• Title/Summary/Keyword: UV-vis spectrophotometer

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Properties Evaluation of $SnO_2$ : Sb transparent conductive films by $SiO_2$ barrier ($SiO_2$ barrier에 따른 $SnO_2$ : Sb 투명전도막의 특성고찰)

  • 김범석;김창열;임태영;오근호
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.03a
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    • pp.190-190
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    • 2003
  • 여러원소 (Sb, F 등)를 도핑한 SnO$_2$ 투명전도막은 여러 가지 훌륭한 특성으로 Solar cell, heat mirrors, gas sensors, liquid crystal displays, thick film resistor 등과 같이 넓은 범위에서 응용되고 있다. 본 연구에서는 Sb 도핑된 Tin Oxide films이 Sol-gel dip coating법에 의해 준비되었다. SnO$_2$:Sb 용액은 SnC1$_2$ 와 SbC1$_3$ Power를 알코올에 용해하여 Ethylene glycol 와 Citric acid를 첨가하여 합성하였다. 막의 상형성은 XRD와 SEM(Scanning electron microscope)에 의해서 분석되었으며, 특성분석은 투과율(UV/VIS Spectrophotometer)과 표면전기저항(four point probe)으로 분석되었다. SiO$_2$ barrier이 SnO$_2$:Sb 막의 특성에 미치는 영향을 확인하기 위하여 XPS(X-ray photoelectron spectroscopy) 분석이 적용되었다.

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A study on Characteristics of Microcrystalline Silicon Films Fabricated by PECVD Method (플라즈마 화학증착법으로 제작한 미세결정질 실리콘 박막 특성에 관한 연구)

  • Lee, Jong-Ha;Lee, Byoung-Wook;Lee, Ho-Nyeon;Kim, Chang-Kyo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.04a
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    • pp.57-58
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    • 2008
  • Microcrystalline (${\mu}c$) silicon thin films were prepared on glass by plasma-enhanced-chemical-vapor-deposition (PECVD) at various substrate temperature, and dilution ratio of $H_2$ with $SiH_4$. The structural and optical properties of. the ${\mu}c-Si$ thin films were investigated using XRD and UV-VIS spectrophotometer. The ${\mu}c-Si$ thin film with 42 nm grain size was grown at optimal condition of 2.5 Torr, spacing between electrodes of 3cm, deposition time of 3000s, RF power of 200W, substrate temperature of $350^{\circ}C$, $SiH_4$ ($20%SiH_4$+80%He) of 50sccm, and $H_2$ of 100sccm.

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A stability on the solvents of 9-Phenyl-5,5'-Diphenyl-3,3'-Bis-(3-sulfopropy)-benzoxazolo carbocyanine triethyl ammonium salt (9-Phenyl-5,5'-Diphenyl-3,3'-Bis-(3-sulfopropy)-Benzoxazolo Carbocyanine Triethyl Ammonium Salt의 용매에 대한 안정성)

  • Kim, Yeoung-Chan
    • The Journal of Information Technology
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    • v.7 no.2
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    • pp.1-5
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    • 2004
  • The symmetric 9-phenyl-5,5'-diphenyl-3,3'-bis-(3-sulfopropyl)-benzoxazolo carbocyanine triethyl ammonium salt is of industrial importance as green-sensitizing dye in the spectral sensitization of emulsion microcrystals in negative film and positive paper-making. The stability on the solvents of benzoxazolo carbocyanine dye was measured by UV-Vis spectrophotometer, and then dye was stabilized in various solvents. The maximum absorption peak range in various solvents was 507nm~515nm. It was identified that the solvents can be used to photographic emulsion.

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Effects of Precursor Concentration on the Growth of ZnO Nanorods (ZnO 나노로드 성장에 미치는 전구체 농도의 영향)

  • Ma, Tae-Young
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.65 no.11
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    • pp.1835-1839
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    • 2016
  • In this study, ZnO nanorods were grown by a hydrothermal method. $SiO_2/Si$ wafers and glass were used as substrates. ~20 nm-thick ZnO thin films were rf magnetron sputtered for seed layers. The precursor was prepared by mixing zinc nitrate hexahydrate and hexamethylenetetramine (hexamine) in DI water. The concentration of zinc nitrate hexahydrate was fixed at 0.05 mol, and that of hexamine was varied between 0 mol to 0.1 mol. The reactor containing substrates and precursor was put in an oven maintained at $90^{\circ}C$ for 1 h. X-ray diffraction was carried out to analyze the crystallinity of ZnO nanorods, and a field emission scanning electron microscope was employed to observe the morphology of nanorods. Transmittance and absorbance were measured by a UV-Vis spectrophotometer. Photoluminescence measurements were conducted using 266 nm light.

Electrical and Optical Propeties of CdS Films Prepared by Vacuum Evaporation (진공증착법으로 제조한 CdS 박막의 전기적 및 광학적 성징)

  • 김동섭;임호빈
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1991.10a
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    • pp.12-16
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    • 1991
  • Cadmium sulphide films with thickness of 0.6∼1.2$\mu\textrm{m}$ were deposited onto corning 7059 glass substrate under a vacuum of 5${\times}$10$\^$-6/ Torr. Source and substrate temperature ranges used were 800∼1100$^{\circ}C$ and 100∼200$^{\circ}C$, respectively. The microstructures and semiconducting properties of the films were studied using X-ray diffraction, UV-VIS-IR spectrophotometer and Hall measurement unit. Electrical resistivity and optical transmission of the CdS films decrease with an increase in source temperature while they increase with an increase in substrate temperature. The resistivity of the film evaporated at 1100$^{\circ}C$ varied from 7${\times}$10$^3$ohm-cm at the substrate temperature of 100$^{\circ}C$ to 2${\times}$10$\_$6/ohm-cm at 190$^{\circ}C$. All the films had hexagonal structure and strong texture with c-axis of grains normal to the substrate glass.

Formation of $TiO_2$ Nanoparticle by Photochemical Synthesis(III) (광화학 합성에 의한 $TiO_2$ 나노입자 형성 (III))

  • Jeong, Jae-Hoon;Moon, Jeong-Oh;Moon, Byung-Kee;Son, Se-Mo;Chung, Su-Tae
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2002.07b
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    • pp.756-759
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    • 2002
  • Nanoparticles of titanium dioxide$(TiO_2)$ were prepared by photochemical synthesis. Surface structure, morphology and particle size of $TiO_2$ thin films were investigated by UV-VIS spectrophotometer, scanning electron microscopy(SEM) and transmission electron microscopy(TEM). All process was prepared at room temperature. The absorption peak of the films was showed at 360nm and $TiO_2$ nanopaticle size was observed at about 20~30nm. Electron diffraction ring patterns of $TiO_2$ nanoparticles and crystallographic spacing were observed by TEM. As a result, crystallographic spacing was about 3.6A in HR-TEM micrographs.

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Electrical and optical properties of ZnO:Ga, Al thin films prepared by sol-gel method (Sol-gel법에 의한 ZnO:Ga, Al 박막의 투명 전도막 제작과 전기 광학적 특성)

  • Nam, Gil-Mo;Kwon, Myoung-Seok
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.11a
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    • pp.305-306
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    • 2006
  • Ga-doped and Al-doped ZnO thin films were fabricated via a sol-gel technique and electrical and optical properties of the films were investigated. Film deposition was performed by spin coating at 4000 rpm for 30 s on $SiO_2$ glass substrate FE-SEM was used to obtain the surface morphology images and the film thickness Four-point probe and UV-VIS spectrophotometer were used to measure the sheet resistance and the optical transparency, respectively.

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Hybrid Nanocomposites of Palladium Nanoparticles Having POSS and MWNTs via Ionic Interactions

  • Jeon, Jong-Hwan;Lim, Jung-Hyurk;Kim, Kyung-Min
    • Macromolecular Research
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    • v.17 no.12
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    • pp.987-994
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    • 2009
  • Palladium nanoparticles having cubic silsesquioxanes (POSS) (Pd-POSS) were produced by the reaction of palladium (II) acetate and octa(3-aminopropyl)octasilsesquioxane octahydrochloride (POSS-${NH_3}^+$ in methanol at room temperature. Functionalized multiwalled carbon nanotubes (MWNT-COOH) were prepared by acid treatment of pristine MWNTs. The hybrid nanocomposites of Pd-POSS and MWNT-COOH (Pd-MWNT nanocomposites) were synthesized by self-assembly method via ionic interaction between positively charged Pd-POSS and negatively charged MWNT-$COO^-$. The spherical aggregates of Pd-POSS with a diameter of 40-60 urn were well attached to the surfaces of MWNT-COOH on Silicon wafer. The composition, structure, and surface morphology of Pd-MWNT nanocomposites were studied by UV-vis spectrophotometer, energy dispersive spectrum (EDX), scanning electron microscopy (SEM), and atomic force microscope (AFM).

Surface and Optical Characteristics of Cobalt Dopped-titanium Oxide Film Fabricated by Water Spray Pyrolysis Technique (습식 분무 열분해 방법으로 제조한 코발트 도핑된 티타늄 산화막의 표면 및 광학적 특성)

  • Song Ho-Jun;Park Yeong-Joon
    • Korean Journal of Materials Research
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    • v.15 no.3
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    • pp.209-215
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    • 2005
  • Titanium dioxide films $(TiO_2)$ doped cobalt transition metal were prepared on titanium metal by water spray pyrolysis technique. Micro-morphology, crystalline structure, chemical composition and binding state of sample groups were evaluated using field emission scanning microscope(FE-SEM), X-ray diffractometer(XRD), Raman spectrometer, X-ray photoelectron spectrometer(XPS). $TiO_2$ films of rutile structure were predominately formed on all sample groups and $Ti_2O_3$ oxide was coexisted on the surface of cobalt doped-sample groups. The optical absorption peaks measured by using UV-VIS-NIR spectrophotometer were observed at specific wavelength region in sample groups doped cobalt ion. This result could be analyzed by introducing crystal field theory.

Synthesis of Fe2O3−CoO−Cr2O3−MnO2 Pigments and Coloring in Glazes (Fe2O3−CoO−Cr2O3−MnO2계 안료의 합성 및 유약에서의 발색)

  • Shin, Kyung-Hyun;Lee, Byung-Ha
    • Journal of the Korean Ceramic Society
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    • v.44 no.10
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    • pp.554-561
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    • 2007
  • Synthesis and characterization of pigments by using $Fe_2O_3,\;CoO,\;Cr_2O_3\;and\;MnO_2$ were undertaken. The resulting pigments were characterized by using XRD, SEM, FT-IR and UV-Vis spectrophotometer. The color of glazed tiles containing 6 wt% pigment changed from dark green to black depending on the compositions of used materials. Pigments were calcined with mixed materials at $1350^{\circ}C$, and the dark green and dark brown color were obtained. Pigments were used to determine possible interactions between a pigment and a glaze.