• Journal of the Korean Society of Manufacturing Process Engineers
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• v.19 no.7
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• pp.67-73
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• 2020

Shrinkage is inevitable in the curing of resins during the nanoimprint process. The degree of shrinkage that occurs as the resin transforms from a viscous liquid to solid differs depending on the type of resin. However, if the cured material is repeatedly cured using the same material, constant shrinkage can be confirmed. In this study, the pattern of change was observed by repeatedly performing the nanoimprint process using a resin with a constant shrinkage rate. The observed pattern for the change of shape was made using a triangular pyramid-shaped aluminum master mold and a flexible replica mold made from the master. Shrinkage that results from the nanoimprint process occurs linearly in the longitudinal direction of the pattern and can be predicted by simple calculations. The change of the pattern due to shrinkage occurred as expected. If the shrinkage rate remains constant, various patterns can be manufactured with high accuracy by correcting these changes before producing a specific shape. This study confirms that the pattern of the desired angle can be obtained by performing the repeated imprint without having to manufacture a master mold.

• Journal of the Korean Society of Industry Convergence
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• v.22 no.5
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• pp.467-473
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• 2019

In this study, approached to improve durability of the multi-functional nano-pattern fabricated on the curved lens surface using nanoimprint lithography (NIL) was proposed, and the effects of the proposed methods on functionality after wear test were examined. To improve the mechanical property of ultraviolet(UV)-curable resin, UV-NIL was conducted at the elevated temperature around $60^{\circ}C$. In addition, micro/nano hierarchical structures was fabricated on the lens surface with a durable film mold. Analysis on the worn surfaces of nano-hole pattern and hierarchical structures and measurements on the static water contact angle and critical water volume for roll-off indicated that the UV curing process with elevated temperature is effective to maintain wettability by increasing hardness of resin. Also, it was found that the micro-scale pattern is effective to protect nano-pattern from damage during wear test.

• Textile Coloration and Finishing
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• v.9 no.6
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• pp.79-86
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• 1997

The microcapsule for thermochromism is based on the polymerization reaction between epoxy resin and amine curing agent. The preparation process of microcapsule is based on dissolving or dispersing a hydrophobic core materials[one-dye-black(OBD), bis-phenol A(BPA), cetyl alcohol] in an aqueous solution of gelatin, epoxy resin and isophorondiamine(IPDA) ; the gelatin and IPDA used as a dispersion stabilizer and an hardening agent, respectively. The structures of epoxy resin and microcapsule materials have been analyzed by FT-IR and UV/Vis spectra. The mean diameter and size distribution of microcapsule are 1.46~1.75${\mu}{\textrm}{m}$ and 1.42, respectively. The DSC thermograms of microcapsules indicated 2 kinds of endothermic peaks at 47 and 322$^{\circ}C$. This is possibly corresponding to the melting peak of core material and wall meterial. These microcapsules are applied to the fabric by printing. Complex finished fabric showed a good wear resistance on rubbing test and the print pattern to the cotton fabric showed a reversible thermochromism ; ${\mu}_{max}$ are 580 nm below 4$0^{\circ}C$ and 276.5nm above 4$0^{\circ}C$ in ethanol/water(2/8), respectively.

• Journal of the Korea Convergence Society
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• v.12 no.7
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• pp.125-131
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• 2021

Blue light with strong energy is required for light-curing resin treatment, which is being used more frequently in dentistry. To reduce the risk of exposure to scattered light, we tried to use colored lenses. The tips for light curing machine and a commercially available yellow-type blue-light blocking lens and a yellow lens colored with yellow dye, which are expected to be effective in blocking blue light, were placed in a UV-Vis spectrometer device, and transmission and blocking of blue light were tested respectively. As a result, the average blue light blocking rate of the light curing machine tips was 99.49%, and the C lens with the highest color density among commercially available lenses showed a high blue light blocking rate of 99.54%. In the case of lenses tinted with yellow, the yellow tinted C lens with the highest tint concentration showed 87.57% of blue light blocking rate. It is judged that the side effects related to the eyes caused by blue light can be reduced if a yellow-type commercially available or colored lens is worn along with a light curing machine tip during resin treatment.

• Polymer(Korea)
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• v.35 no.4
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• pp.320-324
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• 2011

Two functional urethane acrylates were synthesized by using polycarprolactonediol (PCLD) and diisocyanate. The synthesized fuctional urethane acrylate was mixed with butyl acrylate(BA) or adhesion promoters, and their properties were investigated. To synthesize an excellent transparent urethane acrylate, isophorone diisocyanate(IPDI) was used. In addition, the effect of adding butyl acrylate for the improvement of shrinkage of urethane acrylate was studied. The results showed that the addition of butyl acrylate improved the shrinkage, and the optimum butyl acrylate content was 15 wt%. Both 2-ethyl hexyl acrylate (2-EHA) and ethyl acrylate(EA) were polymerized at $85^{\circ}C$ for 4 hrs to use as adhesion promoters, and the polymerized adhesion promoters were mixed to the UV-curing resin. The results showed that the adhesion properties increased with the increase of adhesion promoters content up to 15 wt%.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2012.05a
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• pp.41-42
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• 2012

High temperature / high pressure spray equipment using a conventional method, unlike spray polyurea adjustable pot life and yellowing caused by UV light and chemicals do not occur, or discoloration of Self-Leveling Type of rugged hand-polyurea resin for technology development is underway. This new concept of polyurea resin roller, brush, airless spray, and they installed easily using the unfamiliar labor, and curing time of approximately four hours to gain control of the glass because it is Pot. Construction, but does not like the spray polyurea resin, compared to the existing degradation of the adhesion strength is concerned. In this study, Self-Leveling Type Manual of polyurea resin adhesion strength of target deterioration Let's minimize problems by reviewing existing domestic and infrastructure long-term durability for long life of the facility is to obtain.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2008.11a
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• pp.421-421
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• 2008

Generally, the polymer thick-film resistors for embedded organic or hybrid substrate are patterned by screen printing so that the accuracy of resistor pattern is not good and the tolerance of resistance is too high(${\pm}$20~30%). To reform these demerits, a method using Fodel$^{(R)}$ technology, which is the patterning method using a photosensitive resin to be developable by aqueous alkali-solution as a base polymer for thick-film pastes, was recently incorporated for the patterning of thermosetting thick-film resistor paste. Alkali-solution developable photosensitive resin system has a merit that the precise patterns can be obtained by UV exposure and aqueous development, so the essential point is to get the composition similar to PSR(photo solder resist) used for PCB process. In present research, we made the photopatternable resistor pastes using 8 kinds of epoxy acrylates and a conductive carbonblack (CDX-7055 Ultra), evaluated their developing performance, and then measured the resistance after final curing. To become developable by alkali-solution, epoxy acrylate oligomers with carboxyl group were prepared. Test coupons were fabricated by patterning copper foil on FR-4 CCL board, plating Ni/Au on the patterned copper electrode, applying the resistor paste on the board, exposing the applied paste to UV through Cr mask with resistor patterns, developing the exposed paste with aqueous alkali-solution (1wt% $Na_2CO_3$), drying the patterned paste at $80^{\circ}C$ oven, and then curing it at $200^{\circ}C$ during 1 hour. As a result, some test compositions couldn't be developed according to the kind of oligomer and, in the developed compositions, the measured resistance showed different results depending on the paste compositions though they had the same amount of carbonblack.

• Journal of the Korean Society for Precision Engineering
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• v.23 no.11 s.188
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• pp.116-125
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• 2006

MEMS and LIGA technologies have been used for fabricating microstructures, but their shape is not 3D because of difficulty for preparation of many masks. To fabricate 3D microstructures, microstereolithography technology based on Digital Micromirror Device($DMD^{TM}$) was introduced. It has no need of masks and is capable of fabricating high aspect ratio microstructures. In this technology, STL file is the standard format as the same of conventional rapid prototyping system, and 3D parts are fabricated by layer-by-layer according to 2D section sliced from STL file. The UV light source is illuminated to DMD which makes bitmap images of 2D section, and they are transferred and focused on resin surface. In this paper, we addressed optical design of microstereolithography system in consideration of light path according to DMD operation and image-forming on the resin surface using optical design program. To verify the performance of implemented microstereolithography system, 3D microstructures with complexity and high aspect ratio were fabricated.

• Journal of the Korean Graphic Arts Communication Society
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• v.18 no.2
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• pp.113-124
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• 2000

It is well known that the characteristics of liquid crystal polymer composite(LCPC) films are possessed of large-area and flexible display, polarizer free, high contrast, wide angle of visual filed and high responsiveness. In this study, we have investigated to the best optimal mixing rates chiral nematic liquid crystals and UV-curable resins having different properties acrylate moleculars. The purpose of this study has been the development of new functional application with liquid crystal polymer composite films. For example the films were applied a new thermal sensor. In results, best phase separation behaviors turned out liquid crystal/monomer/oilgomer mixture system.

• Journal of Technologic Dentistry
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• v.42 no.2
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• pp.65-71
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• 2020

Purpose: To know the transmittance of light when wearing shading goggles and to protect eyes from blue light emitted from dental scanner when using CAD/CAM works or inducing polymerization reactions of dental resin with curing unit and infrared light occurred when melting Dental precious metal and non-precious metal alloys. Methods: By measuring and comparing the average transmittances of blue light, visible light and infrared ight by using UV-Vis Spectrophotometer analysis measuring instrument, I compared 3 GREEN Color Goggles worn when casting Dental precious metal and non-precious metal alloys, and compared each of YELLOW, ORANGE Color Goggles worn when using Dental CAD/CAM scanners and Light Curing(LED) the Dental resin. Results: In blue light range, YELLOW Color Goggles are more effective than ORANGE Color Goggles. In infrared light range, No.12 Goggles are more effective than No.10 and No.11 Goggles. Conclusion: When wearing blue light shading goggles to avoid harmful blue light occurred in using dental scanner and curing light, and when wearing infrared light shading goggles to avoid harmful infrared light during casting, to avoid the Side Effects like transmittance rate of blue light and infrared light goggles becomes too high to block appropriate amount of harmful light or too low that causing lower image clarity.