• Title/Summary/Keyword: UV-vis spectrophotometer

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Pigmentation of Diketopyrrolopyrroles Compound through Solvent Thermal-treatment and Its Property (용매 열처리법을 통한 diketopyrrolopyrroles 화합물의 안료화 및 그 특성)

  • Kim, Jae Hwan;Yang, Seok Won;Kim, Dae-Sung;Wu, Guan Zhu;Lee, Gun-Dae;Park, Seong Soo
    • Applied Chemistry for Engineering
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    • v.25 no.4
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    • pp.357-362
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    • 2014
  • To prepare diketopyrrolopyrrole (DPP) red 254 pigment with high shield and bright color, DPP red 254 crude previously synthesized was treated at various thermal-treat temperature, addition derivative and ball-milling. The properties of samples were measured by the means of FT-IR, UV-Vis spectroscopy, TEM, PSA, BET surface area analyzer, viscometer and spectrophotometer. It was found that solvent thermal-treatment of the sample prepared after ball-milling as nano-scale was very effective method in pigmentation process.

Sodium titanate as an infrared reflective material for cool roof application

  • Ullah, Mahboob;Kim, Hee Jung;Heo, Jae Gu;Roh, Dong Kyu;Kim, Dae-Sung
    • Journal of Ceramic Processing Research
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    • v.20 no.spc1
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    • pp.86-91
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    • 2019
  • A solid-state route was used to prepare sodium titanium oxide (NTO, Na2Ti3O7) as a solar heat protecting material with an impressive solar reflectance (TSR = 94.3%) using a high refractive index rutile TiO2. The solar reflectance of the synthesized NTO was measured using UV-Vis-NIR spectrophotometer. Solar reflectance property of the synthesized compound depends on the calcination temperature. The solar reflectance property of the synthesized NTO powder was compared with commercial rutile TiO2. The compound synthesized at 900 ℃ for 24 hrs had remarkable solar reflectance 94.3% than that calcined below 900 ℃. Crystalline nature, structural property, morphology and optical properties of NTO powders were characterized and analyzed using XRD, FE-SEM, EDS and UV-Vis-NIR spectrophotometer. From the results, we guessed that NTO would be a suitable "solar heat protecting candidate" for energy-saving applications in coating industries.

Analysis of Chlorine Species in Chlorine Dioxide Bleaching Liquor and Generation Process by UV-VIS Spectroscopy

  • Wang, Li-Jun;Lee, Seon-Ho;Yoon, Byung-Ho
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 1999.04a
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    • pp.78-83
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    • 1999
  • In this paper the extinction coefficients of molecule chlorine ($Cl_2$), chlorine dioxide (ClO$_2$), hypochlorous acid (HClO), chlorous acid ($HClO_2$$_2$) were determined using a PDA UV-VIS spectrophotometer. Based on these, the concentrations of $Cl_2$, $ClO_2$, and HClO in general chlorine dioxide bleaching liquor can be measured. The concentrations of $Cl_2$, $ClO_2$ and $HClO_2$ produced during the generation of methanol based chlorine dioxide generator can also be determined use the same method. The method was thought to be able to give more information in chlorine dioxide bleaching chemistry if combine its use with titration and ion chromatography.

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Layer-by-layer self-assembly colorant multi-layer preparation using natural colorant Berberine and anionic polyelectrolyte (베르베린 천연색소화합물과 음이온고분자전해질을 이용한 layer-by-layer self-assembly 색소다층박막 제조)

  • Son Young-A;Park Young-Min;Lee Seung-Goo;Ravikumar K.
    • Textile Coloration and Finishing
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    • v.18 no.1
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    • pp.28-32
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    • 2006
  • A multi-layer of the dye, natural colorant Berberine, was successfully developed by the self-assembly deposition from water-soluble cationic dye(Berberine chloride) and anionic polyelectrolyte PSS(Polysodium 4-styrenesulfonate) in aqueous solution via electrostatic attraction. The corresponding results on multi-layer were characterized by UV-Vis absorbance measurements. The growth of multi-layer formed by the sequential interaction was also determined. The findings measured by UV-Vis spectrophotometer showed that the bilayer deposition characteristic was linear and highly reproducible from layer to layer.

Preparation of Nanosized Gold Particles by Microwave Irradiation and Kinetics Study for Reduction of 4-Nitroaniline under Various Conditions

  • Kim, Jae Jin;Ko, Weon Bae
    • Elastomers and Composites
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    • v.50 no.4
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    • pp.274-278
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    • 2015
  • Nanosized gold particles were synthesized by microwave irradiation in a mixture composed of potassium tetrachloroaurate(III) n-hydrate, sodium citrate dihydrate and Tween 20. The synthesized gold particles were characterized by UV-vis spectrophotometer, scanning electron microscopy, and X-ray diffraction techniques. Using UV-vis spectroscopy, it was confirmed that gold nanoparticles act as a catalyst in the reduction of 4-nitroaniline with sodium borohydride to form 1,4-diaminobenzene. Additionally, we studied the kinetics of this reductive reaction in the presence of these gold nanoparticles under various conditions.

Synthesis of Hybrid Fullerene Oxide[C60(O)n, (n≥1)] - Silver Nanoparticle Composites and Their Catalytic Activity for Reduction of 2-, 3-, 4-Nitroaniline

  • Park, Jeong Hoon;Ko, Jeong Won;Ko, Weon Bae
    • Elastomers and Composites
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    • v.54 no.3
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    • pp.252-256
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    • 2019
  • Fullerene oxide[$C_{60}(O)_n$, ($n{\geq}1$)] was synthesized by dissolving fullerene[$C_{60}$] and 3-chloroperoxybenzoic acid in toluene under refluxing condition for 5 h. Hybrid fullerene oxide-silver nanoparticle composites were synthesized by dissolving fullerene oxide and silver nitrate[$AgNO_3$] in diethylene glycol under ultrasonic irradiation for 3 h. The synthesized hybrid nanocomposites were characterized by X-ray diffraction, scanning electron microscopy, and ultraviolet-visible[UV-vis] spectroscopy. The catalytic activity for the reduction of various nitroanilines[NAs] was identified by UV-vis spectrophotometer. The efficiency of the catalytic reduction by the synthesized hybrid nanocomposites has an order of 4-NA > 2-NA > 3-NA.

Synthesis and Characterizations of Manganese and Iron Dopped Titania Pigment (망간과 철이 도핑된 이산화티탄 안료의 합성과 특성)

  • Kang, Kuk-Hyoun;Choi, Ji-Sik;Lee, Jin-Hee;Lee, Dong-Kyu
    • Journal of the Korean Applied Science and Technology
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    • v.29 no.3
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    • pp.393-401
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    • 2012
  • Inorganic pigment is excellent at stability to human body and compatibility with different materials and has been used in a variety of field such as cosmetics, printing inks, paints, and construction materials for improving the aesthetic features. In this paper, hydrothermal synthesis method was used to prepare the manganese and iron dopped with titania pigment. As process parameters, the amount of manganese precursor and iron precursor, and calcined temperature was changed. Optimum amounts of manganese and iron dopped with titania precursor to give excellent color index was manganese 1.0wt% and iron 1.5wt% for dopped titania, and Optimum calcination temperature was $550^{\circ}C$. The synthesized pigments were analyzed by XRD, SEM, EDS, Spectrophotometer and UV-Vis Spectrometer.

Study of the coloration factors of tinted lenses (착색렌즈의 색비율 정량화에 관한 연구)

  • Lim, Yong-Mu;Shim, Moon-Sik;Jung, Ju-Hyun
    • Journal of Korean Ophthalmic Optics Society
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    • v.6 no.2
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    • pp.37-46
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    • 2001
  • In this study, We compared the properties of tinted and colored lenses with the standards m the ordinary optical properties, coloration, UV, IR and luminous transmittance, color acceptance for traffic signal, and chromaticity. The UV, lR and luminous transmittance was analysed in the range of 175 nm to 3000 nm by using a UV-Vis-IR spectrophotometer and was used in the synthesis of spectrum of various color lens. A experimental function was made from the slope obtained from the transmittance change as a function of coloration time. We could expect the ordinary optical properties and color acceptance for traffic signal of various color lenses with the requirements of US standard(ANSI Z-80.3).

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The Study on the Intercalation-Deintercalation of Potassium-Carbon Fiber Intercalation Compounds (칼륨-탄소섬유층간화합물의 Intercalation-Deintercalation에 관한 연구)

  • Oh, Won-Chun;Cho, Sung-Jun;Choi, Young-Jai;Ko, Young-Shin
    • Analytical Science and Technology
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    • v.7 no.2
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    • pp.193-199
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    • 1994
  • We have synthesized K-CFICs by the modified two-bulb method. These synthesized compound were analysed with X-ray diffractometer and UV/VIS spectrophotometer. According to X-ray diffraction analysis, the intercalation of potassium between the carbon layers of carbon fiber was better then other intercalants. From obtained data for this deintercalation process, we can see that a number of potassiums were presented as a residue between the carbon layers and this residue compounds had a stability for a long term. Therefore, it is appear that these compounds have a capability as new useful material. From UV/VIS spectrometry data, we can suppose that spectrum of K-CFICs synthesized at $250^{\circ}C$ had only a $R_{min}$, and spectra of any other compounds were not appeared charecteristic peaks because potassium ions were little affect the energy levels of original carbon fiber.

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A Study on the Coloring of 304 Stainless Steel Screen for Reducing Light Reflectivity (304스테인리스강 스크린의 광 반사율 감소를 위한 착색 처리에 관한 연구)

  • Kim, Ki-Ho
    • Journal of the Korean institute of surface engineering
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    • v.43 no.4
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    • pp.187-193
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    • 2010
  • The colored films formed on 304 stainless steel plates by immersion treatment and electrochemical one in a solution containing sulphuric acids and chromic acids were studied by SEM, AES, and spectrophotometer. The thicknesses of the films by 20 minutes treatment were about 200 nm and it became thinner as the treatment times were increased. The surface texture showed a tortuous network of interlinking pathways. The color of the 304 steel surface changed from metallic white to gray, black, red, yellow-green, and green-blue, gradually, by the treatment time was increased. The reflectivity measured by UV-VIS-NIR spectrophotometer was reduced from max. 38% of basis metal to min. 3.5% of colored surface.