• Nuclear Engineering and Technology
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• v.38 no.4
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• pp.353-358
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• 2006

Alpha track analysis for the determination of the trace amount of alpha emitting nuclides in a very small particle was performed as an efficient and powerful technique during safeguard inspection. Metal particles with well-defined spherical shape, size and isotopic compositions as a reference material were used to correlate the number of tracks or track diameter with an isotopic composition eventually to identify the uranium enrichment in the environmental swipe samples. Slopes in the number of tracks versus the exposure time curve provide a simple insight into the uranium enrichment of an unknown particle. Low enriched uranium metal particles result in slopes still steeper than the depleted or natural uranium metal particles. In addition, a linear relationship between track diameter and particle size Is thought to be a useful first stage analytical tool as an efficient and convenient inspection guide. The significance of the simple linear model was also judged using the usual statistical tests.

• Proceedings of the Korean Radioactive Waste Society Conference
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• 2005.11b
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• pp.39-50
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• 2005

Electrolytic reduction of uranium oxide to uranium metal was studied in a $LiCl-Li_{2}O$ molten salt system. The reduction mechanism of the uranium oxide to a uranium metal has been studied by means of a cyclic voltammetry. Effects of the layer thickness of the uranium oxide and the thickness of the MgO on the overpotential of the cathode and the anode were investigated by means of a chronopotentiometry. From the cyclic voltamograms, the decomposition potentials of the metal oxides are the determining factors for the mechanism of the reduction of the uranium oxide in a $LiCl-3\;wt{\%} Li_{2}O$ molten salt and the two mechanisms of the electrolytic reduction were considered with regards to the applied cathode potential. In the chronopotentiograms, the exchange current and the transfer coefficient based on the Tafel behavior were obtained with regard to the layer thickness of the uranium oxide which is loaded into the porous MgO membrane and the thickness of the porous MgO membrane. The maximum allowable currents for the changes of the layer thickness of the uranium oxide and the thickness of the MgO membrane were also obtained from the limiting potential which is the decomposition potential of LiCl.

• Applied Chemistry for Engineering
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• v.10 no.8
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• pp.1119-1123
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• 1999

In this paper, electrorefining of uranium metal was studied to develop pyrometallurgical processing technology in molten salt system. The reaction between uranium metal and $CdCl_2$ was taken about 3 hours and the uranium metal deposits were obtained in the form of dendrite grown on the cathode surface in every electrotransport experiment. The shapes of dendrite were changed according to the applied voltages. Current efficiency was decreased with the increase of current density. Deposition rate was not changed after 6 hours and its maxium was obtained at $100{\sim}150mA/cm^2$ of current density and about 75 rpm of stirring speed, respectively. Also, the current efficiency was increased with decrease of the pitch of spiral groove curved on cathode.

• Nuclear Engineering and Technology
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• v.53 no.6
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• pp.1931-1938
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• 2021

Uranium ingot is produced by metallothermic reduction of uranium tetrafluoride using magnesium or calcium as reductant. Presence of oxygen containing compounds viz. uranyl fluoride and uranium oxide in the starting uranium fluoride has a significant effect on the firing time, final temperature of the charge, slag-metal separation and hence the metal recovery. As reported in the literature, the maximum tolerable limit for uranyl fluoride in the UF₄ is 2.5 wt% and limit for uranium oxide content is in the range 2-3 wt%. No theoretical or experimental basis is available till date for these limits. Analyses have been carried out in this study to understand the effect of UO₂F₂ concentration in the starting fluoride on the final temperature of the products and thus the reduction characteristics. UF₄ having uranyl fluoride concentration, less than as well as more than 2.5 wt%, have been investigated. Thermodynamic calculations have been carried out to arrive at a general expression for the final temperature attained by the products during calciothermic reduction of UF₄. Finally, an upper limit for the oxygen containing impurities has been estimated using the CaO-CaF₂ phase diagram.

• Nuclear Engineering and Technology
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• v.45 no.7
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• pp.979-986
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• 2013

Uranium metal particle dispersion plates have been proposed as targets for Molybdenum-99 (Mo-99) production to improve the radioisotope production efficiency of conventional low enriched uranium targets. In this study, uranium powder was produced by centrifugal atomization, and miniature target plates containing uranium particles in an aluminum matrix with uranium densities up to 9 $g-U/cm^3$ were fabricated. Additional heat treatment was applied to convert the uranium particles into UAlx compounds by a chemical reaction of the uranium particles and aluminum matrix. Thus, these target plates can be treated with the same alkaline dissolution process that is used for conventional $UAl_x$ dispersion targets, while increasing the uranium density in the target plates.

• Nuclear Engineering and Technology
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• v.49 no.3
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• pp.541-548
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• 2017

Uranium metal used for fabrication of fuel for research reactors in India is generally produced by magnesio-thermic reduction of $UF_4$. Performance of magnesio-thermic reaction and recovery and quality of uranium largely depends on properties of $UF_4$. As ammonium diuranate (ADU) is first product in powder form in the process flow-sheet, properties of $UF_4$ depend on properties of ADU. ADU is generally produced from uranyl nitrate solution (UNS) for natural uranium metal production and from uranyl fluoride solution (UFS) for low enriched uranium metal production. In present paper, ADU has been produced via both the routes. Variation of uranium recovery and crystal structure and composition of ADU with progress in precipitation reaction has been studied with special attention on first appearance of the precipitate Further, ADU produced by two routes have been calcined to $UO_3$, then reduced to $UO_2$ and hydroflorinated to $UF_4$. Effect of two different process routes of ADU precipitation on the characteristics of ADU, $UO_3$, $UO_2$ and $UF_4$ were studied here.

• Proceedings of the Korean Nuclear Society Conference
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• 2001.05a
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• pp.385-385
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• 2001

• Nuclear Engineering and Technology
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• v.41 no.8
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• pp.1101-1108
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• 2009

The ocean contains around eighty elements of the periodic table and uranium is also one among them, with a uniform concentration of 3.3 ppb and a relative abundance factor of 23. With a large coastline, India has a large stake in exploiting the 4 billion tonnes of uranium locked in seawater. The development of radiation grafting techniques, which are useful in incorporating the required functional groups, has led to more efficient adsorbent preparations in various geometrical configurations. Separation based on a polymeric adsorbent is becoming an increasingly popular technique for the extraction of trace heavy metals from seawater. Radiation grafting has provided definite advantages over chemical grafting. Studies related to thermally bonded non woven porous polypropylene fiber sheet substrate characterization and parameters to incorporate specific groups such as acrylonitrile (AN) into polymer back bones have been investigated. The grafted polyacrylonitrile chains were chemically modified to convert acrylonitrile group into an amidoxime group, a chelating group responsible for heavy metal uptake from seawater/brine. The present work has been undertaken to concentrate heavy metal ions from lean solutions from constant potential sources only. A scheme was designed and developed for investigation of the recovery of heavy metal ions such as uranium and vanadium from seawater.

• Proceedings of the Korean Nuclear Society Conference
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• 1996.05b
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• pp.592-597
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• 1996

The KALIMER core, of which nuclear design is largely governed by inherent safety and reactivity control issues, is fueled with metallic fuel, and the initial core will be loaded with 20% enriched Uranium metal fuel. KALIMER safety design objectives include the accommodation of unprotected, ATWS events without operator action, and without the support of active shutdown, shutdown heat removal, or any automatic system without damage to the plant and without jeopardizing public safety. The transient analysis of the core designs has been focused on severe events to assess the margins in the design, and ATWS events are the most severe events that must be accommodated by the KALIMER design. The ATWS performance has been evaluated for the preliminary initial core design of KALIMER with a particular emphasis on the inherent negative reactivity feedback effects, including the Doppler, sodium density, fuel axial expansion, core radial expansion, and control rod driveline expansion. Results show that the Uranium metal core design meets the temperature limits with margin.

• Proceedings of the Korean Nuclear Society Conference
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• 2002.05a
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• pp.274-274
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• 2002