• 제목/요약/키워드: Unsaturated polyester

검색결과 184건 처리시간 0.03초

폴리우레탄 액상고무를 이용한 불포화 폴리에스테르 모르터의 인성개선에 관한 실험 연구 (An Experimental Study on Toughening of Unsaturated Polyester Mortar Using Polyuretane Liquid Rubber)

  • 박준철;배근철;박준호;최영준;김화중
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2001년도 봄 학술발표회 논문집
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    • pp.371-376
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    • 2001
  • The purpose of this study is to investigate toughening of unsaturated polyester resin by addition of polyuretane liquid rubber. In general, unsaturated polyester resin has strong brittleness in spite of its high strength Therefore; it is difficult to use unsaturated polyester mortar for the place where impact resistance is demanded. In this study, it was evaluated strength and Gf by using to polyurethane liquid rubber. As a result, the toughness of unsaturated polyester mortar was increased by polyuretane liquid rubber.

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혈암을 잔골재로 사용한 불포화 폴리에스터 모르터의 특성 (Properties of Unsaturated Polyester Mortar Using Shale as Fine Aggregates)

  • 박준철;배근철;최영준;서인식;김화중;김영수
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2001년도 가을 학술발표회 논문집
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    • pp.129-134
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    • 2001
  • The purpose of this study is to investigate properties of unsaturated polyester mortar using the shale as find aggregates. To evaluate properties of unsaturated polyester mortar using crushed sand from Black shale, Red shale, Gray shale, we peformed the experiment according the F/B ratio of 25, 30, 35% and the volume of fine aggregate of 50, 53, 56%. The Result of this study is as follows. the strength of unsaturated polyester mortar is higher than those of river sand. The F/B ratio is higher and the volume of find aggregate is lower, the strength of unsaturated polyester mortar is higher

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MMA 개질 불포화 폴리에스터 모르타르의 강도 특성 (Strength Properties of MMA-Modified Unsaturated Polyester Mortar)

  • 연규석;조규우;최종윤;정중호
    • 한국농공학회:학술대회논문집
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    • 한국농공학회 2003년도 학술발표논문집
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    • pp.379-382
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    • 2003
  • In this study, methyl methacrylate (MMA)- modified unsaturated polyester mortar, in which the MMA was added to the unsaturated polyester resin, was developed for improving the early-age strength and the workability of the conventional polymer concrete, binder of which was the unsaturated polyester resin. Then the strength properties of the MMA-modified unsaturated polyester mortar were surveyed. The experimental results showed that early-age strength was greater when the MMA contents were increased in the range of $20{\sim}40%$, but the strength rather showed a tendency of decrease when the MMA contents was 50%.

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CNT 강화 불포화 폴리에스터 복합재료의 수분흡수 거동에 관한 연구 (Moisture Absorption Behavior of CNT Reinforced Unsaturated Polyester Composites)

  • 박지혜;윤성호
    • 한국추진공학회:학술대회논문집
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    • 한국추진공학회 2011년도 제37회 추계학술대회논문집
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    • pp.536-538
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    • 2011
  • 본 연구에서는 노출온도와 노출시간에 따른 CNT 강화 불포화 폴리에스터 복합재의 수분흡수 거동을 조사하고 흡수된 수분이 인장특성에 미치는 영향을 평가하였다. 이때 노출온도는 $25^{\circ}C$$75^{\circ}C$의 두 경우를 고려하였으며, 노출시간은 600시간까지를 고려하였다. 연구결과에 따르면 수분흡수율은 CNT의 함량과 노출온도가 높을수록 크게 나타났으며, 또한 인장강도는 CNT가 함유된 경우 CNT의 보강효과로 인해 노출시간에 따른 인장강도의 감소가 낮게 나타났다.

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UV 경화가 비닐에스터와 불포화폴리에스터 블랜드 시스템의 물성 특성에 미치는 영향 (Effect of Radiation Intensity on Mechanical Properties of UV-cured Vinylester/Unsaturated Polyester Blend System)

  • Lee, Jae-Rock;Kim, Young-Mi;Park, Soo-Jin
    • 한국복합재료학회:학술대회논문집
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    • 한국복합재료학회 2002년도 추계학술발표대회 논문집
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    • pp.269-272
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    • 2002
  • UV curing technology becomes important in various sectors of applications due to the high efficiency, environmental protection, and saving of energy. The effect of different proportion of vinylester (VE) and unsaturated polyester (UP) for VE/UP blend system was investigated in context of mechanical properties. The compositions of VE/UP blend were varied within 0:100, 20:80, 40:60, 60:40, 80:20, and 100:0 by weight percent. 1 wt% 1-hydroxy-cyclohexyl-phenyl-ketone was used as photoinitiator. The used intensity of UV light was in the range of $40~70 mW/\textrm{cm}^2$. The flexural strength of vinylester was not sensitive to the intensity of UV light. But the unsaturated polyester was very sensitive to the intensity of UV light. The flexural strength of vinylester was always superior to that of unsaturated polyester. The addition of the vinylester increased the flexural strength of blend system.

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Fabrication and Electrical, Thermal and Morphological Properties of Novel Carbon Nanofiber Web/Unsaturated Polyester Composites

  • Kim, Seong-Hwan;Kwon, Oh-Hyeong;Cho, Dong-Hwan
    • Carbon letters
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    • 제11권4호
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    • pp.285-292
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    • 2010
  • Novel unsaturated polyester composites with PAN-based nanofiber, stabilized PAN nanofiber, and carbonized nanofiber webs have been fabricated, respectively, and the effects of the nanofiber web content on their electrical resistivity, the thermal stability, dynamic storage modulus, and fracture surfaces were studied. The result demonstrated that the introduction of just one single layer (which is corresponding to 2 wt.%) of the carbonized nanofiber web to unsaturated polyester resin (UPE) could contribute to reducing markedly the electrical resistivity of the resin reflecting the percolation threshold, to improving the storage modulus, and to increasing the thermal stability above $350^{\circ}C$. The effect on decreasing the resistivity and increasing the modulus was the greatest at the carbonized PAN nanofiber web content of 8 wt.%, particularly showing that the storage modulus was increased about 257~283% in the measuring temperature range of $-25^{\circ}C$ to $50^{\circ}C$. The result also exhibited that the carbonized PAN nanofibers were distributed uniformly and compactly in the unsaturated polyester, connecting the matrix three-dimensionally through the thickness direction of each specimen. It seemed that such the fiber distribution played a role in reducing the electrical resistivity as well as in improving the dynamic storage modulus.

불포화 폴리에스테르 모르터의 인성강화에 관한 실험 연구 (An Experimental Study on Toughening of Unsaturated Polyester Mortar)

  • 김화중;박준철;윤명덕;윤요현;최영준
    • 한국콘크리트학회:학술대회논문집
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    • 한국콘크리트학회 2000년도 가을 학술발표회 논문집(II)
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    • pp.1115-1120
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    • 2000
  • The purpose of this study is to investigate toughening of unsaturated polyester resin by addition of liquid rubber. In general, unsaturated polyester liquid has strong brittleness in spite of if high strength Therefore; it is difficult use polyurethane liquid rubber for the place where impact resistance is demanded. In this study, it was evaluated strength, impact resistance and fracture toughness by adding to polyurethane liquid rubber(0~25%). As a result, it was found that a tendency to be increase bearing impact and fracture toughness as polyurethane liquid rubber increased but strength was decreased.

Preparation of Unsaturated Polyester-based Hybrid Gel-Coats Containing Urethane Acrylate and Their Coating Performance

  • Kim, Ji-Hee;Baek, Seung-Suk;Kim, Oh Young;Park, Dong Hyup;Hwang, Seok-Ho
    • Elastomers and Composites
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    • 제54권3호
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    • pp.247-251
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    • 2019
  • Two different urethane acrylates (mono-acrylate and di-acrylate) were used to prepare unsaturated polyester-based hybrid gel-coats. The physical properties and surface characteristics of these gel-coats were investigated on the basis of the content and type of urethane acrylate. The set-to-touch time increased and the physical properties (surface hardness and tensile strength) decreased with an increase in the urethane acrylate content. However, the type of urethane acrylate did not affect these parameters. It was found that the optimal urethane acrylate content for the application of unsaturated polyester-based hybrid gel-coats is ~10 wt%.

성숙도 방법을 이용한 불포화 폴리에스터 수지 폴리머 콘크리트의 압축강도 예측 (Prediction of Compressive Strength of Unsaturated Polyester Resin Based Polymer Concrete Using Maturity Method)

  • 최기봉;김남길;이윤수;연규석
    • 한국농공학회논문집
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    • 제59권6호
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    • pp.19-27
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    • 2017
  • This study investigated to predict the compressive strength of unsaturated polyester resin based polymer concrete using the maturity method. The test results show that the development of the compressive strength increased exponentially until an age of 24 hours. After 24 hours, the development of the compressive strength just increased gradually. This test result shows that the strength of unsaturated polyester resin based polymer concrete was developed mainly at the early age. Estimated datum temperature of unsaturated polyester resin based polymer concrete was $-20.67^{\circ}C$ which was much lower than of datum temperature ($-10^{\circ}C$) of Portland cement concrete. Also, this study result shows that the existing maturity index associated with Portland cement concrete was not applicable for polymer concrete because curing time of Portland cement concrete is different clearly with curing time of polymer concrete. The cause of different curing time was that there were different curing mechanisms between Portland cement concrete and polymer concrete. In order to best apply the experimental data to a model, CurveExpert Professional, the commercial software, was used to determine the predictive model regarding the compressive strength of unsaturated polyester resin based polymer concrete. As a result, Gompertz Relation or Weibull Model was an appropriate model as a predictive model. The proposed model can be used to predict the compressive strength, especially, it is more useful when the maturity is in the range between $40^{\circ}C{\cdot}h^{0.4}$ and $900^{\circ}C{\cdot}h^{0.4}$.

섬유강화 복합재료의 물성향상을 위한 몰비가 다른 매트릭스 수지에 관한 연구 (Matrix Resin Systems with Different Molar Ratios to Improve the Properties of Fiber-reinforced Composites)

  • 이상효;이장우
    • 폴리머
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    • 제24권4호
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    • pp.459-468
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    • 2000
  • 유리 또는 아라미드 섬유를 보강재로 사용한 섬유강화 복합재료의 기계적 물성을 증진시키기 위하여 복합재료 적층판을 서로 다른 매트릭스 수지와 섬유를 선정하여 이들의 인장, 굴곡 특성을 조사하였다. 불포화 폴리에스테르와 개질된 표면의 아라미드 섬유 복합재료의 경우, 굴곡 물성의 최대값은 실란 농도가 0.5 wt%일 때 관찰되었다. 불포화 폴리에스테르 수지와 유리섬유 복합재료의 인장 물성은 vinylester계가 가장 높게 나타났으며, 굴곡물성은 isophthalic계가 가장 높은 물성을 나타내었다. 유리섬유와 불포화 폴리에스테르 수지 복합재료의 기계적 물성을 증진시키기 위해 겹침 적층판과 기계적 물성과의 상관 관계에 대해서도 연구가 병행되었다.

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