난연 특성을 비교하였을 때, 50, 55% 함량에서는 일반적으로 2차 입경 크기가 감소함에 따라 LOI값은 상승하지만, UL-94에서는 1차 입자가 작은 경우에 더 우수한 등급을 받는 경우가 있었다. 60%의 높은 함량에서 입자의 제조경로와 무관하게 UL-94는 V0 등급이지만, 미립이더라도 응집성있는 경우 한계산소지수가 상대적으로 낮다는 것을 알 수 있었다.

• 한국응용과학기술학회지
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• 제33권4호
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• pp.802-812
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• 2016

실리콘 폼은 고성능 가스켓, 열 차폐, 진동 마운트 및 Enter 키 패드로 많은 산업 분야에서 난연성 소재로서 매우 유용하다. 실리콘 발포체는 실온에서 백금 촉매 및 무기필러 존재하에서 비닐기를 함유한 폴리실록산 (V-silicone) 및 수산기를 함유한 폴리실록산 (OH-silicone)과 하이드라이드를 함유한 폴리실록산 (H-silicone)의 수소와의 수소축합반응의해 가교와 발포를 동시에 일으켜 제조하였다. 이러한 방법은 종래의 발포와 경화를 각각 실시한 공정보다 매우 편리한 방법이다. 이 실험에 사용 된 기능성 실리콘수지들은 1.0 meq/g의 vinyl기를 가진 점도 20 Pa-s의 V-silicone과 0.4 meq/g의 수산기를 가진 점도 50 Pa-s의 OH-silicone 및 7.5 meq/g의 하이드라이드기를 함유한 점도 0.06 Pa.s.의 H-silicone으로 구성되어 있다. 본 연구에서는 실리콘의 종류 및 함량, 촉매, 충전제 등의 변화에 따른 실리콘수지 발포체의 구조 및 기계적 특성에 미치는 영향을 연구하였다. 백금 촉매는 실리콘 수지에 대하여 0.5 wt%이면 충분하였다. 낮은 점도의 OH-silicone의 첨가는 초기 발포 속도를 높이며 발포체 밀도는 감소시키지만, 낮은 점도의 V-silicone의 첨가는, 인장 강도뿐만 아니라 신율도 감소시킨다. SF-3 조건에서 얻은 실리콘수지 발포체의 밀도, 인장강도 및 신율을 각각 $0.58g/cm^3$, $3.51kg_f/cm^2$ 및 176 %를 얻을 수 있었다. 본 발포 시스템에서의 알루미나 충전재 역시 실리콘수지 발포체의 기계적 특성을 향상시키는 중요한 역할을 하였다.

• The Journal of Advanced Prosthodontics
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• 제5권1호
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• pp.44-50
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• 2013

PURPOSE. The aim of this study was to evaluate the effects of repeated porcelain firing process on the corrosion rates of the dental alloys. MATERIALS AND METHODS. Cr-Co, Cr-Ni and Pd-Ag alloys were used for this study. Each metal supported porcelain consisted of 30 specimens of 10 for 7, 9 and 11 firing each. Disc-shaped specimens 10 mm diameter and 3 mm thickness were formed by melting alloys with a propane-oxygen flame and casted with a centrifuge casting machine and then with the porcelain veneer fired onto the metal alloys. Corrosion tests were performed in quintuplicate for each alloy (after repeated porcelain firing) in Fusayama artificial saliva solution (pH = 5) in a low thermal-expansion borosilicate glass cell. Tamhane and Sheffe test was used to compare corrosion differences in the results after repeated firings and among 7, 9 and 11 firing for each alloy. The probability level for statistical significance was set at ${\alpha}$=0.05. RESULTS. The corrosion resistance was higher (30 mV), in case of 7 times firing (Commercial). On the other hand, it was lower in case of 11 times firing (5 mV) (P<.05). Conclusion. Repeated firings decreased corrosion resistance of Pd-Ag, Cr-Co and Cr-Ni alloys. The Pd-Ag alloy exhibited little corrosion in in vitro tests. The Cr-Ni alloy exhibited higher corrosion resistance than Cr-Co alloys in in vitro tests.

• 한국분무공학회지
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• 제20권2호
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• pp.107-113
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• 2015

To date, the demand for Combined Cycle Power Plant (CCPP) has been continuously increased to overcome the problem of air pollution and lack of energy. In particular, the underground CCPP is exposed to substantial fire and explosion risks induced by gas leakage. The present study conducted numerical simulations to examine the fire behavior and gas leakage characteristics for a restricted region including gas turbine and other components used in a typical CCPP system. The commercial code of FLUENT V.14 was used for simulation. From the results, it was found that flammable limit distribution of leakage gas affects fire behavior. Especially, the flame is propagated in an instant in restricted region with LNG gas. In addition, consequence analysis factors such as critical temperature and radiation heat flux are introduced. These results would be useful in making the safety guidelines for the underground CCPP.

• 설비공학논문집
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• 제28권7호
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• pp.275-282
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• 2016

MILD (Moderate and Intense Low-oxygen Dilution) combustion using oxygen as an oxidizer is considered as one of the most promising combustion technologies for high energy efficiency and for reducing nitrogen oxide and carbon dioxide emissions. In order to investigate the effects of nozzle angle and oxygen velocity conditions on the formation of oxygen-MILD combustion, numerical and experimental approaches were performed in this study. The numerical results showed that the recirculation ratio ($K_V$), which is an important parameter for performing MILD combustion, was increased in the main reaction zone when the nozzle angle was changed from 0 degrees to 15 degrees. Also, it was observed that a low and uniform temperature distribution was achieved at an oxygen velocity of 400 m/s. The perfectly invisible oxy-MILD flame was observed experimentally under the condition of a nozzle angle of $10^{\circ}$ and an oxygen velocity of 400 m/s. Moreover, the NOx emission limit was satisfied with NOx regulation of less than 80 ppm.

• 한국추진공학회지
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• 제3권3호
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• pp.53-61
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• 1999

충돌제트는 미사일 또는 수직/단거리 이착륙기의 배기가스가 지면이나 화염 편향기 등에 부딪힐 때 발생하며 노즐의 형상, 노즐과 평판과의 거리등에 따라 유동양상이 달라진다. 본 연구에서는 초음속 노즐을 통해 과소 팽창된 제트가 평판에 부딪힐 때 형성되는 평판 압력분포 및 버블 발생 등에 대한 시험결과를 선행된 충격파 풍동을 이용한 시험 결과와 비교하고 초음속 유동시험장치 이용시의 유동 특성을 규명하였다. 초음속 유동시험장치와 충격파 풍동의 평판에서 압력분포는 저압 챔버 내의 수분과 온도 때문에 차이가 나타났고 과소 팽창비에 따른 압력분포는 서로 유사한 경향을 보여주었다.