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http://dx.doi.org/10.7473/EC.2019.54.3.252

Synthesis of Hybrid Fullerene Oxide[C60(O)n, (n≥1)] - Silver Nanoparticle Composites and Their Catalytic Activity for Reduction of 2-, 3-, 4-Nitroaniline  

Park, Jeong Hoon (Department of Convergence Science, Graduate School, Sahmyook University)
Ko, Jeong Won (Nanomaterials Research Institute, Sahmyook University)
Ko, Weon Bae (Department of Convergence Science, Graduate School, Sahmyook University)
Publication Information
Elastomers and Composites / v.54, no.3, 2019 , pp. 252-256 More about this Journal
Abstract
Fullerene oxide[$C_{60}(O)_n$, ($n{\geq}1$)] was synthesized by dissolving fullerene[$C_{60}$] and 3-chloroperoxybenzoic acid in toluene under refluxing condition for 5 h. Hybrid fullerene oxide-silver nanoparticle composites were synthesized by dissolving fullerene oxide and silver nitrate[$AgNO_3$] in diethylene glycol under ultrasonic irradiation for 3 h. The synthesized hybrid nanocomposites were characterized by X-ray diffraction, scanning electron microscopy, and ultraviolet-visible[UV-vis] spectroscopy. The catalytic activity for the reduction of various nitroanilines[NAs] was identified by UV-vis spectrophotometer. The efficiency of the catalytic reduction by the synthesized hybrid nanocomposites has an order of 4-NA > 2-NA > 3-NA.
Keywords
Fullerene oxide[$C_{60}(O)_n$, ($n{\geq}1$)]; Silver nanoparticle; Ultrasonic irradiation; Catalytic activity; Nitroanilines;
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