• Journal of Electrochemical Science and Technology
• /
• v.10 no.1
• /
• pp.55-60
• /
• 2019

Herein, the effect of counter anions on the formation of a solid electrolyte interphase (SEI) in a propylene carbonate (PC)-based electrolyte solution was investigated. Although the reversible capacities were different, reversible intercalation and de-intercalation of lithium ions occurred in the graphite negative electrode in the PC-based electrolyte solutions containing 1 M $LiClO_4$, $LiPF_6$, $LiBF_4$, and $LiCF_3SO_3$ at low temperature ($-15^{\circ}C$). This indicated that the surface films acted as an effective SEI to suppress further co-intercalation and decomposition reactions at low temperature. However, the SEIs formed at the low temperature were unstable in 1 M $LiPF_6$ and $LiBF_4/PC$ at room temperature ($25^{\circ}C$). On the other hand, increasing reversible capacity was confirmed in the case of $LiCF_3SO_3/PC$ at room temperature, because the SEI formed at the low temperature was still maintained. These results suggest that counter anions are an important factor to consider for the formation of effective SEIs in PC-based electrolyte solutions.

• Steel and Composite Structures
• /
• v.31 no.2
• /
• pp.187-199
• /
• 2019

This paper presents the semi-analytical development of the dynamic instability behavior and the dynamic response of functionally graded (FG) cylindrical shallow shell panel subjected to different type of periodic axial compression. First, in prebuckling analysis, the stresses distribution within the panels are determined for respective loading type and these stresses are used to study the dynamic instability behavior and the dynamic response. The prebuckling stresses within the shell panel are the same as applied in-plane edge loading for the case of uniform and linearly varying loadings. However, this is not true for the case of parabolic loadings. The parabolic edge loading produces all the stresses (${\sigma}_{xx}$, ${\sigma}_{yy}$ and ${\tau}_{xy}$) within the FG cylindrical panel. These stresses are evaluated by minimizing the membrane energy via Ritz method. Using these stresses the partial differential equations of FG cylindrical panel are formulated by applying Hamilton's principal assuming higher order shear deformation theory (HSDT) and von-$K{\acute{a}}rm{\acute{a}}n$ non-linearity. The non-linear governing partial differential equations are converted into a set of Mathieu-Hill equations via Galerkin's method. Bolotin method is adopted to trace the boundaries of instability regions. The linear and non-linear dynamic responses in stable and unstable region are plotted to know the characteristics of instability regions of FG cylindrical panel. Moreover, the non-linear frequency-amplitude responses are obtained using Incremental Harmonic Balance (IHB) method.

• The Journal of Engineering Geology
• /
• v.30 no.4
• /
• pp.497-514
• /
• 2020

This study investigated the causes of large-scale ground subsidence in the upper part of mining cavities of the Samdo limestone mine, Samcheok city, Gangwondo, Korea. Geological and electrical resistivity surveys were undertaken on the collapsed slope of the mountain and in the mine tunnel where subsidence occurred, with geotechnical evaluations and numerical analysis. It is concluded that wide mining cavities, with irregular pillars in unstable rock masses hosting discontinuities, weathered over time, resulting in subsidence occurring along a fault plane due to increasing ground stress.

• Journal of the Korean Orthopaedic Association
• /
• v.55 no.2
• /
• pp.178-182
• /
• 2020

Isolated fractures of lower sacrum are commonly treated conservatively in most cases because of low energy damage and stable fracture. However, surgical treatment is required in displaced unstable fracture. But the surgical technique is not established and even case reports are not common. We reported a case of displaced transverse fracture of the lower sacrum that was treated with an open reduction and dual plate fixation.

• 제어로봇시스템학회:학술대회논문집
• /
• 1991.10b
• /
• pp.1659-1663
• /
• 1991

A new control design methodology is presented here which is based on a nonlinear time-series reference model. It is indicated by highly nonlinear simulations that such designs successfully stabilize troublesome aircraft maneuvers undergoing large changes in angle of attack as well as large electric power transients due to line faults. In both applications, the nonlinear controller was significantly better than the corresponding linear adaptive controller. For the electric power network, a flexible a.c. transmission system (FACTS) with series capacitor power feedback control is studied. A bilinear auto-regressive moving average (BARMA) reference model is identified from system data and the feedback control manipulated according to a desired reference state. The control is optimized according to a predictive one-step quadratic performance index (J). A similar algorithm is derived for control of rapid changes in aircraft angle of attack over a normally unstable flight regime. In the latter case, however, a generalization of a bilinear time-series model reference includes quadratic and cubic terms in angle of attack. These applications are typical of the numerous plants for which nonlinear adaptive control has the potential to provide significant performance improvements. For aircraft control, significant maneuverability gains can provide safer transportation under large windshear disturbances as well as tactical advantages. For FACTS, there is the potential for significant increase in admissible electric power transmission over available transmission lines along with energy conservation. Electric power systems are inherently nonlinear for significant transient variations from synchronism such as may result for large fault disturbances. In such cases, traditional linear controllers may not stabilize the swing (in rotor angle) without inefficient energy wasting strategies to shed loads, etc. Fortunately, the advent of power electronics (e.g., high-speed thyristors) admits the possibility of adaptive control by means of FACTS. Line admittance manipulation seems to be an effective means to achieve stabilization and high efficiency for such FACTS. This results in parametric (or multiplicative) control of a highly nonlinear plant.

• Journal of Hydrogen and New Energy
• /
• v.28 no.1
• /
• pp.106-112
• /
• 2017

The present study describes flow induced noise generated from a ball valve used for a gas pipeline. Noise generation from a ball valve mainly induces by interference between unstable(or fluctuating) leakage flow and pipe wall when the ball valve is working closed or opened. To measure the positions of the noise source and the amplitude of noise with respect to measuring frequencies, a commercial acoustic camera is introduced. Noise characteristics generated by the ball valve have been performed by four valve opening rates: 30, 50, 70 and 100 percents. It is noted that 100 percent opening rate means that the valve is fully opened. Throughout the experimental measurements using the acoustic camera, the location of the noise source and the noise amplitude with respect to the frequencies for the test ball valve are clearly evaluated. It is found that the dominant frequencies come from the fluctuating flow at the downstream of the ball valve for four opening rates are observed between 3,000Hz and 3,200Hz. Maximum noise amplitude comes from the ball valve reaches 75dB at the valve opening rate of 50 percent.

• Composites Research
• /
• v.16 no.4
• /
• pp.44-50
• /
• 2003

The damage zone around a crack tip occurring before the fracture is a significant domain. which affects the toughening mechanism of materials. In this study. the growth process of damage zone in the vicinity of crack tip for rubber-modified epoxy resin is investigated using an acoustic emission(AE) analysis. The weight fractions of rubber(CTBN 1300$\times$B) in rubber-modified epoxy resin are 5 wt% and 15 wt%. The fracture toughness($K_{IC}$) and the fracture energy($G_{IC}$) were measured using 3 point bending single-edge notched specimens. The damage zone and rubber particles distributed around the crack tip were observed by a polarized optical microscope and an atomic force microscope(AFM). The damage zone around crack tip of rubber-modified epoxy resin was formed at 13 % loading and developed until 57 % loading of the fracture load. The crack initiated at 57 % loading grew repeatedly in the stick-slip propagation behavior. Based on time-frequency analysis, it was confirmed that AE signals with frequency bands of 0.15~0.20 MHz and 0.20~0.30 MHz were generated from cavitation and stable/unstable cracking inside the damage zone.

• Tribology and Lubricants
• /
• v.36 no.3
• /
• pp.153-160
• /
• 2020

In this paper, we present a hydrostatic bearing design and rotordynamic analysis of a pump-and-drive turbine module for a 250-kW supercritical CO₂ cycle application. The pump-and-drive turbine module consists of the pump and turbine wheel, assembled to a shaft supported by two hydrostatic radial and thrust bearings. The rated speed is 21,000 rpm and the rated power is 143 kW. For the bearing operation, we use high-pressure CO₂ as the lubricant, which is supplied to the bearing through the orifice restrictor. We calculate the bearing stiffness and flow rate for various orifice diameters, and then select the diameter that provides the maximum bearing stiffness. We also conduct a rotordynamic analysis based on the design parameters of the pump-and-drive turbine module. The predicted Campbell diagram shows that there is no critical speed below the rated speed, owing to the high stiffness of the bearings. Furthermore, the predicted damping ratio indicates that there is no unstable mode. We conduct the operating tests for the pump and drive turbine modules within the supercritical CO₂ cycle test loop. The pressurized CO₂, at a temperature of 136℃, is supplied to the turbine and we monitor the shaft vibration during the test. The test results show that there is no critical speed below the rated speed, and the shaft vibration is controlled to below 3 ㎛.

• Polymer(Korea)
• /
• v.34 no.3
• /
• pp.220-225
• /
• 2010

The optical properties and dimensional stability of polyethersulfone(PES) retardation film have been studied as function of chain orientation and the temperature applied to PES retardation film. It was confirmed that the appropriate retardation values of $R_e$ and $R_{th}$ for the retardation film application were able to obtain by the chain orientation and these values could be controlled by the chain relaxation through the thermal annealing process. It was found that unstable $R_e$ and $R_{th}$ values were shown by the repeated cooling and heating applied to the retardation films but this could be stabilized by means of the annealing process after stretching of PES film. The dimensional shrinkage due to the chain orientation was found as temperature increase and the intrinsic thermal expansion of PES appeared after shrinking. The shrinkage of PES films affected by the chain orientation and thermal annealing dramatically but the effect on the coefficient of thermal expansion was found to be negligible.

• Journal of Energy Engineering
• /
• v.10 no.4
• /
• pp.363-369
• /
• 2001

Process design and performance evaluation were made for medium-size gasification combined/cogeneration plant. Based on the designed plant process configuration, the effects of $NO_x$ reduction techniques on the $NO_x$ emission, the power output, the efficiency and the stability of plant are investigated by applying various $NO_x$ reduction methods such as unsaturated/saturated nitrogen injection and fuel saturation of gas turbine combustor. The $NO_x$ reduction by nitrogen injection is more remarkable than that by fuel saturation, and its effect can be more enhanced by using saturated nitrogen. In addition, the applications of $NO_x$ reduction techniques accompany the improvement of plant power output and efficiency with the decrease of $NO_x$ emission, while it can cause unstable gas turbine operation.