• Title/Summary/Keyword: Unusual stability

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Study on Thermal Stability of Ni-P-Fe and Ni-P-B Layers Electroplated on Alloy 600 (Alloy 600에 전기 도금한 Ni-P-Fe 및 Ni-P-B 층의 열적 안정성 연구)

  • Kim, Myong-Jin;Kim, Joung-Soo;Kim, Dong-Jin;Kim, Hong-Pyo
    • Journal of the Korean institute of surface engineering
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    • v.43 no.2
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    • pp.57-63
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    • 2010
  • In this study, thermal stability of the mechanical properties of Ni-P-B and Ni-P-Fe layers electroplated on Alloy 600 material was evaluated by measuring their microhardness, tensile strength, and elongation after heat treatment at $325^{\circ}C$ and $400^{\circ}C$. According to the results, there was no noticeable change in microhardness of the two electrodeposits before and after heat treatment at the temperatures for 30 days. In the case of a Ni-P-B electrodeposit, ultimate tensile strength (UTS) slightly increases with heat treatment time, while its elongation decreases, showing good thermal stability in the mechanical properties at high temperature. On the other hand, UTS and elongation of Ni-P-Fe decrease with heat treatment time, which is very unusual observation. This result was attributed to the bad microstructure of Ni-P-Fe having many defects in the deposit formed early stage of an electroplating process and their redistribution to link to become large ones during heat treatment.

Evaluation of Maintenance Coating Materials for Steel Bridges

  • Lee, Chan-Young;Cheong, Haimoon;Kim, Ok-Sun
    • Corrosion Science and Technology
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    • v.4 no.5
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    • pp.207-210
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    • 2005
  • Coating performance of various coating systems including chlorinated rubber and epoxy/urethane used most for steel structures of highway in Korea, was evaluated by exposing test specimen to complex deterioration factors such as ultraviolet ray, moisture, freeze-thaw cycle and salt. Deteriorated specimens were evaluated by chalking and rust grades according to ASTM, and measurement of color differences and adhesion. In overall coating performances such as corrosion resistance, photochemical stability, and adhesion, ceramic/ urethane, moisture-curable urethane/ urethane, etc. were superior. As for other coating materials tested in this study, superior materials against certain deterioration factors may be inferior against other factors. Accordingly, in order to select suitable maintenance coating materials for the use, it is thought that investigation of suitability through experiment should precede selection of materials, especially for unusual coatings or paints.

In situ UHV TEM studies on nanobubbles in graphene liquid cells

  • Shin, Dongha;Park, Jong Bo;Kim, Yong-Jin;Kim, Sang Jin;Kang, Jin Hyoun;Lee, Bora;Cho, Sung-Pyo;Novoselov, Konstantin S.;Hong, Byung Hee
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.102-102
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    • 2016
  • Water, which is most abundant in Earth surface and very closely related to all forms of living organisms, has a simple molecular structure but exhibits very unique physical and chemical properties. Even though tremendous effort has been paid to understand this nature's core substance, there amazingly still lefts much room for scientist to explore its novel behaviors. Especially, as the scale goes down to nano-regime, water shows extraordinary properties that are not observable in bulk state. One of such interesting features is the formation of nanoscale bubbles showing unusual long-term stability. Nanobubbles can be spontaneously formed in water on hydrophobic surface or by decompression of gas-saturated liquid. In addition, the nanobubbles can be generated during electrochemical reaction at normal hydrogen electrode (NHE), which possibly distorts the standard reduction potential at NHE as the surface nanobubble screens the reaction with electrolyte solution. However, the real-time evolution of these nanobubbles has been hardly studied owing to the lack of proper imaging tools in liquid phase at nanoscale. Here we demonstrate, for the first time, that the behaviors of nanobubbles can be visualized by in situ transmission electron microscope (TEM), utilizing graphene as liquid cell membrane. The results indicate that there is a critical radius that determines the long-term stability of nanobubbles. In addition, we find two different pathways of nanobubble growth: i) Ostwald ripening of large and small nanobubbles and ii) coalescence of similar-sized nanobubbles. We also observe that the nucleation and growth of nanoparticles and the self-assembly of biomolecules are catalyzed at the nanobubble interface. Our finding is expected to provide a deeper insight to understand unusual chemical, biological and environmental phenomena where nanoscale gas-state is involved.

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A Study on Design and Validation of Pilot Activated Recovery System to Recover Aircraft Abnormal Attitude, Altitude and Speed (항공기 비정상 자세, 고도 및 속도 회복을 위한 자동회복장치 설계 및 검증에 관한 연구)

  • Kim, Chong-Sup;Kang, Im-Ju
    • Journal of Institute of Control, Robotics and Systems
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    • v.14 no.12
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    • pp.1302-1312
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    • 2008
  • Relaxed Static Stability(RSS) has been applied to improve flight performance of modern version supersonic jet fighters. Flight control systems are necessary to stabilize an unstable aircraft and to provide adequate handling qualities. Also, flight control systems of modern aircraft employ many safety measure to cope with emergency situations such as a pilot unknown attitude flight conditions of an aircraft in night flight-testing. This situation is dangerous because the aircraft can lose if the pilot not take recognizance of situation. The system called the "Pilot Activated Recovery System" or PARS, provided a pilot initiated automatic maneuver capable of an aircraft recoveries in situations of unusual attitudes, speed and altitude. This paper addresses the concept of PARS with AARS(Automatic Attitude Recovery System), ATCS(Automatic Thrust Control System) and MARES(Minimum Altitude Recovery Estimation System), and this control law is designed by nonlinear control law design process based on model of supersonic jet trainer. And, this control law is verified by real-time pilot evaluation using an HQS(Handling Quality Simulator). The result of evaluation reveals that the these systems support recovery of an aircraft unusual attitude and speed, and improve a safety of an aircraft.

Antagonistic effects Na+ and Mg2+ on the structure, function, and stability of mycobacteriophage L1 repressor

  • Bandhu, Amitava;Ganguly, Tridib;Chanda, Palas K.;Das, Malabika;Jana, Biswanath;Chakrabarti, Gopal;Sau, Subrata
    • BMB Reports
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    • v.42 no.5
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    • pp.293-298
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    • 2009
  • Temperate mycobacteriophage L1 encodes an unusual repressor (CI) for regulating its lytic-lysogenic switching and, in contrast to the repressors of most temperate phages, it binds to multiple asymmetric operator DNAs. Here, ions like $Na^+$, $Cl^-$, and $acetate^-$ ions were demonstrated to facilitate the optimal binding of CI to cognate operator DNA, whereas $K^+$, $Li^+$, ${NH_4}^+$, $Mg^{2+}$, $carbonate^{2-}$, and $citrate^{3-}$ ions significantly affected its operator binding activity. Of these ions, $Mg^{2+}$ unfolded CI most severely at room temperature and, compared to $Mg^{2+}$, $Na^+$ provided improved thermal stability to CI. Furthermore, the intrinsic tryptophan fluorescence of CI was changed notably upon replacing $Na^+$ with $Mg^{2+}$ and these opposing effects of $Mg^{2+}$ and $Na^+$ were also noticed in their actions on the C-terminal fragment (CTD) of CI. Taken together, $Na^+$ appeared to be more appropriate than $Mg^{2+}$ for maintaining the biologically active conformation of CI needed for its optimal binding to operator DNA.

Biochemical and NMR Characterization of MTH1880 Mutant Proteins for Folding-Unfolding Studies

  • Kim, Hee-Youn;Ryu, Soo-Young;Yun, Ji-Hye;Kim, Suhk-Mann;Chang, Ik-Soo;Lee, Weon-Tae
    • Bulletin of the Korean Chemical Society
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    • v.31 no.12
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    • pp.3521-3524
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    • 2010
  • MTH1880 is a hypothetical protein derived from Methanobacterium thermoautotrophicum, thermophilic methanogen. The solution structure determined by NMR spectroscopy showed that it has a novel $\alpha+\beta$-fold with a highly acidic ligand binding pocket. Since MTH1880 maintains its ultra-stable structural characteristics at both high temperature and pressure, it has been considered as an excellent model for studying protein folding. To initiate the structural and folding study of MTH1880 in proving its unusual stability, we performed the site directed mutagenesis and biochemical analysis of MTH1880 mutants. Data from circular dichroism and NMR spectroscopy suggest that the point mutations perturbed the structural stability of protein even though the secondary structure is retained. This study will provide the useful information in understanding the role of participating residues during folding-unfolding process and our result will be used in designing further folding experiments for hyper-thermopile proteins like MTH1880.

Influence of Cu and Ni on Ductile-Brittle Transition Behavior of Metastable Austenitic Fe-18Cr-10Mn-N Alloys (준안정 오스테나이트계 Fe-18Cr-10Mn-N 합금의 연성-취성 천이 거동에 미치는 Cu와 Ni의 영향)

  • Hwang, Byoungchul
    • Korean Journal of Materials Research
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    • v.23 no.7
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    • pp.385-391
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    • 2013
  • The influence of Cu and Ni on the ductile-brittle transition behavior of metastable austenitic Fe-18Cr-10Mn-N alloys with N contents below 0.5 wt.% was investigated in terms of austenite stability and microstructure. All the metastable austenitic Fe-18Cr-10Mn-N alloys exhibited a ductile-brittle transition behavior by unusual low-temperature brittle fracture, irrespective of Cu and/or Ni addition, and deformation-induced martensitic transformation occasionally occurred during Charpy impact testing at lower temperatures due to reduced austenite stability resulting from insufficient N content. The formation of deformation-induced martensite substantially increased the ductile-brittle transition temperature(DBTT) by deteriorating low-temperature toughness because the martensite was more brittle than the parent austenite phase beyond the energy absorbed during transformation, and its volume fraction was too small. On the other hand, the Cu addition to the metastable austenitic Fe-18Cr-10Mn-N alloy increased DBTT because the presence of ${\delta}$-ferrite had a negative effect on low-temperature toughness. However, the combined addition of Cu and Ni to the metastable austenitic Fe-18Cr-10Mn-N alloy decreased DBTT, compared to the sole addtion of Ni or Cu. This could be explained by the fact that the combined addition of Cu and Ni largely enhanced austenite stability, and suppressed the formation of deformation-induced martensite and ${\delta}$-ferrite in conjunction with the beneficial effect of Cu which may increase stacking fault energy, so that it allows cross-slip to occur and thus reduces the planarity of the deformation mechanism.

A METHOD FOR OPTIMUM LAYOUT DESIGN OF CONCRETE GRAVITY DAMS

  • A. Melih Yanmaz;Goktug Seckiner;Vehbi Ozaydin
    • Water Engineering Research
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    • v.2 no.4
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    • pp.199-207
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    • 2001
  • A computer-assisted desktop is developed for layout design of a concrete gravity dam on the basis of safety and economy. Using a set of regression equations, a dam layout is proposed. With reference to the regression equations and relevant input data, overall dam dimensions are determined by satisfying the stability criteria jointly under usual, unusual, and extreme loading conditions with the desired hydraulic conformity. Among several feasible alternatives, the program enables a designer to select the optimum layout, which corresponds to the minimum total cost of the structure. The method is applied to a case study to examine dimensions of proposed alternatives and to compare them with those of an existing dam.

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Effect of Polymerization Conditions on the Size Development of Nano-sized PPy (나노 사이즈 폴리파이롤의 합성 조건에 따른 크기 변화)

  • Kim, Hyemin;Park, Chong-Rae
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.10b
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    • pp.171-172
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    • 2003
  • Electrically conducting polymers have attracted a great deal of attention because of their unusual electronic Properties.1 One of them, polypyrrole has been widely studieddue to its high conductivity and good environmental stability. 2Especially polypyrrole nano-Particles and -fibers are interesting because of their unique properties and applications. Recently amorphous polypyrrole nano-particles were fabricated using microemulsion Polymerization at low temperature. (omitted)

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A new pitch-catch method for structural damage detection (구조손상 검출을 위한 새로운 Pitch-catch 기법)

  • Choi, Jung-Sik;Lee, U-Sik
    • Proceedings of the KSR Conference
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    • 2009.05a
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    • pp.148-151
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    • 2009
  • In these days it is important to secure the life and stability of the structure such as aircrafts, automobiles and building. So the structural health monitoring is needed. In conventional lamb wave techniques, damage is identified by comparing the measured data (baseline signals) and the current data. But this method can lead to high false signal in the intact condition of the structure due to environmental conditions of the structure. As a solution to resolve it, the structural health monitoring method which doesn't use baseline signals is necessary. Damaged structure has unusual elastic wave. This paper proposed a PC(pitch-catch) method which doesn't use baseline signal. New baseline signals can get from detection signal. Damage signals based on new baseline signals. This paper made an image includes damage information by applying damage-signals to beamformming.

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