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Methyl Viologen Mediated Oxygen Reduction in Ethanol Solvent: the Electrocatalytic Reactivity of the Radical Cation

  • Lin, Qianqi;Li, Qian;Batchelor-McAuley, Christopher;Compton, Richard G.
    • Journal of Electrochemical Science and Technology
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    • v.4 no.2
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    • pp.71-80
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    • 2013
  • The study of methyl viologen ($MV^{2+}$) mediated oxygen reduction in electrolytic ethanol media possesses potential application in the electrochemical synthesis of hydrogen peroxide mainly due to the advantages of the much increased solubility of molecular oxygen ($O_2$) and high degree of reversibility of $MV^{2+/{\bullet}+}$ redox couple. The diffusion coefficients of both $MV^{2+}$ and $O_2$ were investigated via electrochemical techniques. For the first time, $MV^{2+}$ mediated $O_2$ reduction in electrolytic ethanol solution has been proved to be feasible on both boron-doped diamond and micro-carbon disc electrodes. The electrocatalytic response is demonstrated to be due to the radical cation, $MV^{{\bullet}+}$. The homogeneous electron transfer step is suggested to be the rate determining step with a rate constant of $(1{\pm}0.1){\times}10^5M^{-1}s^{-1}$. With the aid of a simulation program describing the EC' mechanism, by increasing the concentration ratio of $MV^{2+}$ to $O_2$ electrochemical catalysis can be switched from a partial to a 'total catalysis' regime.

EBSD studies of the grain size and grain orientation distribution of $SrTiO_3$ (EBSD를 이용한 $SrTiO_3$의 입자 크기 및 입자 배향 분포)

  • Park, Myung-Beom;Shih, Shao-Ju;Cho, Nam-Hee;Cockayne, David J.H.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.06a
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    • pp.46-46
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    • 2006
  • $SrTiO_3$ was annealed at two different annealing times (1 h and 16 h) to investigate the annealing effect on the grain size and orientation distribution. Electron backscattered diffraction (EBSD) was used to analyze the grain size and grain orientation distributions of the $SrTiO_3$. It is possible to understand the annealing effect on the microstructure evolution, by comparing the grain size and orientation distribution of the $SrTiO_3$ as a function of annealing time.

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EFFECT OF SURFACE ROUGHNESS ON THE ADHESION OF SILICON WAFERS PRIOR TO BONDING

  • Lee, D. H.;B. Derby
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.06a
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    • pp.497-502
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    • 1998
  • To understand the effect of surface roughness on silicon wafer bonding, a continuum mechanical model is presented. This model is based on Obreimoff's experiment and the contact theory of rough surfaces. The surface energy of silicon was calculated to be much reduced than the theoretical value. Problems are discussed concerning surface film effects and the assumption of constant asperity radius and statistical distribution function.

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Association between Smoking and Mortality: Khon Kaen Cohort Study, Thailand

  • Kamsa-ard, Siriporn;Promthet, Supannee;Lewington, Sarah;Burrett, Julie Ann;Sherliker, Paul;Kamsa-ard, Supot;Wiangnon, Surapon;Parkin, Donald Maxwell
    • Asian Pacific Journal of Cancer Prevention
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    • v.14 no.4
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    • pp.2643-2647
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    • 2013
  • Background: Despite anti-smoking campaigns, smoking prevalence among Thai males aged 30 or older is high, at around 50%. The purpose of this study was to determine the relationship between smoking and mortality in a rural Thai community. Materials and Methods: Subjects enrolled into the Khon Kaen cohort study between 1990 and 2001 were followed up for their vital status until $16^{th}$ March 2012. The death resource was from the Bureau of Policy and Strategy, Ministry of Interior, Thailand. A Cox proportional hazards model was used to analyse the association between smoking and death, controlling for age, education level and alcohol drinking, and confidence intervals were calculated using the floating risk method. Results: The study recruited 5,962 male subjects, of whom 1,396 died during a median 13.5 years of follow-up. Current smokers were more likely to die than never smokers after controlling for age, education level and alcohol drinking (HR, 95%CI: 1.41, 1.32-1.51), and the excess mortality was greatest for lung cancer (HR, 95%CI: 3.51, 2.65-4.66). However, there was no increased risk with increasing dose of tobacco, and no difference in risk between smokers of yamuan (hand-rolled cigarettes) and manufactured tobacco. Conclusion: Mortality from cancer, particularly lung cancer, and from all causes combined is dependent on smoking status among men in rural Thailand, but the relative risks are lower than have been reported from studies in high income countries, where the tobacco epidemic is more established.

Dual effects of ram pressure on star formation in multiphase disk galaxies with strong stellar feedback

  • Lee, Jaehyun;Kimm, Taysun;Katz, Harley;Rosdahl, Joakim;Devriendt, Julien;Slyz, Andrianne
    • The Bulletin of The Korean Astronomical Society
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    • v.46 no.1
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    • pp.28.2-28.2
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    • 2021
  • We investigate the impact of ram pressure stripping due to the intracluster medium (ICM) on star-forming disk galaxies with a multiphase interstellar medium maintained by strong stellar feedback. We carry out radiation-hydrodynamic simulations of an isolated disk galaxy embedded in a 1011 M⦿ dark matter halo with various ICM winds mimicking the cluster outskirts (moderate) and the central environment (strong). We find that both star formation quenching and triggering occur in ram pressure-stripped galaxies, depending on the strength of the winds. HI and H2 in the outer galactic disk are significantly stripped in the presence of moderate winds, whereas turbulent pressure provides support against ram pressure in the central region, where star formation is active. Moderate ICM winds facilitate gas collapse, increasing the total star formation rates by ~40% when the wind is oriented face-on or by ~80% when it is edge-on. In contrast, strong winds rapidly blow away neutral and molecular hydrogen gas from the galaxy, suppressing star formation by a factor of 2 within ~200 Myr. Dense gas clumps with nH≳10 M⦿ pc-2 are easily identified in extraplanar regions, but no significant young stellar populations are found in such clumps. In our attempts to enhance radiative cooling by adopting a colder ICM of T=106K only a few additional stars are formed in the tail region, even if the amount of newly cooled gas increases by an order of magnitude.

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