• Applied Chemistry for Engineering
• /
• v.27 no.6
• /
• pp.664-668
• /
• 2016

The contamination in soil, underground water and river environment became serious due to illegal waste dumping. In this study, our research group analyzed the oil species of illegally disposed oils from J City. After pretreating the mixture of oil, water and solid phases to obtain homogeneous phase components, the physical property analysis, atom analysis, and gas chromatography were performed. From the results showing 11.8% of oxygen content, $-6^{\circ}C$ of pour point and chromatogram pattern. the contaminated oil was identified as a vegetable one. High performance liquid chromatography (HPLC) analysis was also performed in order to know what kind of vegetable oil was, and the ratio of LLO, OOL and POL was found to be high indicating that the disposed oil is majorly the used soybean oil with some vegetable oil mixtures. This study can be used for identifying contaminators for oils from the illegal waste dumping.

• Food Engineering Progress
• /
• v.21 no.1
• /
• pp.49-56
• /
• 2017

Vegetable seed oils (VSOs) have been extracted and used not only as ingredients in food and as sources of dietary lipids, but also as sources of nutraceuticals used to overcome the various oxidative stresses that contribute to the development of diseases, including cancer and other chronic conditions. The chemical compositions and oxidative stabilities of various VSOs were therefore investigated; samples were stored for 35 d, with each oil having been tested under $O_2$ exposure, sealed from $O_2$ exposure and sealed from $O_2$ exposure while containing $O_2$ scavengers. Oxidative stability was evaluated by peroxide value (POV), p-anisidine value (p-AnV), iodine value (IV), and thiobarbituric acid (TBA) value. Perilla seed and flaxseed oil were mostly composed of linolenic acid (45.5% and 59.7%, respectively), whereas pine seed oil was mostly composed of linoleic acid (48.3%). Meanwhile, camellia seed and olive oils contained 80% oleic acid, which correlated strongly with oxidative stability. The POV, p-AnV, and TBA values were the highest under $O_2$ exposure, and the lowest in the presence of $O_2$ scavengers. These results indicate that VOS oxidative stability depends not only on storage conditions, but on unsaturated fatty acid profiles as well.

• Journal of Energy Engineering
• /
• v.25 no.3
• /
• pp.18-26
• /
• 2016

Mineral oil is the most widely used for electrical transformer, though some factors should be considered such as their environmentally harmfulness when it spill and low flash point. To cover these disadvantages, vegetable oil has developed because of its high biodegradability and thermal stability. However, it is necessary that many studies should conduct to reveal the detailed impacts of long-term operation as transformer oil. In this paper, we applied the accelerated aging test which simulate the real transformer circumstances using insulation paper, coil, steel at $150^{\circ}C$, which is higher than normal operation, for 2 weeks. To figure out the oxidation characteristics between mineral oil and vegetable oil test major properties and components such as total acid number, dielectric breakdown and dissolved gas components during that period. As a result of these tests, we found that vegetable oil has higher electric insulation ability than mineral oil though poor total acid number by hydrophile property. Vegetable oil also kept its thermal stability under the given circumstances.

• Tribology and Lubricants
• /
• v.38 no.2
• /
• pp.41-52
• /
• 2022

Mineral electrical insulating oil, which is widely used in transformers, exhibits excellent cooling performance and transformer efficiency. However, given that it is composed of petroleum-based components, it is weak in terms of biodegradability. This causes environmental problems in case of leakage and a low flash point, which is a factor that would cause great damage in the event of a fire in a substation. In this context, the use of eco-friendly electric insulating oil composed of bio-based vegetable oil and synthetic ester, which has excellent biodegradability and flame retardancy performance, has recently been expanded to the field of electric power, and various research and development (R&D) studies are in progress. According to different research results, vegetable oil and synthetic ester manufacturing technology, thermal stability, oxidation stability, property change, and quality control, which are characteristics of eco-friendly electrical insulating oils, are major factors affecting the maintenance of insulating oil properties. In addition, power companies have established and operated quality control standards according to the use of eco-friendly electrical insulating oil as they expand the exploitatoin of renewable energy in electricity production. In particular, deterioration and oxidation characteristics were jointly identified in R&D as an important influencing factor according to the content of saturated and unsaturated fatty acids present in vegetable oils and synthetic esters in power transformer applications.

• Proceedings of the Korean Society of Machine Tool Engineers Conference
• /
• 2002.04a
• /
• pp.223-238
• /
• 2002

This paper presented on an environment estimation of cutting fluid which is a mouse model of acute bacterial rhinosinusitis using cutting fluid in grinding and cutting. Above results will be remarked the necessity of friendly environmental cutting skill when it had used in workshop. The results of a mouse experimental using cutting fluid showed that it are occurred to the respiratory organs sickness. Also cutting fluid are occurred to hurtfulness a person when it used to grinding and cutting in workshop. Also, the results of grinding experiments in avitation materials showed that surface roughness are superior to more emulsion type oil than vegetable type oil according to increase of the depth of cut. Grinding force are similar to both emulsion type oil and vegetable type oil.

• Asian Pacific Journal of Cancer Prevention
• /
• v.16 no.12
• /
• pp.5125-5135
• /
• 2015

Background: Total fat intake may be associated with increased risk of breast cancer, and fish oil has been suggested as a protection factor to breast cancer. But the effect of vegetable oils is inconclusive. We aimed to investigate the association with high vegetable oils consumption and breast cancer risk, and evaluated their dose-response relationship. Design: We systematically searched the MEDLINE, EMBASE, Cochrane databases, and CNKI updated to December 2014, and identified all observational studies providing quantitative estimates between breast cancer risk and different vegetable oils consumption. Fixed or random effect models were used to estimate summary odds ratios for the highest vs. lowest intake, and dose-response relationship was assessed by restricted cubic spline model and generalized least-squares trend (GLST) model. Results: Five prospective cohort studies and 11 retrospective case-control studies, involving 11,161 breast cancer events from more than 150,000 females, met the inclusion criteria. Compared with the lowest vegetable oils consumption, higher intake didn't increased the risk of breast cancer with pooled OR of 0.88 (95% CIs:0.77-1.01), and the result from dose-response analyses didn't show a significant positive or negative trend on the breast cancer risk for each 10g vegetable oil/day increment (OR=0.98, 95% CIs: 0.95-1.01). In the subgroup analyses, the oils might impact on females with different strata of BMI. Higher olive oil intake showed a protective effect against breast cancer with OR of 0.74 (95% CIs: 0.60-0.92), which was not significant among the three cohort studies. Conclusions: This meta-analyses suggested that higher intake of vegetable oils is not associated with the higher risk of breast cancer. Olive oil might be a protective factor for the cancer occurrence among case-control studies and from the whole. Recall bias and imbalance in study location and vegetable oils subtypes shouldn't be ignored. More prospective cohort studies are required to confirm the interaction of the impact of vegetable oils on different population and various cancer characteristic, and further investigate the relationship between different subtype oils and breast cancer.

• Tribology and Lubricants
• /
• v.12 no.3
• /
• pp.6-11
• /
• 1996

There has been a growing concern for the use of mineral oil based lubricants because of the worldwide interest in environmental issues. This has prompted the use of vegetable oils as more environmentally acceptable base fluids. In view of this, four-ball wear test was carried out to investigate the tribological behavior of selected vegetable oils blended with ZDDP, TCP and DBP under high speed and temperate conditions. Of the additive evaluated, the new additive, DBP has provided antiwear performance superior to the two other additives more commonly used. This superior performance by DBP is probably caused by different wear mechanism. This wear mechanism has been evidenced by the surface analysis of worn balls conducted using optical microscope and EDAX.

• Nutrition Research and Practice
• /
• v.7 no.4
• /
• pp.256-261
• /
• 2013

The aim of this study was to examine the effects of perilla oil as well as several vegetable oils, including flaxseed oil, canola oil, and rice bran oil on plasma levels of cardioprotective (n-3) polyunsaturated fatty acids in mice by feeding each vegetable oil for a period of eight weeks. Concentrations of docosapentaenoic acid (DHA) and eicosapentaenoic acid (EPA), fish-based (n-3) polyunsaturated fatty acids, showed an increase in the plasma of mice fed perilla and flaxseed oils compared to those of mice in the control group (P < 0.05), whereas rice bran and canola oils did not alter plasma DPA and EPA concentrations. Arachidonic acid concentration was increased by feeding rice bran oil (P < 0.05), but not canola, flaxseed, or perilla oil. In addition, oleic acid, linoleic acid, and docosahexaenoic acid concentrations were altered by feeding dietary rice bran, canola, perilla, and flaxseed oils. Findings of this study showed that perilla oil, similar to flaxseed oil, is cardioprotective and could be used as an alternative to fish oil or even flaxseed oil in animal models.

• Journal of Advanced Marine Engineering and Technology
• /
• v.16 no.5
• /
• pp.97-110
• /
• 1992

Rape-seed oil has high viscosity and high rubber content like other vegetable oils. When crude rape-seed oil obtained by a general oil extraction process is used in a diesel engine, automization condition during injection is not good and a large amount of combustion product is doposited in a combustion chamber. The improvement of a diesel engine is required to use rape-seed oil as a diesel engine fuel. In this study, the physical and chemical properties and combustion characteristics of rape-seed oil were investigated. The auxiliary aid was developed to improve automization condition and the effect of the auxiliary injection aid on the performance of a diesel engine was determined. The results are as follows. 1) Oil content of rape-seed is 45%. The exraction rate is 33%. The resuls show higher values compared to those of other vegetable oils. 2) The viscosity of rape-seed oil is 50.8 cSt and nearly 14 times of diesel oil viscosity. 3) The heating value and flash point of rape-seed oil are 9720kcal/Kg and 318$^{\circ}C$, respectively. 4) In case rape-seed oil is used as fuel, brake horse power, specific fuel consumption and brake thermal efficiency are compared to those of diesel oil. The results of rape-seed oil show 3.6%, 12.7% and 3.1% higher values. 5) Particle size of injection fuel with the auxiliary injection aid on the performance of a diesel engine was determined. The results are as follows. 1) Oil content of rape-seed is 45%. The extraction rate is 33%. The results show higher values compared to those of other vegetable oils. 2) The viscosity of rape-seed oil is 50.8 cSt and nearly 14 times of diesel oil viscosity. 3) The heating value and flash point of rape-seed oil are 9720kcal/Kg and 318.deg.C, respectively. 4) In case rape-seed oil is used as fuel, brake horse power, specific fuel consumption and brake thermal efficiency are compared to theose of diesel oil. The results of rape-seed oil show 3.6%, 12.7% and 3.1% higher values. 5) Particle size of injection fuel with the auxiliary injection aids is 100.mu.m smaller than that od injection fuel without the aid. 6) Brake horse power and brake thermal efficiency with the auxiliary injection aid increase 5.07% and 6.07%, respectively. However, specific fuel consumption decreases 3.85% with the auxiliary injection aid.

• Asian-Australasian Journal of Animal Sciences
• /
• v.22 no.4
• /
• pp.565-575
• /
• 2009

Two experiments in the sequential order were conducted to determine the effects of different dietary lipid sources on the growth and fatty acid composition of rohu (Labeo rohita) and to examine the viability of a return fish oil finisher diet in restoring the human cardio-protective fatty acid profile. In the first experiment, fish were fed either with coconut oil (D1), olive oil (D2), sunflower oil (D3), linseed oil (D4) and fish oil (D5) as the main lipid source in the isonitrogenous diet for 90 days. No significant differences in growth were observed. Among the experimental diets moisture content of fish varied significantly (p<0.05) between the groups. Dietary lipid sources had a profound influence on the fatty acid profile of the muscle and liver as tissue fatty acid profile reflected the dietary fatty acid composition. Increased amounts of eicosapentaenoic acid and docosahexaenoic acid were observed in tissue of fish fed D4 and arachidonic acid was observed in the tissue of fish fed D3. We have also detected the metabolites of n-3 and n-6 pathway in D4 and D3 groups respectively, which prompted us to conclude that rohu, can desaturate and elongate $C_{18}$ essential fatty acids to $C_{20}$ and $C_{22}$ HUFA. A second feeding trial was conducted using the animals from the five different treatment groups for the duration of 30 days with fish oil rich diet (D5). Feeding with fish-oil rich washout diet resulted in the near equalization of all the other treatment groups tissue fatty acid profiles to that of fish oil (D5) fed group. These results indicate that a finishing fish oil diet can be effectively used to restore the human cardioprotective fatty acid profile in rohu fed with vegetable oils as lipid source.