• Title/Summary/Keyword: UV-absorption

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Computational Analysis of 355 nm UV Laser Single-Pulsed Machining of Copper Material Considering the Strain Rate Effect (변형률 속도 효과를 고려한 355 nm UV 레이저 구리재질의 싱글 펄스 전산해석)

  • Lee, Jung-Han;Oh, Jae Yong;Park, Sang Hu;Shin, Bo Sung
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.9 no.3
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    • pp.56-61
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    • 2010
  • Recently, UV pulse laser is widely used in micro machining of the research, development and industry field of IT, NT and BT products because the laser short wavelength provides not only micro drilling, micro cutting and micro grooving which has a very fine line width, but also high absorption coefficient which allows a lot of type of materials to be machined more easily. To analyze the dynamic deformation during a very short processing time, which is nearly about several tens nanoseconds, the commercial Finite Element Analysis (FEA) code, LS-DYNA 3D, was employed for the computitional simulation of the UV laser micro machining behavior for thin copper material in this paper. A finite element model considering high strain rate effect is especially suggested to investigate the micro phenomena which are only dominated by mechanically pressure impact in disregard of thermally heat transfer. From these computational results, some of dynamic deformation behaviors such as dent deformation shapes, strains and stresses distributions were observed and compared with previous experimental works. These will help us to understand micro interaction between UV laser beam and material.

Development of UV Corona Camera for the Detecting of Discharge on Power Facility using UV Transmittance Improvement Filter (UV 투과율 향상 필터 기술을 이용한 전력설비 방전 검출용 자외선 코로나 카메라 개발)

  • Kim, Young-Seok;Choi, Myeong-Il;Kim, Chong-Min;Bang, Sun-Bae;Shong, Kil-Mok
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.61 no.11
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    • pp.1656-1661
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    • 2012
  • UV inspection technology is being used for predictive maintenance of power facility together with IR-thermography and ultrasonic devices. In this paper, the UV corona camera design, fabrication, and perform a simple test to be take advantage of the diagnostic equipment. The UV corona camera developed a $6.4^{\circ}{\times}4.8^{\circ}$ of the field of view as a conventional camera to diagnose a wide range of slightly enlarged, and power equipment to measure the distance between the camera and the distance meter has been attached. The transmission between 250 to 280nm was 11% ($12.5%{\times}88%{\times}98%$) by combing the transmission on absorption film, window and other filter(UG 5, nickel sulphate and so on). In a distance of 5m with the UV corona camera it is possible to detect partial discharge with a PD level of 2.5pC and a RIV level of $3.6dB{\mu}V$.

Effect of Photoinitiator System on Mechanical Properties and Water Sorption Behavior of Urethane Acrylate/MMT Nanocomposite by UV Radiation Curing (UV 경화형 우레탄 아크릴레이트/MMT 나노복합체의 기계적 성질과 내흡수성에 대한 광개시제의 영향)

  • Kim, Ho-Gyum;Min, Kyung-Eun
    • Polymer(Korea)
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    • v.39 no.2
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    • pp.256-260
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    • 2015
  • The addition of montmorillonite (MMT) in the UV curable polyurethane diacrylate based resins was investigated to fabricate nanocomposites with improved mechanical properties and water sorption behavior using different photoinitiator systems. As a result, it was observed that 1 wt% of clay loading fairly improved tensile resistance and water uptake behavior. It can be also confirmed that dual photoinitiator system consisted of benzyldimethyl ketal and bisacyl phosphine oxide exhibited enhanced energy absorption band 340~450 nm even with 3 wt% of MMT concentration, which may affect the curing behavior of nanocomposite especially in our UV lamp system.

Photohysical Properties of New Psoralen Derivatives:Psoralens Linked to Adenine through Polymethylene Chains

  • Yoo, Dong-Jin;Park, Hyung-Du;Kim, Ae-Rhan;Rho, Young S.;Shim, Sang-Chul
    • Bulletin of the Korean Chemical Society
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    • v.23 no.9
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    • pp.1315-1327
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    • 2002
  • The model compounds, 8-methoxypsoralen-CH2O(CH2)n-adenine (MOPCH2OCnAd, n=2, 3, 5, 6, 8, and 10) in which 5 position of 8-methoxypsoralen (8-MOP) is linked by various lengths of polymethylene bridge to N9 of adenine. UV absorption spectra are identical with the sum of MOPCH2OC3 and adenine absorption spectra. Solvent effects on the UV absorption and fluorescence emission spectra indicate that the lowest excited singlet state is the $(\pi${\rightarrow}$\pi*)$ state. The spectral characteristics of the fluorescence of MOPCH2OCnAd are strongly dependent upon the nature of the solvents. The fluorescence emission spectra in aprotic solvents are broad and structureless due to the excimer formation through the folded conformation accelerated by hydrophobic ${\pi}-{\pi}$ stacking interaction. Increasing polarity of the protic solvents leads to higher population of unfolded conformation stabilized through favorable solvation and H-bonding, and consequently to an increase in the fluorescence intensity, fluorescence lifetime, and a shift of fluorescence maximum to longer wavelengths. The decay characteristics of the fluorescence in polar protic solvents shows two exponential decays with the lifetimes of 0.6-0.8 and 1.6-1.9 ns in 5% ethanol/water, while MOPCH2OC3 shows 0.5 and 1.7 ns fluorescence lifetimes. The long-lived component of fluorescence can be attributed to the relaxed species (i.e., the species for which the solvent reorientation (or relaxation) has occurred), while the short-lived components can be associated with the unrelaxed, or only partially relaxed, species.

Evaluation of electrical energy consumption in UV/H2O2 advanced oxidation process for simultaneous removal of NO and SO2

  • Shahrestani, Masoumeh Moheb;Rahimi, Amir
    • Environmental Engineering Research
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    • v.24 no.3
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    • pp.389-396
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    • 2019
  • The electrical energy consumption (EEC) in removal of NO by a $UV/H_2O_2$ oxidation process was introduced and related to removal efficiency of this gas. The absorption-reaction of NO was conducted in a bubble column reactor in the presence of $SO_2$. The variation in NO removal efficiency was investigated for various process parameters including NO and $SO_2$ inlet concentrations, initial concentration of $H_2O_2$ solution and gas flow rate. EEC values were obtained in these different conditions. The removal efficiency was increased from about 22% to 54.7% when $H_2O_2$ concentration increased from 0.1 to 1.5 M, while EEC decreased by about 70%. However, further increase in $H_2O_2$ concentration, from 1.5 to 2, had no significant effect on NO absorption and EEC. An increase in NO inlet concentration, from 200 to 500 ppm, decreased its removal efficiency by about 10%. However, EEC increased from $2.9{\times}10^{-2}$ to $3.9{\times}10^{-2}kWh/m^3$. Results also revealed that the presence of $SO_2$ had negative effect on NO removal percentage and EEC values. Some experiments were conducted to investigate the effect of $H_2O_2$ solution pH. The changing of pH of oxidation-absorption medium in the ranges between 3 to 10, had positive and negative effects on removal efficiency depending on pH value.

Study on Optical Characteristics of Nano Hollow Silica with TiO2 Shell Formation

  • Roh, Gi-Yeon;Sung, Hyeong-Seok;Lee, Yeong-Cheol;Lee, Seong-Eui
    • Journal of the Korean Ceramic Society
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    • v.56 no.1
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    • pp.98-103
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    • 2019
  • Optical filters to control light wavelength of displays or cameras are fabricated by multi-layer stacking process of low and high index thin films. The process of multi-layer stacking of thin films has received much attention as an optimal process for effective manufacturing in the optical filter industry. However, multi-layer processing has disadvantages of complicated thin film process, and difficulty of precise control of film morphology and material selection, all of which are critical for transmittance and coloring effect on filters. In this study, the composite $TiO_2$, which can be used to control of UV absorption, coated on nano hollow silica sol, was synthesized as a coating material for optical filters. Furthermore, systematic analysis of the process parameters during the chemical reaction, and of the structural properties of the coating solutions was performed using SEM, TEM, XRD and photo spectrometry. From the structural analysis, we found that the 85 nm nano hollow silica with 2.5 nm $TiO_2$ shell formation was successfully synthesized at proper pH control and titanium butoxide content. Photo luminescence characteristics, excited by UV irradiation, show that stable absorption of 350 nm-light, correlated with a 3.54 eV band gap, existed for the $TiO_2$ shell-nano hollow silica reacted with 8.8 mole titanium butoxide solution. Transmittance observed on substrate of the $TiO_2$ shell-nano hollow silica showed effective absorption of 200-300 nm UV light without deterioration of visible light transparency.

Analysis of Germanium in the Ore Samples by UV-Visible Spectroscopy

  • Reddy, K. Raghava;Lee, Kwang-Pill;Gopalan, Anantha Iyengar;Showkat, Ali Md;Kim, Sang-Ho;Paek, U-Hyon
    • Analytical Science and Technology
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    • v.17 no.6
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    • pp.476-480
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    • 2004
  • A simple, rapid, reproducible and selective UV-Visible spectrophotometric method has been developed for determination of germanium in a week acid medium (pH = 3.0) in the presence of mandelic acid (MA) and malachite green (MG). A single extraction in chlorobenzene was used for the analysis. The germanium-MA ion association complex exhibits an absorption maximum at ${\lambda}_{max}=618nm$ with MG as counter ion and has an apparent molar absorptivtity of $1.313{\times}10^5L\;mol^{-1}\;cm^{-1}$. The values obtained by this UV-Visible spectrophotometric method are in good agreement with the values from inductively coupled plasma-mass spectrometer analysis.

Estimation of the Light Absorption Contribution for Asian Dust and Polluted Particles at Gosan, Jeju during the Asian Dust Episode in the Spring 2011 (2011년 봄 황사시기 제주도 고산에서의 황사와 오염입자의 광흡수 기여도 산정)

  • Lee, Si-Hye;Kim, Sang-Woo;Yoon, Soon-Chang
    • Journal of Korean Society for Atmospheric Environment
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    • v.28 no.4
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    • pp.411-422
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    • 2012
  • Ground-based in-situ measurements of aerosol optical properties at Gosan climate observatory have been analyzed to investigate the optical contribution of Asian dust and polluted particles on light absorption in springtime 2011. During the Asian dust episode, the contribution of Asian dust particle to aerosol absorption coefficient estimated about 45% at 370 nm and about 23% at 520 nm. Especially, black carbon in dust plume contributes about 48% to aerosol light absorption at 520 nm since the airmass are transported from the Gobi and inner Mongolia deserts, and this airmass comes across the northeastern coast of China, near the Shandong Peninsula. In pollution case, the contributions of dust particle and black carbon to aerosol absorption coefficient estimated about 41% and 11% at 370 nm, respectively. However, pollution case shows the highest light absorption of 48% for brown carbon at 370 nm, which indicates the significantly high mass concentration of organic carbon ($6.3{\pm}2.2{\mu}g\;m^{-3}$) in pollution plume can contribute to the increase of light absorption at near-UV spectral region.

Mg II LINE VARIATION OF 32 CYGNI

  • Kang, Young-Woon
    • Journal of Astronomy and Space Sciences
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    • v.9 no.2
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    • pp.154-164
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    • 1992
  • The Mg II lines been extracted from the IUE archival spectra of 32 Cygni to investigate the effect of the atmospheric eclipse. The UV light curve has been reduced from the continuum flux at the center wavelength of 2807.5 ${\AA}$ in the IUE spectra. The equivalent width of the Mg II k absoption line has been measured for each spectra. The results of the light variation and flux tracing of the absorption line at the vicinity of the primary eclipse confirmed the atmospheric eclipse. The atmospheric effect lasted until the phase 0.06 in the absorptin line tracing, while it lasted until the phase 0.02 in the UV light curve, respectively.

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Symmetry and Spectra of Complexes of Azo-Substituted Copper Phthalocyanine (Copper Phthalocyanine과 그 Azo 置換錯鹽들의 對稱과 Spectra)

  • Cho Nam-Sook;Kim Ki-Hwan;Hahn Chi-Sun
    • Journal of the Korean Chemical Society
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    • v.16 no.6
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    • pp.378-384
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    • 1972
  • The UV absorption spectra of the copper phthalocyanine and its azo derivatives in pyridine have been examined on the basis of symmetry operation, ligand field theory and molecular orbital consideration. The above treatment was also employed to determine the structure of the synthesized complexes.

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