• KSBB Journal
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• v.14 no.2
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• pp.225-229
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• 1999

Enzymatic resolution reactions were investigated using Candida rugosa lipase for the production of potically pure S-(+)-Ketoprofen. When the enzymatic hydroysis (and esterification) of recemic ketoprofen esters (and recemic ketoprofen with alcohol) was investigated comparatively, aqueous media was more specific for S-enantiomer than organic media. In the enzymatic hydrolysis of racemic ketoprofen ethyl ester in aqueous media, optimal temperature and pH for enantioselectivity were $37^{\circ}C$ and 4, respectively. The stereoselectivity of the enzyme was enhanced by adding dialcohols such as ethylene glycol and propylene glycol. The enantiomeric ratio obtained in the 40 %(v/v) ethylene glycol was 2-fold higher than that without the additive. By adding $CH_2Cl_2$, $CHCl_3$ and $CCl_4$ (5%,v/v), the enantioselectivity was reversed. A dramatic increase in the stereoselectivity was achieved using lipase purified by anion exchange chromatography. The type A lipase(the first eluted lipase fraction) showed an enantiomeric ratio of >100, whereas the type B lipase(the second eluted lipase fraction) exhibited enantimomer ratio of 9.0 in the hydrolysis of racemic ketoprofen ethyl ester.

• Journal of the Korea Concrete Institute
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• v.18 no.5 s.95
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• pp.667-675
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• 2006

Concrete is much more easily damaged by various parameters than by the only one and performance reducing mechanism grows more complicated in that condition. In addition, the factors which really act in concrete structure tend to be activated in turn and the degradation of concrete is very rapidly progressed. The purpose of this study is to evaluate the properties of polymer cement mortars under combined cures. The polymer cement mortars are prepared with various polymer types, polymer-cement ratios and cement-fine aggregate ratio, and tested for compressive and flexural strengths, accelerated carbonation, chloride ion penetration and acid resistance test, and freezing-thawing test. The properties of polymer cement mortars under combined cures is discussed. From the test results, polymer cement mortars have superior strengths compared with plain cement mortar under combined cures. The strengths of polymer cement mortars are markedly increased at curing condition II and V, however strengths are not improved at curing condition I and IV irregardless of polymer types. The carbonation and chloride ion penetration depths of polymer cement mortars tend to decrease in curing conditions, III-C, IV-B, V-A order, and decrease with increasing polymer cement ratios. It is concluded that polymer cement ratio of 10 to 15% are considered optimum for the preparation of such polymer cement mortars.

• The Transactions of the Korean Institute of Power Electronics
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• v.5 no.2
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• pp.176-183
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• 2000

In this paper, sixth order hannonic injected PWM for improving‘ input CWTent distortion of single switch t three phase boost converter is presented. Peliodic sixth order hmmonic ${\gamma}$oltage is inj<:ded in the control circuit t to var${\gamma}$ the duty ratio of the converter switch within one switching cycle. In the result, the input phase c currents are forced to track the input voltage and an 해most unity power factor is obtained. Expelimental r results are verified by converter operating at 400V /6kW with three phase 140V ~220V input and by C02 arc w welding machine which was nonlinear load with 3 $\phi$ 220V input.

• Applied Biological Chemistry
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• v.34 no.3
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• pp.273-278
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• 1991

Methanol assimilating bacterium, Pseudomonas sp. ILS-003 was used to investigate the optimum conditions for the production of $poly-{\beta}-hydroxybutyric$ acid from methanol. For PHB production, the optimum initial pH was 6.4 and the optimum temperature was $30^{\circ}C$. Also the optimum methanol concentration was found to be 1.0%(v/v). In the PHB production, $(NH_4)_2SO_4$ was the most effective nitrogen source and the optimum concentration was 0.8 g/l, which was eqivalent to 17.4 in C/N ratio. Also, deficiency of the 2 valence metal ions in the medium had stimulating effect on PHB accumulation. Under the optimum substrate concentration, successive feeding of 0.25%(v/v) methanol was the most effective on PHB production. Under the optimum conditions, 1.94 g/l of PHB and 2.78 g/l of dry biomass were produced in 96 hours, and the yield was 69.8%(w/w).

• The Journal of The Korea Institute of Intelligent Transport Systems
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• v.15 no.5
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• pp.29-41
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• 2016

V2X environment is the most popular part of the C-ITS based on the high technologies. To evaluate V2X environment technologies, radio communication range and market penetration rate of V2X vehicle are used. This paper studies the V2X environment considering various traffic congestion level, radio communication range and market penetration rate of V2X vehicle using the microscopic simulation (VISSIM) based on proper parameters and algorithm. In conclusion, V2X environment can reduce the congestion in proper traffic volume. However, if traffic volume is almost near the capacity, even V2X environment can't relieve the road condition. Furthermore, increase of the radio communication range does not always mean the decrease of the congestion and even with the small market penetration rate, it can also have an impact on the V2X environment. This result will be the foundation for the V2X environment much better.

• Journal of the Korean Chemical Society
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• v.47 no.2
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• pp.121-126
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• 2003

Tris(2-cyclohexylaminoethyl)amine (L) was synthesized by the Schiff base condensation reaction of tris(2-aminoethyl)amine with cyclohexanone, followed by reduction. The thermodynamic characteristics, mole ratio and formation constant of [Zn(II)-L] complex were measured by the cyclic voltammetry and isothermal titration. In the case of Zn(II), well-defined cathodic and anodic peak were obtained at -1.02V and -0.48V vs Ag/AgCl , respectively. For the [Zn(II)-L] complex, both peaks were obtained at -1.19V and -0.45V vs Ag/AgCl, respectively. In addition, the peak height gradually increases as the scan rate increases, suggesting that the currents obtained were diffusion - controlled. The mole ratio and stability constant of the complex measured cyclic voltammerty were 1:1 and logK$_f$= 5.8, respectively. And the mole ratio and stability constant of the complexe calculated by isothermal titration method was 1:1 and logK =5.4, respectively. ${\Delta}$H, ${\Delta}$G and T${\Delta}$S for the complex formation were -53.0 kJ/mol, -31.1 kJ/mol, and -21.9 J/K at 25 ${\circ}$C, respectively.

• Korean Chemical Engineering Research
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• v.49 no.5
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• pp.600-604
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• 2011

Solution processed IGO thin films were prepared using a general chemical solution route by spin coating. The effect of the annealing temperature of IGO thin films based on the ratio of 2:1 of indium to gallium on crystallization was investigated with varying annealing temperature from $300^{\circ}C$ to $600^{\circ}C$. The electronic device characteristic of IGO thin film was investigated. The solution-processed IGO TFTs annealed at 300 and $600^{\circ}C$ in air for 1 h exhibited good electronic performances with field effect mobilities as high as 0.34 and 3.83 $cm^2/V{\cdot}s$, respectively. The on/off ratio of the IGO TFT in this work was $10^5$ with 98% transmittance.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2001.06a
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• pp.72-72
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• 2001

Plasma polymerized thin films have been deposited on Si(lOO) substrates at $25-400^{\circ}C$ using thiophene ($C_4H_4S$) precursor by plasma assisted chemical vapor deposition (PACVD) method for low-dielectric device application. In order to compare physical properties of the as-grown thin films, the effects of the plasma power, gas flow ratio and deposition temperature on the dielectric constant and thermal stability were mainly studied. XRD and TED studies revealed that the as-grown thin films have highly oriented amorphous polymer structure. XPS data showed that the polymerized thin films that grown under different RF power and deposition temperature as well as different gas ratio of $Ar:H_2$ have different stoichiometric ratio of C and S compared with that of monomer, indicating a formation of mixture polymers. Moreover, we also realized that oxygen free and thermally stable polymer thin films could be grown at even $400^{\circ}C$. The results of SEM, AFM and TEM showed that the polymer films with smooth surface and sharp interface could be grown under various deposition conditions. From the electrical property measurements such as I-V and C-V characteristics, the minimum dielectric constant and the best leakage current were obtained to be about 3.22 and $10-11{\;}A/\textrm{cm}^2$, respectively.

• Journal of the Korean Geotechnical Society
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• v.17 no.2
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• pp.5-12
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• 2001

고유기질토의 정규압밀과 과입밀에 대한 압밀특성을 연구하기 위하여 전북지역에서 채취한 2종류의 고유기질토 IS와 YJ를 사용하여 일련의 실내 표준압밀시험과 반복압밀시험을 수행하였다. 전북지역 대표적인 고유기질토의 물리적 특성은 유기물함량이 각각 58%와 72%, 자연함수비 487%와 635%, 초기공극비 7.02와 9.72이었다. 표준압밀시험결과 K, $M_{v}$ , $C_{v}$ 는 압밀하중이 증가함에 따라서 선행하중을 경계로 일반 점토보다 크게 감소하는 특성을 보였다. 또한 2단계, 3단계 반복압밀 시험결과 K, $M_{v}$ 는 압밀하중이 증가함에 따라서 완만하게 감소하였으며 표준압밀시험결과보다는 작게 나타났다. 2단계 반복압밀의 경우 $C_{v}$ 는 정규압밀영역에서 표준압밀시험결과보다 약 10-12배정도 크게 나타났다. $C_{c}$ , $C_{a}$ 는 압밀하중이 증가함에 따라서 각각 선행하중의 약 2.5배, 3배 하중을 정점으로 크게 증감하는 고유기질토 고유의 특성을 나타냈다. 고유기질토의 $C_{c}$ , $C_{a}$ 는 일반 점토보다 압밀압력 의존성이 큰 특성을 나타냈으며 최대값도 각각 2.9-3.8, 0.3-0.4로 일반 점토보다 큰 값을 보였다. 2단계, 3단계 반복압밀시험결과 $C_{c}$ , $C_{a}$ 는 압밀하중이 증가함에 따라서 약간 증가하였다. $C_{a}$ 는 OCR이 증가함에 따라서 감소하였으며 특히 OCR이 1-2 범위에서 감소폭이 크게 나타났다. 고유길토의 제압밀계수는 반복회수 및 하중의 크기 등에 따라서 큰 영향을 받으며 또한 과압밀 크기의 대소는 고유기질토의 $C_{a}$ 에 큰 영향을 미치는 것으로 생각되어 이 분야에 대한 더 많은 연구가 필요하다.

• KSBB Journal
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• v.26 no.1
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• pp.13-18
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• 2011

In this study, precipitation process was developed for the recovery of the lactic acid from calcium lactate fermentation broth. Calcium lactate yield was improved by decreasing the solubility of calcium lactate through the addition of ethanol (25%, v/v) as a co-precipitant. The optimal lime type, lime concentration, stirrer speed, precipitation time, temperature, and solvent amount for $Ca(LA)_2$ precipitation were CaO, 0.0175 g/mL, 220 rpm, 24 h, $5^{\circ}C$, ethanol 25% (v/v), respectively. Lactic acid was easily and efficiently recovered from precipitated $Ca(LA)_2$ by adding sulfuric acid ($Ca(LA)_2/H_2SO_4$ molar ratio=1:1). In the model solution of organic acids and fermentation broth, the overall yields of recovered lactic acid were 62% and 55%, respectively, under the aforementioned optimal conditions.