• Title/Summary/Keyword: Urushiol

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Inhibitory Effects of the Extract of Rhus verniciflua Stokes on the Reverse Transcriptase of AIDS

  • Kim, Myong-Jo;Choi, Won-Cheol;Barshinikov, A. M.;Kobayashi, A.
    • Korean Journal of Medicinal Crop Science
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    • v.10 no.4
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    • pp.284-287
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    • 2002
  • Four olefinic catechols, commonly referred to as urushiol were isolated from the sap of Korean Rhus verniciflua Stokes and had the stronger inhibitory effects on the reverse transcriptase of AIDS. The hexane extract with a inhibitory effects on reverse transcriptase was purified by silica and ODS gel column chromatography. The active compounds were identified by MS and $^1H-NMR$ as 3-[8' (Z), 11' (Z), 14' -pentadecatrienyl]catechol, 3-[8' (Z), 11' (Z)-pentadecadienyl]catechol, 3-[8' (Z)-penta- decenyl]catechol, and 3-pentadecylcatechol. All of these compounds showed strong inhibitory effects on reverse transcriptase of AIDS, in which 3-pentadecylcatechol exhibited the highest activity $(IC_{50}\;:\;10.87\;{\mu}g/ml)$.

Characteristics of Hardening Behavior of Korean Rhus Lacquer by F.T.-I.R. (F.T.-I.R.에 의한 한국산 옷액의 경화거동 특성)

  • Lee, Phil-Woo;Kim, Hyun-Joong
    • Journal of the Korean Wood Science and Technology
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    • v.18 no.1
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    • pp.10-14
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    • 1990
  • 한국산 옻액의 경화거동을 알아보기 위하여 F.T.-I.R. 분석을 수행하였다. Acetone 추출한 urushiol의 F.T.-I.R. peak는 $3,422cm^{-1}$, $2,928cm^{-1}$, $1,622cm^{-1}$, $1,475cm^{-1}$, $1,281cm^{-1}$, $984cm^{-1}$, $947cm^{-1}$, $735cm^{-1}$이었다. 또한, 옻액의 정시경화거동에서 $1,651cm^{-1}$ peak는 urushiol-quinone이 laccase의 촉매작용에 의하여 산화중합한 후 982와 $947cm^{-1}$의 conjugated diene와 결합해서 dimer 형성을 알 수 있었다.

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The analysis of the urushiol congeners from the extracts of lacquer trees (옻나무 추출물 중 우루시올 동종체의 함량비 분석)

  • Cho, Yumi;Jung, Yu-Kyung;Kim, Jinsan;Lee, Joonbae;Paeng, Ki-Jung
    • Analytical Science and Technology
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    • v.22 no.1
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    • pp.65-74
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    • 2009
  • Active components of lacquer tree referred to as urushiol congeners, which are catechol derivatives with various alkyl or alkenyl substituents. The olefin side chains typically have one, two or three double bonds. In this study, the each congener's ratio analysis of extracts from korean lacquer tree are compared to the one from other asian lacquer tree. Extraction was performed using liquid-liquid extraction (LLE) method with soxhlet system from tree's bark and sap. Extracts were analyzed by reverse phase liquid chromatography and on-line electro spray ionization mass spectrometry (LC-MS/MS).

Antioxidative Activities of Rhus verniciflua Bark from Different Area (산지별 옻피의 항산화 활성과 옻닭국 기호특성 비교)

  • Park, Sung-Jin;Yang, Byung-Wook;Hahm, Young-Tae;Oh, Deog-Hwan;Kim, Jung-Beom;Yang, Ji-Yun;Kang, Byung-Sun
    • The Korean Journal of Food And Nutrition
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    • v.25 no.3
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    • pp.430-435
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    • 2012
  • The objectives of this study were to form comparisons of total polyphenol compounds, the antioxidant activities and the urushiol contents of lacquer tree(Rhus verniciflua) bark and the sensory properties of chicken soup was made with lacquer tree bark that was cultivated from different cultivation areas; Hamyang, Wonju and China. Total polyphenol contents of Hamyang, Wonju and China were estimated as $375.28{\pm}3.48$, $403.60{\pm}6.6$ and $311.06{\pm}4.99$ mg/g. The total flavonoids contents of Hamyang, Wonju and China were measured as $374{\pm}14.12$, $683.70{\pm}12.64$ and $334.64{\pm}18.40$ mg/g. The total phenolic compounds and flavonoids concentration, DPPH radical scavenging activity, and ABTS radical scavenging of lacquer tree cultivated in Wonju were higher than the others; Hamyang and China. The urushiol content of lacquer tree bark from Hamyang was $4.59{\pm}0.04$ ppm and higher than others. Urushiol was not detected in China lacquer tree bark. Sensory evaluation tests for chicken soup containing lacquer tree bark showed that the scores of Wonju lacquer tree bark chicken soup was highest, however there are no differences between Hamyang, Wonju, and China significantly(p<0.05).

Effects of CEPA on the Secretion of Lacquer and Bark Physiology of Lactree(Rhus verniciflua Stokes) (CEPA 처리(處理)가 옻나무의 칠액분비(漆液分泌) 및 수피생리(樹皮生理)에 미치는 영향(影響))

  • Choi, Tae Bong;Kim, Mahn Jo;Hyun, Jung Oh
    • Journal of Korean Society of Forest Science
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    • v.89 no.1
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    • pp.116-125
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    • 2000
  • This study was conducted to investigate the effects of CEPA(2-chloroethyl phosphonic acid) on bark physiology and anatomy of lactree(Rhus verniciflua Stokes). Sample trees of similar size and growth rate were selected from 7-year-old lactree plantation located in Hyengsung-kun, Kangwon-do. Lanolin pastes containing 0.1, 1, or 10% CEPA were put into the bark-removed hole made by corer(${\phi}1cm$) on the main stem at 1.2m above the ground on June 16, 1995. Five weeks after application of CEPA, bark thickness was markedly increased as a result of the increase in the amount of phloem and intercellular spaces, and correlated with the increased production of urushiol. By the application of 10% CEPA, bark thickness was increased approximately 2.5 times, and the urushiol content within bark was increased 2.8 times compared to that of untreated trees because CEPA stimulated the accumulation of urushiol within bark. Treatment of 10% CEPA also increased the size and the total number of secretory canals, and induced an increase in ray width. The phloem parenchyma cells of CEPA-treated trees were well-developed and closely packed with little intercellular space.

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Study on using a Leather Coating with Urushiol (옻을 이용한 가죽 코팅 처리 연구)

  • Yang, Seung-Hun;Min, Byung-Wook;Shin, Soo-Beom;Park, Min-Seok;Kim, Yung-Jun
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2011.03a
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    • pp.112-112
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    • 2011
  • 가구용으로 제조되는 가죽(Leather)은 대부분 화학적인 약품을 이용하여 코팅을 진행하기 때문에 현대사회에서 추구하는 친환경적인 면에서 미흡한 면이 있다. 그래서 예전부터 전해오는 전통적인 방법인 나무 및 식물에서 추출한 천연 탄닝제인 Minosa, Quebracho, Chestnut, Tara 등을 사용하여 가죽을 제조하고, 자연그대로의 맞을 살릴 수 있는 전통 코팅 방법인 옻을 이용하여 가죽에 코팅하는 가죽 제조 연구를 진행하였다. 옻은 방부성, 항균성, 아토피 피부염 예방, 자연스러움 등이 우수한 친환경적인 코팅제 재료이다. 특히, 현대 실내용 가구의 친환경적인 코팅제에 대한 관심이 증가하면서 주목을 받는 천연 물질이다. 본 연구에서는 천연 탄닝제를 이용하여 가죽 원단(Curst)에 옻의 주성분인 우르시올(Urushiol)을 이용하여 패딩, 스프레이, 롤코터 등의 다양한 방법으로 코팅 처리 후 가죽의 물성 및 특성을 연구하였다. 연구 결과 제조된 옻 코팅 가죽은 고기능성을 가질 뿐 만 아니라, 안락감과 고감성을 지니는 최고급 소파 소재로 다양한 표면 효과를 창출할 수 있을 것으로 기대되었다.

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The Study on the Process and Quality Control of Rhus Verniciflua Stokes Extract (Nexia) (건칠(乾漆) 추출물(Nexia)의 Quality Control을 위한 기시법 및 안정성 연구)

  • Park, Sang-Jae;Kim, Kyung-Suk;Jung, Hyun-Sik;Choi, Won-Cheol;Yoon, Seong-Woo
    • Journal of Korean Traditional Oncology
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    • v.11 no.1
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    • pp.31-39
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    • 2006
  • Rhus Verniciflua Stokes has been used for long history to treat blood stasis and cancer in Oriental Medicine. But urushiol, a constituent of Rhus Verniciflua Stokes has T-cell mediated allergic reaction, so it has made clinical limitation. Nexia is allergen removed extract of Rhus Verniciflua Stokes and its extraction process as well as quality control is needed to be standardized. The optimized extraction condition is as follow; temperature is $90{\sim}95^{\circ}C$, volume of slovent 10 times, extraction time >6 hours, pressure $, slovnet water or EtOH(60%), yield 8.1${\sim}$9.8(w/w). HPLC pattern and isolation study showed Nexia contain fisetin(>13.0%), fustin(>7.0%) and no urushiol.

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