• Title/Summary/Keyword: Unstable surface

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Preparation and Application of Nanofiltration Membranes (NF막 제조 및 응용공정)

  • 이규호;오남운;제갈종건
    • Proceedings of the Membrane Society of Korea Conference
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    • 1998.06a
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    • pp.135-153
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    • 1998
  • Nanofiltration (NF) is a recently introduced term in membrane separation. In 1988, Eriksson was one of the first authors using the word 'nanofiltration' explicitly. Some years before, FilmTech started to use this term for their NF50 membrane which was supposed to be a very loose reverse osmosis membrane or a very tight ultrafiltration membrane. Since then, this term has been introduced to indicate a specific boundary of membrane technology in between ultrafiltration and reverse osmosis. The application fields of the NF membranes are very broad as follows: Demeneralizing water, Cleaning up contaminated groundwater, Ultrapure water production, Treatment of effleunts containing heavy metals, Offshore oil platforms, Yeast production, Pulp and paper mills, Textile production, Electroless copper plating, Cheese whey production, Cyclodextrin production, Lactose production. The earliest NF membrane was made by Cadotte et al, using piperazine and trimesoyl chloride as monomers for the formation of polyamide active layer of the composite type membrane. They coated very thin interfacially potymerized polyamide on the surface of the microporous polysulfone supports. The NF membrane exhibited low rejections for monovalent anions (chloride) and high rejections for bivalent anions (sulphate). This membrane was called NS300. Some of the earliest NF membranes, like the NF40 membrane of FilmTech, the NTR7250 of Nitto-Denko and the UTC20 and UTC60 of Toray, are formed by a comparable synthesis route as the NS300 membrane. Commercially available NF membranes nowadays are as follows: ASP35 (Advanced Membrane Technology), MPF21; MPF32 (Kiryat Weizmann), UTC20; UTC60; UTC70; UTC90 (Toray), CTA-LP; TFCS (Fluid Systems), NF45; NF70 (FilmTec), BQ01; MX07; HG01; HG19; SX01; SX10 (Osmonics), 8040-LSY-PVDI (Hydranautics), NF CA30; NF PES 10 (Hoechst), WFN0505 (Stork Friesland). The typical ones among the commercially available NF membranes are polyamide composite membrane consisting of interfacially polymerized polyamide active layer and microporous support. While showing high water fluxes and high rejections of multivalent ions and small organic molecules, these membranes have relatively low chemical stability. These membranes have low chlorine tolerance and are unstable in acid or base solution. This chemical instability is appearing to be a big obstacle for their applications. To improve the chemical stability, we have tried, in this study, to prepare chemically stable NF membranes from PVA. The ionomers and interfacially polymerized polyamide were used for the modification of'the PVA membranes. For the detail study of the active layer, homogeneous NF membranes made only from active layer materials were prepared and for the high performance, composite type NF membranes were prepared by coating the active layer materials on microporous polysulfone supports.

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Meiobenthic Animals of the Tidal Flat Near the Yeonggwang Nuclear Power Plant (영광원전 주변 해역의 조간대 갯벌에 서식하는 중형저서생물)

  • Kim, Dong-Sung;Choi, Jin-Woo;Kang, Rae-Seon
    • Ocean and Polar Research
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    • v.23 no.2
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    • pp.109-119
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    • 2001
  • Meiobenthic community structure of tidal flats near the Yeonggwang Nuclear Power Plant have studied during summer (June) and fall (October) 1997. Examination of sediment samples collected along the transects showed that there were 18 different types of meiobenthos in the study area. The most abundant meiobenthic animals belonged to Phylum Nematoda in both seasons and all transects. However, sediment samples collected near discharge areas, transects A and B, showed relatively lower abundance than other general coastal areas. Another abundant meiobenthic organism is benthic Harpacticoids which is very sensitive to any environmental changes. Polycheats and Ostracods were next abundant meiobenthos which also showed the difference between the study area and other general coastal areas. Only transect C maintained similar meiobenthic abundance and diversity to other coastal areas. Horizontal distribution for transects A and B showed higher densities in upper and mid tidal flat zones. On the other hand, transect C which is located furtherest from the discharges showed an increasing trend in abundance from upper to lower areas. For size distribution analyses showed that animals which fit into the meshsize of 0.125 mm were abundant, Vertical distribution of meiobenthic animals within the sediments for both sampling seasons showed the highest individual numbers in the surface sediment layers of 0-1 cm depth and showed a decreasing trend as sediment gets deeper. Each class of meiobenthos had different vertical profiles. When comparing survey transects A and B with other similar tidal flat areas, this sites seems to a very unstable environment of tidal flats near the Yeonggwang Nuclear Power Plant.

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The Development of Image Processing System Using Area Camera for Feeding Lumber (영역카메라를 이용한 이송중인 제재목의 화상처리시스템 개발)

  • Kim, Byung Nam;Lee, Hyoung Woo;Kim, Kwang Mo
    • Journal of the Korean Wood Science and Technology
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    • v.37 no.1
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    • pp.37-47
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    • 2009
  • For the inspection of wood, machine vision is the most common automated inspection method used at present. It is required to sort wood products by grade and to locate surface defects prior to cut-up. Many different sensing methods have been applied to inspection of wood including optical, ultrasonic, X-ray sensing in the wood industry. Nowadays the scanning system mainly employs CCD line-scan camera to meet the needs of accurate detection of lumber defects and real-time image processing. But this system needs exact feeding system and low deviation of lumber thickness. In this study low cost CCD area sensor was used for the development of image processing system for lumber being fed. When domestic red pine being fed on the conveyer belt, lumber images of irregular term of captured area were acquired because belt conveyor slipped between belt and roller. To overcome incorrect image merging by the unstable feeding speed of belt conveyor, it was applied template matching algorithm which was a measure of the similarity between the pattern of current image and the next one. Feeding the lumber over 13.8 m/min, general area sensor generates unreadable image pattern by the motion blur. The red channel of RGB filter showed a good performance for removing background of the green conveyor belt from merged image. Threshold value reduction method that was a image-based thresholding algorithm performed well for knot detection.

Material Retention: A Novel Approach to Performance of Pigment Coating Colors (물질 보류 : 안료 코팅 처리를 위한 새로운 시도)

  • McKenzie, Ken;Rutanen, Anne;Lehtovuori, Jukka;Ahtikari, Jaana;Piilola, Teuvo
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2008.05a
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    • pp.47-70
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    • 2008
  • Cost efficiency is today the primary requirement in the paper and board industry. This has led therefore, to a greater preponderance of products with specifically designed functionality to take account of current industry needs. Continually increasing machine coating speeds together with these new coating colour components have put more emphasis on the importance of the correct rheology and water retention of the coating colours to achieve good runnability and end product quality. In the coating process, some penetration of the aqueous phase, to the base paper or board must occur to anchor the pre-coating to the base or the topcoat to the pre-coat. The aqueous phase acts as a vehicle not only for the binder, but also for the other components. If this water or material penetration is not controlled, there will be excessive material shift from the coating colour to the base, before immobilization of the coating colour will stop this migration. This can result in poor machine runnability, unstable system and uneven coating layer, impacting print quality. The performance of rheology modifiers or thickeners on the coating color have tended to be evaluated by the term, "water retention". This simple term is not sufficient to explain their performance changes during coating. In this paper we are introducing a new concept of "material retention", which takes note of the total composition of the coating colour material and therefore goes beyond the concept of only water retention. Controlled material retention leads to a more uniform z-directional distribution of coating colour components. The changes that can be made to z-directional uniformity will have positive effects on print quality as measured by surface strength, ink setting properties, print gloss, mottling tendency. Optical properties, such as light scattering, whiteness and light fastness delivery should also be improved. Additionally, controlled material retention minimizes changes to the coating colour with time in re-circulation giving less fluctuation in quality in the machine direction since it more closely resembles fresh coating for longer periods. Use of the material retention concept enables paper and board producers to have more stable runnability (i.e. lower process costs), improved end product quality (i.e. better performance of used chemicals) and/or optimized use of coating colour components (i.e. lower total formulation cost)

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Spatio-temporal Distributions of Macrobenthic Community on Subtidal Area around Mokpo, Korea (목포 주변 해역 조하대 저서동물 군집의 시 ${\cdot}$ 공간적 분포)

  • Lee, Jae-Hac;Choi, Jin-Woo;Park, Heung-Sik
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.5 no.2
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    • pp.169-176
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    • 2000
  • This study was carried out to clarify the spatial and temporal patterns of macrobenthic assemblages on the subtidal area around Mokpo, southwest of Korea. A total of 238 species and 663 ind./$m^{2}$ were collected. Polychaetes were the most abundant faunal group that comprised 88 species and had a mean density of 389 ind./$m^{2}$. In the semi-enclosed Youngsan River estuarine bay and neighbouring Mokpo Port area were composed of fine sediments with high organic content, and revealed large seasonal variations in the salinity of surface water and bottom dissolved oxygen in contrast to little seasonal changes in those parameters in the outer area. The study area was classified into four station groups by the cluster analysis; the harbor area, the offshore area, and the inner and outer estuarine bay. Two estuarine bay areas showed different species composition; the dominant species of inner bay were Tharyx sp., Poecilochaetus johnsoni, Heteromastus filiformis and other opportunistic species whereas those in the outer bay were Ruditapes philippinarum, Corophium sinense. From the environmental data and species composition of benthic community, the inner bay was characterized to have unstable benthic faunal assemblages, especially under the seasonal disturbance and receiving large amount of organic matter input and intermittant discharge of fresh water. The coastal developments around Mokpo city also seem to have stressed the subtidal communities spatio-temporally.

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The study on corrosion of the inner area of closed box-girder for unpainted weathering steel bridges (무도장 내후성 강 교량의 밀폐형 박스거더 내부의 부식에 대한 고찰)

  • Ma, Seung-Hwan;Noh, Young-Tai;Jang, Gun-Ik
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.4
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    • pp.2391-2400
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    • 2015
  • Weather proof steels are used for steel bridges due to its high corrosion resistance under atmospheric conditions. However, instead of forming stabilized rust layers, general rust occurs on weather proof steels under high humidity condition close to seawater or shady places. In Japan, therefore, they perform rust stabilization treatment instead of unpainted treatment due to severe atmospheric conditions. However, most of domestic weather proof steels were constructed unpainted in the form of closed box-girder, which makes the periodical repetition of dry and wet hard to occur. For the steel bridges constructed on the Han river, the evaporation of water, dew condensation due to temperature change, and stagnant water due to rain affect harmfully on the formation of passive film on weather proof steels. Thus, in this research, in order to analyze corrosion properties inside the closed box-girder for the unpainted weather proof steel bridge in the waterworks safety zone, multiple ways of analysis such as observation with eyes, cellophane-tape test, steel thickness measurement, surface corrosion potential measurement, electron microscope analysis, and X-ray diffraction analysis of the rust were performed. As a result, unstable rust layer was observed inside the closed box-girder, and severe corrosion was observed on the top and bottom of the flanges due to the effects of stagnant water caused by rain, dew condensation, and de-icing materials.

Correlation of Tectolineaments and Discontinuities in connection with Slope Failure (사면 붕괴와 관련 구조선 분석과 불연속면의 상관성 연구)

  • Baek, Yong;Koo, Ho-Bon;Kim, Seung-Hyun
    • The Journal of Engineering Geology
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    • v.11 no.3
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    • pp.303-313
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    • 2001
  • A cut-slope near Guam-Ri Hwado-Eup Namyangju-Si Kyunggi-Do collapsed during a heavy rainfall over 400mm at 28th of August 2000. The cut-slope collapse reportedly developed mainly by block sliding along a set of discontinuities, although slope angle of the cut-slope was 40$^{\circ}$(1:1.2) that agrees with the road construction criteria. This study aims to analyze differences and correlations among several data-collecting methods limited to discontinuity analysis related with cut-slope collapse. This study started with analysing discontinuity surface characteristics, geology of the country rock and orientations of the discontinuities directly related with the collapse. Analysis of aerial photos around the study area provided regional lineament data, and discontinuity plane description and measurements were collected from core logging and Borehole Image Processing System (BIPS). Spearmans correlation ranking coefficient method was used to get correlation of discontinuity planes according to analysis methods. The result suggests that the correlation coefficient is ${\gamma}_s$ = 0.91 Plus, stability analysis of discontinuity plane orientation data using equal-area stereonet revealed that the study area is unstable to planar failure. This study suggests that the cut-slope angles currently applied should be shallower and that significant attention is required to orientation distribution of discontinuities existed in cut-slopes studies.

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Production of Single-Cell Protein on Petroleum Hydrocarbon -V. Recovery and Purification of the Yeast Cell and Its Preliminary Animal Feeding Test- (석유탄화수소를 이용한 단세포단백질의 생산에 관한 연구 -V. 균체의 회수, 정제 및 예비 동물사육 시험-)

  • Pyun, Yoo-Ryang;Kwon, Tai-Wan;Chee, Kew-Mahn;Kim, Chun-Su
    • Korean Journal of Food Science and Technology
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    • v.4 no.4
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    • pp.252-258
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    • 1972
  • Methods of separating yeast cells from oil-water-cell emulsion and subsequent purification of the recovered yeast have been studied. In addition, the results of preliminary feeding experiments in which a yeast grown on gas oil was incorporated into chick rations are reported. According to the present study, it appears that the recovery of the yeasts would be easier at pH 9, since the emulsion is relatively more unstable. A class of surface active agent at a concentration of 0.3% was found to facilitate the separation of the yeast from the emulsion. The use of electrolytes such as NaCl and KCl were found to be most effective in breaking the emulsion. Solvent treatment using iso-propyl alcohol and its azeotropic mixture with hexane at $58^{\circ}C$ are particularly suitable for purification of the yeast. In the feeding experiment it was found that 5 percent of the fishmeal in the control ration could be replaced by the yeast with no adverse effect on performance. However, when 8 percent of the fish meal in the control ration was replaced by the yeast, some effect on live-weight gain of the chicks was observed.

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Generation of Longitudinal Twin of GaAs Single Crystal by LEC Method (LEC법 GaAs 단결정의 종단쌍정 발생)

  • Gang, Jin-Gi;Yu, Hak-Do;Park, Jong-Mok
    • Korean Journal of Crystallography
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    • v.2 no.1
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    • pp.1-11
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    • 1991
  • When GaAs single crystals are grown by LEC method, a serious problem is that longitudinal twins are often generated. the growth axis is changed from (100) to (221) direction by logitudinal twin. In this experiment, 3 inch GaAs single crystals, slaving (100) uonh axis, were von by LEC method. Striations and edge facets generated during crystal growth, were observed by SPW photo-etching. Relationship between striations and edge facets was studied. Instability of their generation was the cause of goneration of longitudinal twins. The shape of striations was changed with the growth conditions such as crystal diameter and melt volume. In the region of crystal edge: there was the microscopic fluctuation by the instability of melt convection. Edge facets consisting of {111} plane developed well in the region which striation were convex to the melt. Because the angle between striation and {111} edge facet decreased in that region. Longitudinal twins were generated on the crystal surface at the <111> direction which is perpendicular to the growth axis. These were generated by unstable melt convection and propagated in the crystal as crystal grew. Longitudinal twins were generated when regrowth rate was very fast after {111} edge facets were remelted. So, in order to supress the generation of longitudinal twin, abrupt change of melt convection must be prohibited.

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A Biomechanical Comparative Analysis of the Multi-Radius Total Knee Arthroplastry System for Go up Stair and Go down Stair (계단 오르기와 내리기 동안 다축범위(multi-radius) 무릎인공관절 수술자의 운동역학적 비교분석)

  • Jin, Young-Wan;Yoo, Byung-In;Kawk, Yi-Sub
    • Korean Journal of Applied Biomechanics
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    • v.16 no.1
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    • pp.31-41
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    • 2006
  • The primary purpose of a TKA is to restore normal knee function Therefore, ideally, a TKA should: (a) maintain the natural leverage of the knee joint muscles to ensure generating adequate knee muscle moments to accomplish daily tasks such as rising from climbing stairs; (b) provide adequate knee joint stability. A 16-channel MyoResearch XP EMG system was used to collect the differential input surface electromyography signals VM, VL, RF, BF, ST during climbing/descending stair tests. A Peak Motion Measurement System was used to collect the kinematic and kinetic data. AKIN-COM Ill isokinetic dynamometer was used for EMG of VM, VL, RF, BF and ST during maximal voluntary contraction. I Quadriceps EMG results for the VM of the passed 1year group limb demonstrated significant less RMS EMG than that of the passed 3year group limb $60^{\circ}-15^{\circ}$ of knee flexion(p<0.05). The VL of the passed 1year group limb also demonstrated significants less RMS EMG than that of the passed 3year group limb from $60^{\circ}-45^{\circ}$ of knee flexion(p<0.05). Similar to the VM and VL, the RF of the passed 1year group limb showed less RMS EMG than that of the passed 3year group limb from $60^{\circ}-30^{\circ}$ do knee flexion(p<0.05). Hamstring EMG results for the BF of the passed 1year group limb demonstrated less RMS EMG than that of the passed 3year group limb from $75^{\circ}-15^{\circ}$ of knee flexion(p<0.05). The passed 1year group limb tended to have less ADD displacement(p<0.071) than that of the passed 3year group limb. There was no significant difference of the ABD displacement between the passed 1year group and the passed 3year group limbs(p<0.73). The passed 3year group used compensatory adaptation movement strategies to compensate for the strength deficit of passed 3year group limbs. The passed 3year group limb also increased the quadriceps muscle activation level to produce more knee extension moment to compensate for the short quadriceps moment arm. The passe 3year group limb might have an unstable knee joint in the medio-Iateral direction during the climbing/descending by showing a tendency of more ADD displacement and greater hamming co-activation EMG than the passed 1year group limbs. The TKA design was not able to help the knee joint to produce adequate knee extension moment with less quadriceps muscle effort. I think that old man needs continuous exercise for muscle strength.