• Title/Summary/Keyword: Unsaturated Polyester resin

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An Experimental Study on the Mechanical Properties of Permeable Polymer Concrete (투수용 폴리머 콘크리트의 역학적 특성에 관한 실험적 연구)

  • 성찬용
    • Magazine of the Korean Society of Agricultural Engineers
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    • v.38 no.5
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    • pp.95-105
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    • 1996
  • This study was performed to evaluate the mechanical properties of permeable polymer concrete using fillers and unsaturated polyester resin. The following conclusions were drawn; 1. The unit weight was in the range of 1, 663~ l, 892kg/$cm^3$, the weights of those concrete were decreased 18~28% than that of the normal cement concrete. 2. The highest strength was achieved by fly ash filled permeable polymer concrete, it was increased 22% by compressive strength, 190% by tensile strength and 192% by bending strength than that of the normal cement concrete, respectively. 3. The external strength of permeable pipe was in the range of 3, 083~3, 793kg/m, the external strengths of those concrete were increased 2~26% than that of the normal cement concrete. Accordingly, these permeable polymer concrete pipe can be used to the members and structures which need external strength. 4. The static modulus of elasticity was in the range of $5.7{\times} 10^4 ~ 15.4{\times} 10{^4}kg/cm^2 $, which was approximately 35~64% of that of the normal cement concrete. Fly ash filled permeable polymer concrete was showed relatively higher elastic modulus. The poisson's number of permeable polymer concrete was less than that of the normal cement concrete. 5. The dynamic modulus of elasticity was in the range of $83{\times} 10^3 ~ 211{\times} 10{^3}kg/cm^2 $, which was approximately Ins compared to that of the normal cement concrete. Fly ash filled permeable polymer concrete was showed higher dynamic modulus. The dynamic modulus of elasticity were increased approximately 22~45% than that of the static modulus. 6. The ultrasonic pulse velocity was in the range of 2, 584 ~ 3, 587m/sec, . which was showed about the same compared to that of the normal cement concrete. Fly ash filled permeable polymer concrete was in the range of$0.58~8.88 {\ell}/cm^2/hr$, , and it was larglely dependent upon the mixing ratio. These concrete can be used to the structures which need water permeability.

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Comparison of Geogrid Bonding Methods under Asphalt Overlay Layer for Reflection Cracking Retardation (아스팔트 덧씌우기 하부의 Geogrid 부착방법에 따른 반사균열 지연특성 비교)

  • Doh, Young-Soo;Kim, Bun-Chang;Ko, Tae-Young;Kim, Kwang-Woo
    • International Journal of Highway Engineering
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    • v.7 no.4 s.26
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    • pp.9-20
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    • 2005
  • This study was carried out to select most efficient bonding methods of geogrid at the interface of old concrete pavement before placing asphalt overlay layer for reflection cracking retardation. Three bonding methods, a RSC-4 emulsified asphalt, a compound and an unsaturated polyester resin (UPR) were compared in this study. Three types of asphalt mixture (AC 60-80, RLDPE 8%, PG 76-22) and a dense-graded aggregate were used for overlay asphalt pavement. A reinforcing material which consists of a woven fabric underneath a glass fiber grid was used. An expedite test method which is for simulating mixed mode (mode I and II) fracture test was performed using a wheel tracker in laboratory. Cracking development by load repetition was measured as fatigue life (number of load cycle) and expansion of specimen body were measured for each test specimen. The results showed that UPR was the best and RSC-4 the next. But considering field applicability, RSC-4 was considered as an appropriate choice for bonding reinforcing material.

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Hardening properties in MMA monomer using UP and EPS in addition hardener (경화제의 첨가에 따른 UP와 EPS 혼입 MMA 수지의 경화특성)

  • Lee, Jung-Hui;Song, Hun;Chu, Yong-Sik;Lee, Jong-Kyu
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.445-448
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    • 2008
  • The unsaturated polyester(UP) and epoxy resin have a superior material properties and a chemical resistance using sewerage pipes rehabilitation. However, UP and epoxy have not a low temperatures harding, the requirement $8{\sim}11$ hours long times harding and heating system used by reinforcement liner. This study is to evaluate the effects of low temperature harding properties methyl methacrylate(MMA) monomer using expanded polystyrene(EPS) and UP in addition of initiator and promoters. From the test result, viscosity tends to increase with increasing EPS and UP contents. However, harding time change of the MMA resins which it follows in addition of the initiator and promoter.

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Property improvement of natural fiber-reinforced green composites by water treatment

  • Cho, Dong-Hwan;Seo, Jeong-Min;Lee, Hyun-Seok;Cho, Chae-Wook;Han, Seong-Ok;Park, Won-Ho
    • Advanced Composite Materials
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    • v.16 no.4
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    • pp.299-314
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    • 2007
  • In the present study, natural fibers (jute, kenaf and henequen) reinforced thermoplastic (poly(lactic acid) and polypropylene) and thermosetting (unsaturated polyester) matrix composites were well fabricated by a compression molding technique using all chopped natural fibers of about 10 mm long, respectively. Prior to green composite fabrication, natural fiber bundles were surface-treated with tap water by static soaking and dynamic ultrasonication methods, respectively. The interfacial shear strength, flexural properties, and dynamic mechanical properties of each green composite system were investigated by means of single fiber microbonding test, 3-point flexural test, and dynamic mechanical analysis, respectively. The result indicated that the properties of the polymeric resins were significantly improved by incorporating the natural fibers into the resin matrix and also the properties of untreated green composites were further improved by the water treatment done to the natural fibers used. Also, the property improvement of natural fiber-reinforced green composites strongly depended on the treatment method. The interfacial and mechanical results agreed with each other.

Strengths and Permeability Properties of Porous Polymer Concrete for Pavement with Different Fillers (충전재 종류에 따른 포장용 포러스 폴리머 콘크리트의 강도 및 투수 특성)

  • Kim, Young-Ik;Sung, Chan-Yong
    • Journal of The Korean Society of Agricultural Engineers
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    • v.49 no.4
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    • pp.51-59
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    • 2007
  • Recently, concrete has been made porous and used for sound absorption, water permeation, vegetation and water purification according to void characteristics. Many studies are carried out on the utilization of sewage sludge, fly ash and waste concrete to reduce the environmental load. This study was performed to evaluate the void, strength, relationship between void and strength, permeability and chemical resistance properties of porous polymer concrete for pavement with different fillers. An unsaturated polyester resin was used as a binder, crushed stone and natural sand were used as an aggregate and bottom ash, fly ash and blast furnace slag were used as fillers. The mix proportions were determined to satisfy the requirement for the permeability coefficient, $1{\times}10^{-2}$ cm/s for general permeable cement concrete pavement in Korea. The void ratios of porous polymer concrete with fillers were in the range of $18{\sim}23%$. The compressive strength and flexural load of porous polymer concrete with fillers were in the range of $19{\sim}22$ MPa and $18{\sim}24$ KN, respectively. The permeability coefficients of porous polymer concrete with fillers were in the range of $5.5{\times}10^{-1}{\sim}9.7{\times}10^{-2}$ cm/s. At the sulfuric acid resistance, the weight reduction ratios of porous polymer concrete immersed during 8-week in 5% $H_{2}SO_{4}$ were in the range of $1.08{\sim}3.56%$.

Hardening properties of MMA Monomer Using EPS in addition of Initiator and Promoter (개시제 및 촉진제의 첨가에 따른 EPS 혼입 MMA 수지의 경화특성)

  • Lee, Jung-Hui;Song, Hun;Chu, Yong-Sik;Lee, Jong-Kyu
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.929-932
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    • 2008
  • The unsaturated polyester(UP) and epoxy resin have a superior material properties and a chemical resistance using sewerage pipes rehabilitation. However, UP and epoxy have not a low temperatures harding, the requirement $8{\sim}11$ hours long times harding and heating system used by reinforcement liner. This study is to evaluate the effects of low temperature harding properties methyl methacrylate(MMA) monomer using expanded polystyrene(EPS) in addition of initiator and promoters. From the test result, viscosity tends to increase with increasing EPS contents. However, harding time change of the MMA resins which it follows in addition of the initiator and promoter.

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A STUDY ON THE FIT OF THE IMPLANT-ABUTMENT-SCREW INTERFACE (임플란트-지대주-나사의 적합에 관한 연구)

  • Kim Nak-Hyung;Chung Chae-Heon;Son Mee-Kyoung;Back Dae-Hwa
    • The Journal of Korean Academy of Prosthodontics
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    • v.41 no.4
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    • pp.503-518
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    • 2003
  • Statement of problem : There have been previous studies about considerable variations in machining accuracy and consistency in the implant-abutment-screw interfaces. Purpose : The purpose of this study was to evaluate the machining accuracy and consistency of implant/abutment/screw combinations on two randomly selected implants from each of four manufactures. Material and methods : In this study, screws were respectively used to secure a cemented abutment, to a hexlock implant fixture ; teflon coated titanium alloy screw(Torq-Tite) and titanium alloy screw in Steri--Oss system, gold-plated gold-palladium alloy screw(Gold-Tite) and titanium alloy screw in 3i system gild screw ana titanium screw in AVANA Dental Implant system, and titanium screws in Paragon System. The implants were perpendicularly mounted in polymethyl methacrylate autopolymerizing acrylic resin block(Orthodontic resin, Densply International Inc. USA) by use of dental surveyer. Each abutment screw was secured to the implant with recommended torque value using a digital torque controller. Each screw was again tightened after 10 minutes. All samples were cross sectioned with grinder-polisher unit(Omnilap 2000 SBT Inc) after embeded in liquid unsaturated polyester (Epovia, Cray Valley Inc) Results : There were the largest gaps in the neck areas of screws in hexagonal extension implants which were examined in this study. The leading edge of the abutment screw thread (superior surface) was in contact with the implant body thread, and the majority of the contacting surfaces were localized to the middle portion of the mating threads. Considerable variation in the contacting surfaces was noted in the samples evaluated. Amounts of contact in the abutment screw thread were larger for assemblies with Gold-Tite screw, gold alloy screw. Torq-Tite screw than those with titanium screws. The findings of intimate contact between the screw and screw seat were seen in all samples, regardless of manufacturers. However, microgap between the head and lateral neck surface of the screw and the abutment could be dectected in all samples. The findings of intimate contact between the platform of the implant and the bottom of the abutment were consistent in all samples, regardless of manufacturers. However, microgaps between the lateral surface of external hex of the fixture and the abutment could be dectected in all samples. Conclusion : Considerable variations in machining accuracy and consistency were noted in the samples and the implant-abutment-screw interfaces were incomplete. From the results of this study, further development of the system will be required, including improvements in pattern design.

Preparation and Mechanical Properties of Bulk Molding Compound Composite Prepared using Recycled FRP Waste Powder (폐FRP 미분말을 재활용한 BMC 복합재료의 제조 및 기계적 물성)

  • Hwang, Eui-Hwan;Jeon, Jong-Ki
    • Applied Chemistry for Engineering
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    • v.21 no.2
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    • pp.217-223
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    • 2010
  • In general, fiber-reinforced plastics (FRP) wastes are simply buried or burned. Landfill brings about a permanent contamination of soil due to the inability of FRP to decompose and incineration causes an issue of generating toxic gases and dusts. There have been several ways to treat the FRP wastes such as landfill, incineration, chemical recycling, material recycling and the utilization of energy from combustion. Most methods excluding material recycling are known to have critical limitations in economic, technical and environmental manners. However it is known that material recycling is most desirable among the methods handling FRP wastes. In this study, to investigate the purpose of feasibility of material recycling, various bulk molding compound (BMC) specimens were prepared with the various contents of unsaturated polyester resin binder (25, 30, 35 wt%) and the various replacement ratios of FRP wastes powder (0, 25, 50, 75, 100 wt%) substituted for filler. To evaluate the physical properties BMC specimens, various tests such as tensile strength, flexural strength, impact strength, hot water resistance and SEM imaging were conducted. As a results, mechanical strengths decreased with an increase of replacement ratio of FRP waste powder and physical properties of BMC specimens were deteriorated in the hot water resistance. The fluidity of BMC with more than 50 wt% of the replacement ratio of FRP wastes powder decreased remarkably, causing a problem in the BMC composite.

Durability of High Performance Polymer Concrete Composites (Focusing on Chemical Resistance and Hot Water Resistance) (고성능 폴리머 콘크리트 복합재료의 내구성(내약품성 및 내열성을 중심으로))

  • Hwang, Eui-Hwan;Kim, Yong-Yeon;Song, Min-Kyu
    • Applied Chemistry for Engineering
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    • v.28 no.3
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    • pp.360-368
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    • 2017
  • In order to investigate the durability of high performance polymer concrete composites, polymer concrete specimens were prepared using the ortho-type unsaturated polyester resin (UPR) and iso-type UPR as a polymer binder and the calcium carbonate and silica fine powder as a filler. The durability of polymer concrete specimens was measured by hot water resistance, chemical resistance, pore analysis and SEM observation. The compressive strength of the specimen using the iso-type UPR was higher than that of using the ortho-type UPR, and the compressive strength of the specimen using the silica fine powder was higher than that of using the calcium carbonate filler. From hot water resistance results, it was found that the specimen using the iso-type UPR was superior to that of using the ortho-type UPR and the specimen using the calcium carbonate filler was superior to that of using the silica fine powder. The compressive strength reduction rate was measured after the chemical resistance test and the sodium hydroxide solution showed the highest reduction rate, followed by sulfuric acid, hydrochloric acid and calcium chloride solutions. When using the alkaline solution of sodium hydroxide, the weight reduction rate of the specimen using calcium carbonate was lower than that of using silica fine powder, while for the acidic solutions of sulfuric acid and hydrochloric acid, the weight reduction rate of the specimen using the silica fine powder was lower than that of using calcium carbonate.

Engineering Properties of Permeable Polymer Concrete with CaCO3 and Stone Dust (CaCO3와 석분을 혼입한 투수용 폴리머 콘크리트의 공학적 성질)

  • Sung, Chan Yong;Song, Young Jin;Jung, Hyun Jung
    • Korean Journal of Agricultural Science
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    • v.23 no.1
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    • pp.61-69
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    • 1996
  • This study was performed to evaluate the engineering properties of permeable polymer concrete with fillers and unsaturated polyester resin. The following conclusions were drawn. 1. The highest strength was achieved by stone dust filled permeable polymer concrete, it was increased 17% by compressive, 148% by tensile and 188% by bending strength than that of the normal cement concrete, respectively. 2. The static modulus of elasticity was in the range of $1.17{\times}10^5{\sim}1.32{\times}10^5kg/cm^2$, which was approximately 53~56% of that of the normal cement concrete. Stone dust filled permeable polymer concrete was showed relatively higher elastic modulus. The poisson's number of permeable polymer concrete was less than that of the normal cement concrete. 3. The dynamic modulus of elasticity was in the range of $1.3{\times}10^5{\sim}1.5{\times}10^5kg/cm^2$, which was approximately less compared to that of the normal cement concrete. Stone dust filled permeable polymer concrete was showed higher dynamic modulus. The dynamic modulus of elasticity were increased approximately 10~13% than that of the static modulus. 4. The water permeability was in the range of $3.076{\sim}4.390{\ell}/cm^2/h$, and it was largely dependent upon the mix design. These concrete can be used to the structures which need water permeability. 5. The compressive strength, tensile strength, bending strength and elastic modulus were largely showed with the decrease of water permeability.

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